Organic electroluminescent element

Patent metadata

Field	Value
Publication number	US-11189802-B2
Application number	US-201816606100-A
Country	US
Kind code	B2
Filing date	Apr 16, 2018
Priority date	Apr 27, 2017
Publication date	Nov 30, 2021
Grant date	Nov 30, 2021

Abstract

There is provided an organic EL element having high efficiency and high driving stability despite having a low driving voltage. An organic electroluminescent element has a light-emitting layer between an anode and a cathode which face each other, and the light-emitting layer contains a first host selected from among indolocarbazole compounds represented by formula (1), a second host selected from among biscarbazole compounds represented by formula (2), and a light-emitting dopant material:

First claim

The invention claimed is:

1. An organic electroluminescent element comprising one or more light-emitting layers between an anode and a cathode which face each other, wherein at least one light-emitting layer contains a first host selected from among compounds represented by the following formula (1), a second host selected from among compounds represented by the following formula (2), and a light-emitting dopant material,

wherein, the ring A is an aromatic hydrocarbon ring represented by formula (1a), the ring B is a heterocycle represented by formula (1b), and the ring A and the ring B are each fused to an adjacent ring at any position,
Ar 1 represents a phenyl group, a biphenyl group or a terphenyl group,
R each independently represents an aliphatic hydrocarbon group having 1 to 10 carbon atoms, an aromatic hydrocarbon group having 6 to 10 carbon atoms, or an aromatic heterocyclic group having 3 to 12 carbon atoms,
a, b, and c each independently represent an integer of 0 to 3, and
m and n each independently represent an integer of 0 to 2, wherein when AO is a phenyl group, m+n is an integer of 1 to 4;

wherein, Ar 2 and Ar 3 represent a hydrogen atom, an aromatic hydrocarbon group having 6 to 14 carbon atoms, or a group in which two of the aromatic hydrocarbon groups are linked to each other, and the aromatic hydrocarbon groups to be linked to each other may be the same as or different from each other, with the proviso that Ar 2 and Ar 3 are not both a hydrogen atom, and L 1 and L 2 represent an m-phenylene group or a p-phenylene group.

2. The organic electroluminescent element according to claim 1 ,
wherein, in formula (2), Ar 2 represents a hydrogen atom or a phenyl group, and AO represents a phenyl group.

3. The organic electroluminescent element according to claim 1 ,
wherein the compound represented by formula (2) is a compound represented by any of the following formulae (3) to (5):

4. The organic electroluminescent element according to claim 3 ,
wherein the compound represented by formula (2) is a compound represented by formula (4).

5. The organic electroluminescent element according to claim 3 ,
wherein the compound represented by formula (2) is a compound represented by formula (5).

6. The organic electroluminescent element according to claim 1 ,
wherein the compound represented by formula (1) is a compound represented by any of formulae (6) to (11):

wherein, Ar 1 , R, a to c, m, and n have the same meaning as in formula (1).

7. The organic electroluminescent element according to claim 1 ,
wherein a proportion of the first host is larger than 20 wt % and less than 55 wt % with respect to a total amount of the first host and the second host.

8. The organic electroluminescent element according to claim 1 ,
wherein the light-emitting dopant material is an organic metal complex containing at least one metal selected from the group consisting of ruthenium, rhodium, palladium, silver, rhenium, osmium, iridium, platinum and gold.

9. The organic electroluminescent element according to claim 1 ,
wherein the light-emitting dopant material is a thermally activated delayed fluorescence-emitting dopant material.

10. The organic electroluminescent element according to claim 1 ,
wherein a hole blocking layer is provided adjacent to the light-emitting layer, and the hole blocking layer contains an indolocarbazole compound.

11. A method of producing an organic electroluminescent element, comprising:
a step of, when the organic electroluminescent element according to claim 1 is produced, mixing a first host and a second host to prepare a pre-mixture, and then vapor-depositing a host material containing the pre-mixture to form a light-emitting layer.

12. The method of producing an organic electroluminescent element according to claim 11 ,
wherein a difference between 50% weight reduction temperatures of the first host and the second host is within 20° C.

Assignees

• Nippon Steel Chemical & Mat Co Ltd

Inventors

• Ogawa Junya
• Tada Masashi

Classifications

• C07D209/86

  with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• C07D403/14

  containing three or more hetero rings · CPC title

• C07D487/04

  Ortho-condensed systems · CPC title

• C07D519/00

  Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00 · CPC title