Electrode production method by binder fibrillation using a particulate fibrillation auxiliary agent

Patent metadata

Field	Value
Publication number	US-11183675-B2
Application number	US-201816635829-A
Country	US
Kind code	B2
Filing date	Jul 30, 2018
Priority date	Aug 2, 2017
Publication date	Nov 23, 2021
Grant date	Nov 23, 2021

Abstract

The invention relates to a method for producing an electrode (E) for an electrochemical cell, in particular for a lithium cell. In order to produce a homogeneous mixture allowing the time-saving, cost-effective production, for example by dry coating, of an electrode (E) with improved properties and/or with a layer thickness significantly greater than 100 μm, for example for vehicle batteries, in particular for electric and/or hybrid vehicles, in said method at least one binder (B) and at least one particulate fibrillation auxiliary agent (F) are mixed in a mixing process with a high shear load, the at least one binder (B) being fibrillated (fB), and at least one electrode component (E1) is then added to the at least one fibrillated binder (B) in a mixing process with a low shear load. The invention also relates to an electrode (E) produced in this manner and to an electrochemical cell equipped with an electrode (E) of this type.

First claim

The invention claimed is:

1. A process for producing an electrode for an electrochemical cell, in particular for a battery cell, for example for a lithium cell, wherein
mixing at least one binder and at least one particulate fibrillation aid by a high-shear mixing procedure, wherein the at least one binder is fibrillated, and
admixing at least one electrode component with the at least one fibrillated binder by a low-shear mixing procedure.

2. The process of claim 1 , wherein the high-shear mixing procedure is carried out by a jet mill.

3. The process of claim 1 , wherein, after the fibrillation of the at least one binder, at least the major part of the at least one particulate fibrillation aid, in particular more than 50% thereof, is removed.

4. The process of claim 1 , wherein the at least one binder and the at least one particulate fibrillation aid, and/or the procedure conditions, in particular the procedure temperature, of the high-shear mixing procedure are selected in a manner that minimizes the adhesion between the at least one fibrillated binder and the at least one fibrillation aid.

5. The process of claim 1 , wherein the at least one particulate fibrillation aid is removed before the at least one electrode component is admixed.

6. The process of claim 5 , wherein,
after the fibrillation of the at least one binder, a mixture comprising the at least one fibrillated binder and the at least one fibrillation aid is subjected to a comminution procedure, in particular chopping procedure, wherein fibrils of the at least one fibrillated binder are comminuted to give shorter fibril sections, and the shorter fibril sections of the at least one fibrillated binder and the at least one particulate fibrillation aid are subjected to a separation procedure, in particular gas-jet separation, and/or to a sieving procedure, wherein the at least one fibrillation aid and the fibril sections of the at least one fibrillated binder are separated from one another,
in particular wherein the at least one electrode component is admixed with the fibril sections of the at least one fibrillated binder by the low-shear mixing procedure.

7. The process according to claim 1 , wherein the at least one particulate fibrillation aid is removed after or before the at least one electrode component is admixed, in particular after the at least one electrode component is admixed.

8. The process of claim 7 , wherein, in particular after the at least one electrode component (El) is admixed, the at least one particulate fibrillation aid (F) is removed thermally and/or by means of vaporization and/or by means of decomposition and/or by means of gasification and/or by means of combustion and/or by means of solvent extraction.

9. The process of claim 1 , wherein, after the at least one electrode component is admixed, the at least one particulate fibrillation aid remains in a mixture comprising the at least one fibrillated binder and the at least one electrode component.

10. The process of claim 9 , wherein the at least one particulate fibrillation aid comprises, at least one electrode additive which does not participate in the electrochemical reaction of the cell and which is intended to intercept side-reactions and/or to scavenge side-reaction products and/or to improve the mechanical stability and/or processability of the electrode, and/or the at least one particulate fibrillation aid comprises, at least one further electrode component which participates in the electrochemical reaction of the cell.

11. The process of claim 1 , wherein the at least one particulate fibrillation aid comprises at least one inorganic material, in particular at least one ceramic and/or glassy material and/or at least one metal and/or at least one metal alloy and/or at least one polymer and/or copolymer and/or at least one pore-former and/or at least one solvent, in particular at least one electrolyte solvent, in particular in solid form.

12. The process of claim 1 , wherein the at least one binder comprises at least one, in particular lithium-ion-conductive or lithium-ion-conducting, polymer, in particular at least one polyalkylene oxide, for example polyethylene oxide, and/or at least one polyester and/or at least one polyacrylate and/or at least one polymethacrylate, for example polymethyl methacrylate, and/or at least one polyacrylonitrile, and/or one copolymer thereof, and/or at least one, in particular non-lithium-ion-conductive or non-lithium-ion-conducting, polymer, in particular at least one fluorinated and/or unfluorinated polyolefin, for example polyvinylidene difluoride and/or polytetrafluoroethylene and/or polyethylene and/or polypropylene, and/or polystyrene, and/or a copolymer thereof, for example polyethylene oxide-polystyrene copolymer and/or acrylonitrile-butadiene-styrene copolymer.

13. The process of claim 1 , wherein:
the at least one binder comprises at least one, in particular non-lithium-ion-conductive or non-lithium-ion-conducting, polymer and/or copolymer, in particular at least one fluorinated or unfluorinated polyolefin, for example polyvinylidene difluoride, and/or copolymer thereof, and/or
the at least one particulate fibrillation aid comprises at least one, in particular lithium-ion-conductive or lithium-ion-conducting polymer and/or a copolymer thereof, in particular at least one polyalkylene oxide, for example polyethylene oxide, and/or a copolymer thereof, and/or
the at least one binder comprises at least one, in particular lithium-ion-conductive or lithium-ion-conducting, polymer and/or a copolymer thereof, in particular at least one polyalkylene oxide, for example polyethylene oxide, and/or a copolymer thereof, and/or the at least one particulate fibrillation aid comprises at least one, in particular non-lithium-ion-conductive or non-lithium-ion-conducting, polymer and/or copolymer, in particular at least one fluorinated or unfluorinated polyolefin, for example polyvinylidene difluoride, and/or copolymer thereof.

14. The claim 1 , wherein the at least one electrode component comprises surface-coated particles and/or gradient-material particles and/or at least one electrode active material, in particular intercalation material and/or insertion material and/or recombination material, and/or at least one conductivity additive.

15. The process of claim 1 , wherein, in a low-shear premixing procedure upstream of the high-shear mixing procedure, the at least one binder and the at least one particulate fibrillation aid are mixed to give a premixture that is then mixed in the high-shear mixing procedure to fibrillate the at least one binder.

16. The process of claim 1 , wherein the low-shear mixing procedure and/or the low-shear premixing procedure is/are carried out with low shear by a gravity mixer and/or by a mixer based on the turbulence principle and/or by a kneader and/or by an extruder and/or by a ploughshare mixer and/or paddle mixer and/or by a drum mixer.

17. The process of claim 1 , wherein an electrode is configured from a mixture which comprises the at least one fibrillated binder and the at least one electrode component (E 1 ), in particular by a dry production procedure and/or by a coating, for example by dry coating.

18. Electrode, in particular anode or cathode, produced by the process of claim 1 .

19. Electrochemical cell, in particular a battery cell, for example a lithium cell, comprising at least one electrode of claim 18 .

Assignees

• Bosch Gmbh Robert
• Gs Yuasa Int Ltd

Inventors

• Reinsch Bernd
• Glanz Leonore
• Wurm Calin Iulius
• Bauer Harald
• Weydanz Wolfgang

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/04 Primary

  Processes of manufacture in general · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/139

  Processes of manufacture · CPC title