Thermally and/or electrically conductive materials and method for the production thereof

Patent metadata

Field	Value
Publication number	US-11180625-B2
Application number	US-201615566238-A
Country	US
Kind code	B2
Filing date	Apr 7, 2016
Priority date	Apr 13, 2015
Publication date	Nov 23, 2021
Grant date	Nov 23, 2021

Abstract

Porous polymeric materials having a very high content of thermally conductive and/or electrically conductive fillers. Process for the preparation of the porous composite material including at least one binder-forming polymeric phase and one or more fillers, this process including the stages of hot mixing, by the molten route, the polymeric phase, the fillers and a sacrificial polymeric phase, so as to obtain a mixture, of shaping the mixture and of removing the sacrificial polymeric phase.

First claim

The invention claimed is:

1. A process for the preparation of a porous composite material comprising at least:
(A) a binder-forming polymeric phase based on at least one polymer selected from the group consisting of thermoplastics, elastomers, and thermoplastic elastomers, wherein the elastomers and/or the thermoplastic elastomers represent at least 95% by weight of the polymers of the binder-forming polymeric phase, and
(B) one or more fillers consisting essentially of thermally conductive fillers exhibiting a thermal conductivity of greater than or equal to 5 W/mK and electrically conductive fillers exhibiting a resistivity of less than or equal to 0 . 1 ohm.cm,
the fillers (B) representing at least 75% by weight, with respect to the sum of the weights of the polymeric phase (A) and of the fillers (B), this process comprising the following stages:
a) hot mixing, by the molten route, the polymeric phase (A), the fillers (B) and a sacrificial polymeric phase (C), so as to obtain a mixture,
b) shaping the mixture,
c) removing the sacrificial polymeric phase,

and the sacrificial polymeric phase (C) represents at least 15% by weight of the total weight of the mixture of stage a),
the porous composite material comprising, by weight, with respect to the total weight of the material, from 0% to 5% of one or more decomposition residues from the sacrificial phase.

2. The process as claimed in claim 1 , wherein the fillers (B) represent at least 80%, by weight, with respect to the sum of the weights of the polymeric phase (A) and of the fillers (B).

3. The process as claimed in claim 1 , wherein the sacrificial polymeric phase (C) represents from 20% to 80% by weight of the total weight of the mixture of stage a).

4. The process as claimed in claim 1 , wherein stage a) is carried out in an internal mixer or in an extruder.

5. The process as claimed in claim 1 , wherein stage c) is carried out by decomposition by the thermal route of the sacrificial polymeric phase.

6. The process as claimed in claim 1 , wherein the binder-forming polymeric phase is based on at least one polymer selected from the group consisting of polyacrylonitrile, halogenated polymers, acrylic polymers, acrylates, methacrylates, polyethers, polyamides, hydrogenated acrylonitrile/butadiene, copolymers of ethylene and of an alkyl acrylate, polyisoprene or rubbers.

7. The process as claimed in claim 1 , wherein the fillers are selected from the group consisting of aluminum nitride, boron nitride, magnesium silicon nitride, silicon carbide, diamond, and their mixtures.

8. The process as claimed in claim 1 , wherein the fillers are selected from the group consisting of graphite, graphene, carbon nanotubes (CNTs), carbon black, metal fillers, and their mixtures.

9. The process as claimed in claim 1 , wherein stage b) comprises a fashioning in the film form.

10. The process as claimed in claim 1 , wherein it additionally comprises, on conclusion of stage c), a compression stage d).

11. The process as claimed in claim 1 , wherein it results in a material that exhibits the following composition, by weight, with respect to the total weight of the material:
from 3% to 25% of a binder-forming polymeric phase selected from the group consisting of thermoplastic polymers, elastomers, and thermoplastic elastomers, wherein the elastomers and the thermoplastic elastomers represent at least 95% by weight of the polymers of the binder-forming polymeric phase,
from 75% to 97% of at least one filler selected from the group consisting of thermally conductive fillers exhibiting a thermal conductivity of greater than or equal to 5 W/mK and electrically conductive fillers exhibiting a resistivity of less than or equal to 0.1 ohm.cm,
from 0% to 5% of one or more additives or decomposition residues from the sacrificial phase.

12. A porous composite material capable of being obtained by the process as claimed in claim 1 , wherein it exhibits the following composition, by weight, with respect to the total weight of the material:
from 3% to 25% of at least one polymer selected from the group consisting of thermoplastic polymers, elastomers, and thermoplastic elastomers,
from 75% to 97% of at least one filler selected from the group consisting of thermally conductive fillers exhibiting a thermal conductivity of greater than or equal to 5 W/mK and electrically conductive fillers exhibiting a resistivity of less than or equal to 0.1 ohm.cm,
from 0% to 5% of one or more additives or decomposition residues from the sacrificial phase.

13. The process as claimed in claim 1 , wherein the binder-forming polymeric phase (A) comprises at least 50% by weight of at least one polymer selected from the group consisting of polyacrylonitrile, hydrogenated acrylonitrile/butadiene, and their mixtures.

14. The process as claimed in claim 1 , wherein the binder-forming polymeric phase (A) consists essentially of at least one polymer selected from the group consisting of polyacrylonitrile, hydrogenated acrylonitrile/butadiene, and their mixtures.

15. A process for the manufacture of a thermally conductive and/or electrically conductive porous carbon-based material, this process comprising the implementation of the process as claimed in claim 1 and additionally comprising, on conclusion of this process, at least one stage d′) of pyrolysis or of graphitization.

16. The process as claimed in claim 5 , wherein the sacrificial polymeric phase is based on at least one polymer selected from the group consisting of polyalkene carbonates.

17. The process as claimed in claim 16 , wherein the sacrificial polymeric phase is based on at least one polymer selected from the group consisting of polyethylene carbonates and polypropylene carbonates.

18. The process as claimed in claim 10 , wherein it results in a material comprising a polymeric matrix, based on polymer selected from the group consisting of thermoplastic polymers, elastomers, and thermoplastic elastomers, comprising at least 95% by weight of elastomers and/or thermoplastic elastomers, and thermally conductive fillers and exhibiting a thermal conductivity in at least one direction of greater than or equal to 15 W/m.K.

19. A material capable of being obtained by the process as claimed in claim 10 , comprising a polymeric matrix, based on polymer selected from the group consisting of thermoplastic polymers, elastomers, and thermoplastic elastomers, and thermally conductive fillers and exhibiting a thermal conductivity in at least one direction of greater than or equal to 15 W/m.K.

20. The process as claimed in claim 11 , wherein it results in a porous composite material selected from the group consisting of a self-supported material and a coating with a thickness of greater than or equal to 250 μm.

21. The porous composite material as claimed in claim 12 , wherein it is selected from the group consisting of a self-supported material and a coating with a thickness of greater than or equal to 250 μm.

Assignees

• Hutchinson

Inventors

• Prebe Arnaud
• Dufour Bruno
• Ayme-Perrot David
• Bureau Yannick
• Sonntag Philippe

Classifications

• C08J9/26 Primary

  by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out · CPC title

• C08J2433/20

  Homopolymers or copolymers of acrylonitrile (C08J2455/02 takes precedence) · CPC title

• C09K5/14

  Solid materials, e.g. powdery or granular · CPC title

• C08J9/0066

  Use of inorganic compounding ingredients · CPC title

• B29K2033/20

  PAN, i.e. polyacrylonitrile · CPC title