Metal single-atom catalyst and method for preparing the same

Patent metadata

Field	Value
Publication number	US-11173481-B2
Application number	US-201916534216-A
Country	US
Kind code	B2
Filing date	Aug 7, 2019
Priority date	Jan 18, 2019
Publication date	Nov 16, 2021
Grant date	Nov 16, 2021

Abstract

Disclosed are a metal single-atom catalyst and a method for preparing the same. The method uses a minimal amount of chemicals and is thus environmentally friendly compared to conventional chemical and/or physical methods. In addition, the method enables the preparation of a single-atom catalyst in a simple and economical manner without the need for further treatment such as acid treatment or heat treatment. Furthermore, the method is universally applicable to the preparation of single-atom catalysts irrespective of the kinds of metals and supports, unlike conventional methods that suffer from very limited choices of metal materials and supports. Therefore, the method can be widely utilized to prepare various types of metal single-atom catalysts. All metal atoms in the metal single-atom catalyst can participate in catalytic reactions. This optimal atom utilization achieves maximum reactivity per unit mass and can minimize the amount of the metal used, which is very economical.

First claim

What is claimed is:

1. A method for preparing a metal single-atom catalyst, comprising:
drying a water-soluble support under vacuum;
depositing metal single atoms on the water-soluble support, wherein the depositing step is performed by sputtering;
dispersing a support in a dispersion solvent and obtaining a support-dispersed solvent;
adding the water-soluble support deposited with the metal single atoms to the support-dispersed solvent and stirring to obtain a solution containing a metal single-atom catalyst loaded on the support; and
separating the metal single-atom catalyst from the solution,
wherein a metal of the metal single atoms is gold or silver,
wherein the water-soluble support is glucosamine,
wherein the support is carbon black,
wherein the dispersion solvent is anhydrous ethanol,
wherein the sputtering is radio frequency (RF) magnetron sputtering, a sputtering working pressure is between 0.3 and 0.7 mTorr, an intensity of sputtering power is between 4 and 6 W, and a power density of the sputtering is between 0.05 and 0.5 W/cm 2 ,
wherein the depositing step by the sputtering is performed simultaneously with stirring the water-soluble support such that the metal single atoms are deposited uniformly over an entire surface of the water-soluble support,
wherein, in the separating step, the solution containing the metal single-atom catalyst loaded on the carbon support is filtered, washed with distilled water, and dried to separate the metal single-atom catalyst loaded on the support.

Assignees

• Korea Inst Sci & Tech
• Global Frontier Ct Multiscale Energy Systems

Inventors

• Yoo Sung Jong
• Jang Injoon
• Park Hee-Young
• Lee So Young
• Park Hyun Seo
• Kim Jin Young
• Jang Jong Hyun
• Kim Hyoung-Juhn

Classifications

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/34

  Mechanical properties · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title

• B01J37/344

  of electromagnetic wave energy · CPC title