Additive manufacturing

Patent metadata

Field	Value
Publication number	US-11179887-B2
Application number	US-201916405756-A
Country	US
Kind code	B2
Filing date	May 7, 2019
Priority date	Nov 7, 2016
Publication date	Nov 23, 2021
Grant date	Nov 23, 2021

Abstract

A method ( 300 ) of fabricating an object by additive manufacturing comprises providing ( 310 ) a layer of polymeric material ( 100 ), said polymeric material ( 100 ) being in particulate form, and comprising linear polymer chains, selectively depositing ( 320 ) a reactive liquid ( 200 ) onto the layer of particulate polymeric material ( 100 ), said reactive liquid ( 200 ) comprising reactive units ( 210 a ) which are monomeric units, linear oligomeric units, linear polymeric units, or combinations thereof, wherein said reactive units ( 210 a ) have two or fewer reactive groups, and allowing ( 330 ) linear polymeric chains in said layer of polymeric material ( 100 ) to react with reactive units in said reactive liquid ( 200 ) so as to form extended polymeric chains that are linear, so as to provide a shaped layer of linear polymer. These steps ( 310, 320, 330 ) are repeated as required to form the object from successive shaped layers of linear polymer.

First claim

The invention claimed is:

1. A method of fabricating an object by additive manufacturing, the method comprising:
a) providing a layer of polymeric material, said polymeric material being in particulate form, and comprising linear polymer chains,
b) selectively depositing a reactive liquid onto the layer of particulate polymeric material, said reactive liquid comprising reactive units which are monomeric units, linear oligomeric units, linear polymeric units, or combinations thereof, wherein said reactive units have two or fewer reactive groups,
c) allowing linear polymeric chains in said layer of polymeric material to react with reactive units in said reactive liquid so as to form extended polymeric chains that are linear, so as to provide a shaped layer of linear polymer, and
d) repeating steps a) to c) as required to form the object from successive shaped layers of linear polymer.

2. The method of claim 1 , wherein the monomeric units and/or linear oligomeric units, and/or linear polymeric units that are provided as reactive units in step b) are bi-functional.

3. The method of claim 1 , wherein the reactive liquid comprises reactive units which are monomeric units.

4. The method of claim 1 , wherein the particulate polymeric material provided in step a) and the shaped layer of linear polymer obtained in step c) are both formed from the same type of polymer.

5. The method of claim 1 , wherein the reactive liquid comprises monomeric units and/or oligomeric units based on the same monomer type or the same repeating unit type or the same linking group type as the linear polymer chains that are in the particulate polymeric material.

6. The method of claim 1 , wherein
a) the linear polymeric chains have reactive functional groups available which are hydroxyl groups or amino groups, and the reactive units in the reactive liquid have reactive functional groups available that can react with hydroxyl groups or amino groups respectively; or
b) the reactive units in the reactive liquid have reactive functional groups available which are hydroxyl groups or amino groups, and the linear polymeric chains have reactive functional groups available that can react with hydroxyl groups or amino groups respectively.

7. The method of claim 1 , wherein the particulate polymeric material is a thermoplastic polymeric material.

8. The method of claim 1 , in which the particulate polymeric material comprises at least one of the following polymer types: (i) polyurethane; (ii) polyurea; (iii) polycarbonate; (iv) polyamide; (v) polyester; and (vi) polyether.

9. The method of claim 8 , in which the particulate polymeric material comprises at least one of the following polymer types: (i) polyurethane; and (ii) polyurea.

10. The method of claim 1 , in which the reactive liquid and the particulate polymeric material undergo linear polymerisation when in contact at room temperature and pressure.

11. The method of claim 1 , wherein two or more reactive liquids are used.

12. The method of claim 1 , comprising selectively depositing the liquid in a pattern corresponding to a cross-section of the object to be fabricated and repeating steps a) to c) to form the object from successive shaped layers of linear polymer.

13. The method of claim 1 , in which the monomeric units and/or oligomeric units in the reactive liquid react with each other, in addition to reacting with polymeric chains in the particulate polymeric material.

14. The method of claim 1 , in which the method is performed without any crosslinking agent or provision of a curing light source, such as a UV or infra-red light source.

15. A kit of parts for use in fabricating an object by additive manufacturing, the kit of parts comprising:
polymeric material, said polymeric material being in particulate foul“, and comprising linear polymer chains,
reactive liquid comprising reactive units which are monomeric units, linear oligomeric units, linear polymeric units, or combinations thereof, wherein said reactive units have two or fewer reactive groups, wherein linear polymeric chains in said layer of polymeric material are able to react with reactive units in said reactive liquid so as to form extended polymeric chains that are linear, so as to provide a shaped layer of linear polymer.

16. The kit of parts of claim 15 , in which at least one of the particulate polymeric material and the reactive liquid is provided in a container suitable for insertion into a user's additive manufacturing apparatus.

17. An apparatus for fabricating an object by additive manufacturing, the apparatus comprising:
a bed arranged to contain polymeric material, said polymeric material being in particulate form, and comprising linear polymer chains;
a powder supply containing the particulate polymeric material and arranged to provide the particulate polymeric material to the bed;
a liquid supply containing reactive liquid comprising reactive units which are monomeric units, linear oligomeric units, linear polymeric units, or combinations thereof, wherein said reactive units have two or fewer reactive groups; and
printing architecture arranged to selectively deposit reactive liquid onto the particulate polymeric material, wherein linear polymeric chains in said layer of polymeric material are able to react with reactive units in said reactive liquid so as to form extended polymeric chains that are linear, so as to provide a shaped layer of linear polymer.

18. The apparatus of claim 17 , comprising one or more additional liquid supplies, each containing a reactive liquid which can react with the particulate polymeric material so as to form a linear polymer with one or more properties different from that of the linear polymer formed by reaction of the particulate polymeric material with the reactive liquid in the first liquid supply.

19. A method of using an additive manufacturing machine that comprises the apparatus of claim 17 , and an energy source arranged to cure an object being fabricated, the method comprising:
putting polymeric material, said polymeric material being in particulate form, and comprising linear polymer chains, into the powder supply;
putting reactive liquid comprising reactive units which are monomeric units, linear oligomeric units, linear polymeric units, or combinations thereof, wherein said reactive units have two or fewer reactive groups, into the liquid supply; and
causing the printing architecture to selectively deposit the reactive liquid on the particulate polymeric material to form a linear polymer by reaction between the reactive liquid and the polymeric material,
without using the energy source, wherein linear polymeric chains in said layer of polymeric material are able to react with reactive units in said reactive liquid so as to form extended polymeric chains that are linear, so as to provide a shaped layer of linear polymer.

20. A 3D polymeric object, the object being obtainable by the method of claim 1 .

Assignees

• Univ Nottingham

Inventors

• Tuck Christopher John
• Begines Ruiz Belén
• He Yinfeng
• Wildman Ricky Darren
• Hague Richard James Mackenzie

Classifications

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B33Y30/00

  Apparatus for additive manufacturing; Details thereof or accessories therefor · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B29K2075/00

  Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title

• B29C64/20

  Apparatus for additive manufacturing; Details thereof or accessories therefor · CPC title