Calibrating a gas sensor

Patent metadata

Field	Value
Publication number	US-11187686-B2
Application number	US-201816603363-A
Country	US
Kind code	B2
Filing date	Apr 5, 2018
Priority date	Apr 6, 2017
Publication date	Nov 30, 2021
Grant date	Nov 30, 2021

Abstract

A gas sensor includes a sensing element of a material including metal oxide and is sensitive to a target gas and to a recalibration gas different from the target gas. For recalibrating the gas sensor, a resistance of the sensing element is measured as an updated recalibration gas baseline resistance in a recalibration environment showing a recalibration gas baseline concentration.

First claim

The invention claimed is:

1. Method for operating a gas sensor comprising a sensing element of a material including metal oxide and being sensitive to a target gas and to a recalibration gas different from the target gas, the method comprising the step of:
recalibrating the gas sensor in a recalibration environment showing a recalibration gas baseline concentration

wherein
the material of the sensing element is such that
for a target gas concentration in a target range a sensor response of the sensing element exceeds its sensor response for a recalibration gas concentration in a baseline range, and
for a target gas concentration in a baseline range the sensor response of the sensing element is less than its sensor response for a recalibration gas concentration in the baseline range.

2. Method according to claim 1 , wherein the recalibration gas is one of hydrogen or methane.

3. Method according to claim 1 ,
wherein the gas sensor is arranged in or at a housing,
wherein the recalibration gas is a background gas present in the housing.

4. Method according to claim 3 wherein at least one of:
the housing is a housing of a device, and wherein the recalibration gas is a background gas present in the housing of the device,
the housing is a housing of the gas sensor, and wherein the recalibration gas is a background gas present in the housing of the gas sensor.

5. Method according to claim 1 comprising the steps of:
for identifying a concentration of the target gas in an environment of the gas sensor: measuring a resistance of the sensing element, and determining the concentration of the target gas dependent on the measured resistance and dependent on an initial recalibration gas baseline resistance value,
for recalibrating the gas sensor: measuring a recalibration gas baseline resistance of the sensing element in the recalibration environment,
for identifying a concentration of the target gas in an environment of the gas sensor subsequent to recalibrating the gas sensor measuring a resistance of the sensing element, and determining the concentration of the target gas dependent on the measured resistance and dependent on the recalibration gas baseline resistance.

6. Method according to claim 5 ,
wherein the measured recalibration gas baseline resistance is stored in one of:
a memory of a semiconductor chip including the sensing element;
a memory of a microprocessor implemented in a semiconductor chip separate from a semiconductor chip including the sensing element;
a memory provided in a device comprising the gas sensor;
a memory remote from the gas sensor.

7. Method according to claim 1 , comprising
automatically detecting when the gas sensor is exposed to an environment qualifying as recalibration environment, and
in response to detecting the exposure of the gas sensor to an environment qualifying as recalibration environment triggering the recalibrating step.

8. Method according to claim 7 ,
wherein the exposure of the gas sensor to an environment qualifying as recalibration environment is detected dependent on one or more of:
a signal of a sensor sensitive to ozone,
on a signal of a sensor sensitive to humidity, and
on a signal of a sensor insensitive to a gas concentration.

9. Method according to claim 7 ,
wherein the exposure of the gas sensor to an environment qualifying as recalibration environment is detected dependent on one or more of:
a signal of a sensor sensitive to hydrogen, and
a signal of a sensor sensitive to methane.

10. Method according to claim 7 ,
wherein the exposure of the gas sensor to an environment qualifying as recalibration environment is detected dependent on one or more of:
a signal of a sensor sensitive to ozone,
wherein the sensor sensitive to ozone is represented by another sensing element of the gas sensor,
wherein the exposure of the gas sensor to the environment qualifying as recalibration environment is detected dependent on one or more of the signal of the ozone sensor indicating an ozone concentration exceeding a threshold, or the signal of the ozone sensor indicating an increase in ozone concentration the increase exceeding a threshold,
on a signal of a sensor sensitive to humidity,
wherein the sensor sensitive to humidity is represented by another sensing element of the gas sensor
wherein the exposure of the gas sensor to the environment qualifying as recalibration environment is detected dependent on one or more of an absolute humidity derived from the signal of the humidity sensor falling below a threshold, or a decrease in absolute humidity derived from the signal of the humidity sensor the decrease exceeding a threshold, and
on a signal of a sensor insensitive to a gas concentration,
wherein the sensor includes one of a GPS sensor, a light sensor,
wherein the exposure of the gas sensor to the environment qualifying as recalibration environment is detected dependent on the signal of the GPS sensor detecting an outdoor location.

11. Method according to claim 7 ,
wherein the exposure of the gas sensor to an environment qualifying as recalibration environment is detected dependent on one or more of:
a signal of a sensor sensitive to hydrogen,
wherein the sensor sensitive to hydrogen is represented by another sensing element of the gas sensor,
wherein the exposure of the gas sensor to the environment qualifying as recalibration environment is detected dependent on one or more of the signal of the hydrogen sensor indicating a hydrogen concentration below a threshold, or the signal of the hydrogen sensor indicating a decrease in hydrogen concentration the decrease rate exceeding a threshold, and

a signal of a sensor sensitive to methane,
wherein the sensor sensitive to methane is represented by another sensing element of the gas sensor,
wherein the exposure of the gas sensor to the environment qualifying as recalibration environment is detected dependent on one or more of the signal of the methane sensor indicating a methane concentration below a threshold, or the signal of the methane sensor indicating a decrease in methane concentration the decrease rate exceeding a threshold.

12. Method according to claim 1 , comprising
determining a calibration characteristic of the gas sensor, and
determining a reference concentration of the target gas in an environment showing the recalibration gas baseline concentration (c BaseRG ) resulting in the initial recalibration gas baseline resistance value.

13. Method according to claim 1 ,
wherein in the recalibrating step, a resistance value is selected as recalibration gas baseline resistance out of a set of resistances measured in the past.

14. Method according to claim 13 ,
wherein for a first class of target gases the resistance of the sensing element decreases at increasing concentration (c) of the target gas,
wherein the selected resistance is the resistance showing a maximum value out of the resistances of the set.

15. Method according to claim 14 ,
wherein for a second class of target gases the resistance of the sensing element increases at increasing concentration of the target gas and the selected resistance is the resistance showing a minimum value out of the resistances of the set.

16. Method according to claim 13 , wherein the set of resistances measured in the past is limited to resistances measured since the most recent recalibration respectively, and the set of resistances represents a subset of resistances measured since the most recent recalibration.

17. Method according to claim 1 , wherein the re

Assignees

• Sensirion Ag

Inventors

• Egli Daniel
• Schoch Tobias
• Hoehne Felix

Classifications

• G01N33/0006 Primary

  Calibrating gas analysers · CPC title

• G01N27/403

  Cells and electrode assemblies · CPC title

• G01N33/0027

  concerning the detector · CPC title

• G01N27/04

  by investigating resistance · CPC title