C3 fractionation system

Patent metadata

Field	Value
Publication number	US-11174209-B2
Application number	US-201816475288-A
Country	US
Kind code	B2
Filing date	Jan 2, 2018
Priority date	Jan 2, 2017
Publication date	Nov 16, 2021
Grant date	Nov 16, 2021

Abstract

A C3 hydrocarbon fractionation system includes: a) a unit for providing a feed containing mainly propane and propylene, b) a C3 fractionation column for separating the feed to provide a top product richer in propylene than the feed and a bottom product leaner in propylene than the feed, wherein the bottom product comprises at least 50 wt % of propylene and c) a cumene production unit comprising an alkylation reactor for producing cumene from a propylene feed and a benzene feed, wherein the propylene feed comprises the bottom product of the C3 fractionation column.

First claim

What is claimed is:

1. A C3 hydrocarbon fractionation system, comprising:
a) a unit for providing a feed comprising propane and propylene;
b) a C3 fractionation column for separating the feed to provide a top product richer in propylene than the feed and a bottom product leaner in propylene than the feed, wherein the bottom product comprises at least 50 weight % of propylene, based on a total weight of the bottom product, and an amount of propylene in the top product is at least 98 vol %, based on a total volume of the top product; and
c) a cumene production unit comprising
an alkylation reactor for producing a product stream comprising cumene from a propylene feed and a benzene feed, wherein the propylene feed comprises the bottom product of the C3 fractionation column,
a distillation train comprising a benzene column, a cumene column, and a poly-isopropylbenzene column, wherein
a product stream from the alkylation reactor is fed to the benzene column to produce a top product comprising benzene and a bottom product,
the bottom product from the benzene column is fed to the cumene column to produce a top product comprising cumene and a bottom product, and
the bottom product from the cumene column is fed to the poly-isopropylbenzene column to produce a top product comprising poly-isopropylbenzene, and

a transalkylation reactor to be fed with the top product from the poly-isopropylbenzene column and at least part of the top product from the benzene column, for producing a transalkylated product stream to be fed to the benzene column.

2. The system according to claim 1 , wherein the unit a) comprises one or more of the group consisting of a propane dehydrogenation unit, a steam cracker, and a fluid catalytic cracker.

3. The system according to claim 1 , wherein the unit a) comprises a propane dehydrogenation unit and a steam cracker.

4. The system according to claim 1 , wherein a total amount of propane and propylene in the feed is at least 95 vol %, based on a total volume of the feed.

5. The system according to claim 1 , wherein an amount of propylene in the feed is at least 85 vol %, based on a total volume of the feed.

6. The system according to claim 1 , wherein an amount of propylene in the top product of the C3 fractionation column is at least 99 vol %, based on a total volume of the top product of the C3 fractionation column.

7. The system according to claim 1 , wherein an amount of propylene in the bottom product of the C3 fractionation column is 60-90 vol %, based on a total volume of the bottom product of the C3 fractionation column.

8. The system according to claim 1 , wherein the alkylation reactor produces the product stream comprising C3 hydrocarbons, benzene, cumene, and poly-isopropylbenzene, and wherein the cumene production unit further comprises a separation unit for separating the C3 hydrocarbons from the product stream of the alkylation reactor to produce a C3 lean product stream.

9. The system according to claim 8 , wherein the C3 hydrocarbons from the separation unit are recycled back to the unit a).

10. The system according to claim 1 , wherein an amount of propylene in the bottom product of the C3 fractionation column is 70-80 vol %, based on a total volume of the bottom product of the C3 fractionation column, and an amount of propylene in the top product of the C3 fractionation column is at least 99.5 vol %, based on a total volume of the top product of the C3 fractionation column.

11. A C3 hydrocarbon fractionation system, comprising:
a) a unit for providing a feed comprising propane and propylene;
b) a C3 fractionation column for separating the feed to provide a top product richer in propylene than the feed and a bottom product leaner in propylene than the feed, wherein the bottom product comprises at least 50 weight % of propylene, based on a total weight of the bottom product; and
c) a cumene production unit comprising an alkylation reactor for producing cumene from a propylene feed and a benzene feed, wherein the propylene feed comprises the bottom product of the C3 fractionation column,
wherein the alkylation reactor produces a product stream comprising C3 hydrocarbons, benzene, cumene, and poly-isopropylbenzene, and wherein the cumene production unit further comprises a separation unit for separating the C3 hydrocarbons from the product stream to produce a C3 lean product stream,
the cumene production unit further comprises a distillation train following the separation unit, the distillation train comprising a benzene column, a cumene column, and a poly-isopropylbenzene column, wherein
the C3 lean product stream is fed to the benzene column to produce a top product comprising benzene and a bottom product,
the bottom product from the benzene column is fed to the cumene column to produce a top product comprising cumene and a bottom product, and
the bottom product from the cumene column is fed to the poly-isopropylbenzene column to produce a top product comprising poly-isopropylbenzene.

12. The system according to claim 11 ,
wherein at least part of the top product from the benzene column is recycled back to the alkylation reactor.

13. The system according to claim 11 , wherein the cumene production unit further comprises a transalkylation reactor to be fed with the top product from the poly-isopropylbenzene column and at least part of the top product from the benzene column, for producing a transalkylated product stream to be fed to the benzene column.

14. A process for C3 hydrocarbon fractionation using the system according to claim 1 , comprising the steps of: providing the feed comprising propane and propylene, separating the feed to provide the top product and the bottom product, and producing the cumene from the propylene feed and the benzene feed.

15. The process according to claim 14 , further comprising producing a product stream from the alkylation reactor comprising C3 hydrocarbons, benzene, cumene, and poly-isopropylbenzene, and producing a C3 lean product stream from a separation unit in the cumene production unit by separating the C3 hydrocarbons from the product stream in the separation unit.

16. The process according to claim 15 , further comprising recycling the C3 hydrocarbons from the separation unit to the unit providing the feed comprising the propane and the propylene.

17. The process according to claim 15 , wherein the cumene production unit further comprises a distillation train following the separation unit, the distillation train comprising a benzene column, a cumene column, and a poly-isopropylbenzene column, and wherein the process further comprises
feeding the C3 lean product stream to the benzene column to produce a top product comprising benzene and a bottom product,
feeding the bottom product from the benzene column to the cumene column to produce a top product comprising cumene and a bottom product, and
feeding the bottom product from the cumene column to the poly-isopropylbenzene column to produce a top product comprising poly-isopropylbenzene.

18. The process according to claim 17 , further comprising recycling at least part of the top product from the benzene column to the alkylation reactor.

19. The process according to claim 17 , wherein the cumene production unit further comprises a transalkylation reactor to be fed with the top product from the poly-isopropylbenzene column and at least part of the top product from the benzene column, for producing a transalkylated product stream to be fed to the benzene column.

20. A process for C3

Assignees

• Sabic Global Technologies Bv

Inventors

• Van Willigengburg Joris

Classifications

• B01J19/245

  placed in series · CPC title

• C10G2300/1092

  C2-C4 olefins · CPC title

• C07C5/327

  Formation of non-aromatic carbon-to-carbon double bonds only · CPC title

• C10G29/205

  by reaction with hydrocarbons added to the hydrocarbon oil · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title