Pellet of liquid crystal polyester resin composition and method of producing pellet of liquid crystal polyester resin composition

Patent metadata

Field	Value
Publication number	US-11174342-B2
Application number	US-202016818757-A
Country	US
Kind code	B2
Filing date	Mar 13, 2020
Priority date	May 17, 2019
Publication date	Nov 16, 2021
Grant date	Nov 16, 2021

Abstract

The present invention relates to a pellet of a liquid crystal polyester resin composition, including a liquid crystal polyester resin (A) and an inorganic filler (B), in which the pellet has voids with a sphere equivalent diameter of 10 μm to 1000 μm, an abundance ratio of voids having a sphere equivalent diameter of less than 400 μm in a total amount of the voids is in a range of 40% to 90%, and an average number of the voids in one pellet having a length of 1 mm to 5 mm and a maximum diameter of 1 mm to 3 mm is in a range of 4 to 9.

First claim

What is claimed is:

1. A pellet of a liquid crystal polyester resin composition, comprising:
a liquid crystal polyester resin (A); and
an inorganic filler (B),
wherein the pellet has voids with a sphere equivalent diameter of 10 μm to 1000 μm,
an abundance ratio of voids having a sphere equivalent diameter of less than 400 μm in a total amount of the voids is in a range of 40% to 90%, and
an average number of the voids in one pellet having a length of 1 mm to 5 mm and a maximum diameter of 1 mm to 3 mm is in a range of 4 to 9.

2. The pellet according to claim 1 ,
wherein D50 of a sphere equivalent diameter of the voids in the pellet is in a range of 200 μm to 500 μm.

3. The pellet according to claim 1 ,
wherein an average volume ratio of one void in one pellet is in a range of 0.040% to 0.12%.

4. The pellet according to claim 1 ,
wherein the abundance ratio of voids having a sphere equivalent diameter of less than 400 μm in the total amount of the voids is in a range of 70% to 90%.

5. The pellet according to claim 1 ,
wherein the inorganic filler (B) is at least one inorganic filler selected from the group consisting of chopped glass fibers, milled glass fibers, talc, and mica.

6. The pellet according to claim 1 ,
wherein the liquid crystal polyester resin (A) has a repeating unit represented by Formula (1) shown below:
—O—Ar 1 —CO—  (1)

in which Ar 1 represents a phenylene group, a naphthylene group, or a biphenylylene group, the hydrogen atoms in the group represented by Ar 1 may each independently be substituted with a halogen atom, an alkyl group, or an aryl group.

7. The pellet according to claim 6 ,
wherein the liquid crystal polyester resin (A) further has a repeating unit represented by Formula (2) shown below, and a repeating unit represented by Formula (3) shown below:
—CO—Ar 2 —CO—  (2)

—X—Ar 3 —Y—  (3)

in which Ar 2 and Ar 3 each independently represents a phenylene group, a naphthylene group, a biphenylylene group, or a group represented by Formula (4) shown below, X and Y each independently represents an oxygen atom or an imino group, the hydrogen atoms in the group represented by Ar 2 , or Ar 3 may each independently be substituted with a halogen atom, an alkyl group, or an aryl group:
—Ar 4 —Z—Ar 5 —  (4)

in which Ar 4 and Ar 5 each independently represents a phenylene group or a naphthylene group, Z represents an oxygen atom, a sulfur atom, a carbonyl group, a sulfonyl group, or an alkylidene group, the hydrogen atoms in the group represented by Ar 4 or Ar 5 may each independently be substituted with a halogen atom, an alkyl group having 1 to 10 carbon atoms, or an aryl group having 6 to 20 carbon atoms.

8. The pellet according to claim 6 ,
wherein a content of the liquid crystal polyester resin (A) is 50% by mass or greater and 70% by mass or less, and a content of the inorganic filler (B) is 30% by mass or greater and 50% by mass or less, with respect to the total mass of the pellets.

9. The pellet according to claim 7 ,
wherein a content of the liquid crystal polyester resin (A) is 50% by mass or greater and 70% by mass or less, and a content of the inorganic filler (B) is 30% by mass or greater and 50% by mass or less, with respect to the total mass of the pellets.

10. The pellet according to claim 7 ,
wherein D50 of a sphere equivalent diameter of the voids in the pellet is in a range of 200 μm to 500 μm.

11. The pellet according to claim 7 ,
wherein an average volume ratio of one void in one pellet is in a range of 0.040% to 0.12%.

12. The pellet according to claim 7 ,
wherein the abundance ratio of voids having a sphere equivalent diameter of less than 400 μm in the total amount of the voids is in a range of 70% to 90%.

13. The pellet according to claim 7 ,
wherein the inorganic filler (B) is at least one inorganic filler selected from the group consisting of chopped glass fibers, milled glass fibers, talc, and mica.

14. A method for producing the pellet according to claim 1 , the method comprising:
a step of melt-kneading the liquid crystal polyester resin (A) and the inorganic filler (B) using an extruder,
wherein the extruder includes a main feed port, a downstream side adjacent portion, and a first side feed port in this order toward a downstream in an extrusion direction,
the extruder supplies the liquid crystal polyester resin (A) from the main feed port and supplies the inorganic filler (B) from the first side feed port,
the downstream side adjacent portion and the first side feed port each include a heater, and
a set temperature of the heater included in the first side feed port is set to be higher than a set temperature of the heater included in the downstream side adjacent portion by 50° C. to 100° C.

15. The method according to claim 14 ,
wherein the extruder further comprises a second side feed port on the downstream side of the first side feed port in the extrusion direction,
the extruder supplies the inorganic filler (B) from the second side feed port,
the second side feed port includes a heater, and
a set temperature of the heater included in the second side feed port is set to be lower than the set temperature of the heater included in the first side feed port by 10° C. to 30° C.

Assignees

• Sumitomo Chemical Co

Inventors

• Hara Tomoyuki
• Uonami Masanobu
• Shoda Yoshio

Classifications

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• B29B9/06

  in the form of filamentary material, e.g. combined with extrusion · CPC title

• B29B11/16

  comprising fillers or reinforcement {(non-woven fabrics per se D04H1/00, D04H3/00)} · CPC title

• C08K3/34

  Silicon-containing compounds · CPC title