Carbon black pellets bound by functional polymer

Patent metadata

Field	Value
Publication number	US-11174367-B2
Application number	US-202016794474-A
Country	US
Kind code	B2
Filing date	Feb 19, 2020
Priority date	Sep 23, 2014
Publication date	Nov 16, 2021
Grant date	Nov 16, 2021

Abstract

A carbon black pellet comprising a plurality of agglomerates, aggregates, or primary carbon black particles and a binder including a functional polymer.

First claim

What is claimed is:

1. A carbon black pellet comprising:
(i) a plurality of carbon black agglomerates, carbon black aggregates, or primary carbon black particles; and
(ii) a binder including a functional polymer,

where the carbon black pellet has an average particle size of from about 125 to about 2250 microns, wherein the functional polymer is a copolymer deriving from the polymerization of butadiene monomer, styrene monomer, and at least one functional monomer, and wherein the copolymer includes:
(a) from about 2 to about 30 percent by weight polymeric units deriving from the polymerization of styrene,
(b) from about 2 to about 70 percent by weight polymeric units deriving from the polymerization of butadiene, and
(c) from about 20 to about 99 percent by weight polymeric units deriving from the polymerization of the at least one functional monomer.

2. The carbon black pellet of claim 1 , where the binder forms a matrix in which the agglomerates, aggregates, or primary carbon black particles are dispersed.

3. The carbon black pellet of claim 2 , where the carbon black pellet includes from about 1 to about 35 weight percent binder, based upon the entire weight of the carbon black pellet.

4. The carbon black pellet of claim 1 , where the functional polymer is emulsion polymerized at temperatures above 40° C.

5. The carbon black pellet of claim 1 , where the functional polymer includes a functional group selected from the group consisting of hydroxyl, carbonyl, ether, ester, halide, amine, imine, amide, nitrile, and oxirane groups.

6. The carbon black pellet of claim 1 , where the functional polymer is an acrylate-containing copolymer.

7. The carbon black pellet of claim 1 , where the functional polymer is a nitrile-containing copolymer.

8. The carbon black pellet of claim 1 , where the functional polymer is a styrene-butadiene-based functional polymer including one or more functional groups.

9. A plurality of the carbon black pellets of claim 1 , where the plurality of carbon black pellets are free-flowing pellets.

10. The carbon black pellet of claim 1 , where the at least one functional monomer is selected from the group consisting of acid-bearing monomers, amides of ethylenically unsaturated carboxylic acids, esters of ethylenically unsaturated carboxylic acids, and nitriles of ethylenically unsaturated carboxylic acids.

11. The carbon black pellet of claim 1 , where the functional polymer has a glass transition temperature of from −50 to 15° C.

12. A process for making carbon black pellets, the process comprising:
(i) introducing a plurality of carbon black agglomerates, carbon black aggregates, or primary carbon black particles to a latex containing a functional polymer, wherein the functional polymer is a copolymer deriving from the polymerization of butadiene monomer, styrene monomer, and at least one function monomer to form a mixture, wherein the copolymer includes:
a) from about 2 to about 30 percent by weight polymeric units deriving from the polymerization of styrene,
b) from about 2 to about 70 percent by weight polymeric units deriving from the polymerization of butadiene, and
c) from about 20 to about 99 percent by weight polymeric units deriving from the polymerization of the at least one functional monomer; and

(ii) densifying the mixture to form the carbon black pellets.

13. The process of claim 12 , where the plurality of carbon black agglomerates, carbon black aggregates, or primary carbon black particles are introduced to the latex as a slurry.

14. A plurality of the carbon black pellets of claim 12 , where the plurality of carbon black pellets are free-flowing pellets.

15. The process of claim 12 , wherein the at least one functional monomer is selected from the group consisting of acid-bearing monomers, amides of ethylenically unsaturated carboxylic acids, esters of ethylenically unsaturated carboxylic acids, and nitriles of ethylenically unsaturated carboxylic acids.

Assignees

• Bridgestone Bandag Llc

Inventors

• Bender David L

Classifications

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C01P2006/33

  Phase transition temperatures · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2004/50

  Agglomerated particles · CPC title

• C09C1/58

  Agglomerating, pelleting, or the like by wet methods · CPC title