Indicating the intensity of a predetermined type of radiation

Patent metadata

Field	Value
Publication number	US-11168247-B2
Application number	US-201816617617-A
Country	US
Kind code	B2
Filing date	Oct 17, 2018
Priority date	Nov 7, 2017
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

A detecting device for indicating the intensity of a predetermined type of radiation present in electromagnetic radiation incident on the detecting device can include:a filter element for filtering the incident electromagnetic radiation, wherein the filter element is configured to filter off electromagnetic radiation with a wavelength of above 590 nm from the incident electromagnetic radiation;a converging element configured to increase the density of photons of the predetermined type of radiation present in the incident electromagnetic radiation; anda sensor element of material arranged to receive the incident electromagnetic radiation that has passed through the filter element and the converging element for indicating the intensity of the predetermined type of radiation present in the incident electromagnetic radiation by change of the color of the sensor element of material, wherein the material is represented by the following formula: (M′)8(M″M′″)6O24(X,S)2:M″″ (formula (I)).

First claim

The invention claimed is:

1. A detecting device for indicating an intensity of a predetermined type of radiation present in electromagnetic radiation incident on the detecting device, wherein the detecting device comprises:
a filter element for filtering the incident electromagnetic radiation, wherein the filter element is configured to filter off electromagnetic radiation with a wavelength of above 590 nm from the incident electromagnetic radiation;
a converging element configured to increase a density of photons of the predetermined type of radiation present in the incident electromagnetic radiation; and
a sensor element comprising a material arranged to receive the incident electromagnetic radiation that has passed through the filter element and the converging element, wherein the sensor element is operable to indicate an intensity of the predetermined type of radiation present in the incident electromagnetic radiation by change of a color of the sensor element, wherein the material is represented by formula (I), comprising:
(M′) 8 (M″M′”) 6 O 24 (X,S) 2 :M′”′

wherein:
M′ represents a monoatomic cation of an alkali metal selected from Group 1 of the IUPAC periodic table of the elements, or any combination of such cations;

M″ represents a trivalent monoatomic cation of an element selected from Group 13 of the IUPAC periodic table of the elements, or of a transition element selected from any of Groups 3-12 of the IUPAC periodic table of the elements, or any combination of such cations;
M′″ represents a monoatomic cation of an element selected from Group 14 of the IUPAC periodic table of the elements, or any combination of such cations;
X represents an anion of an element selected from Group 16 of the IUPAC periodic table of the elements, or from Group 17 of the IUPAC periodic table of the elements, or any combination of such anions; and
M″” represents a dopant cation of an element selected from rare earth metals of the IUPAC periodic table of the elements, or from transition metals of the IUPAC periodic table of the elements, or any combination of such cations, or wherein M″” is absent.

2. The detecting device of claim 1 , wherein the filter element is configured to filter off electromagnetic radiation with a wavelength of above 400 nm, or above 300 nm, from the incident electromagnetic radiation.

3. The detecting device of claim 1 , wherein the filter element is configured to pass through incident electromagnetic radiation with a wavelength of above 0 nm to 590 nm, or above 0 nm to 560 nm, or above 0 nm to 500 nm, or above 0 nm to 400 nm, or above 0 nm to 300 nm, or 0.000001-590 nm, or 0.000001-560 nm, or 0.000001-500 nm, 0.000001-400 nm, or 0.000001-300 nm, or 0.000001-10 nm, 0.01-590 nm, or 0.01-560 nm, or 0.01-500 nm, or 10-590 nm, or 10-560 nm, or 10-500 nm, or 0.01-400 nm, or 0.01-300 nm, or 10-400 nm, or 10-300 nm, or 0.01-10 nm.

4. The detecting device of claim 1 , wherein the filter element and the converging element are a combined element configured to filter off electromagnetic radiation with a wavelength of above 590 nm from the incident electromagnetic radiation and to increase the density of photons of the predetermined type of radiation present in the incident electromagnetic radiation.

5. The detecting device of claim 1 , wherein the incident electromagnetic radiation originates from a source of artificial radiation or from sunlight.

6. The detecting device of claim 1 , wherein M’ represents a combination of at least two monoatomic cations of different alkali metals selected from Group 1 of the IUPAC periodic table of the elements.

7. The detecting device of claim 1 , wherein M′ represents a combination of at least two monoatomic cations of different alkali metals selected from Group 1 of the IUPAC periodic table of the elements, wherein the combination comprises 0-98 mol-%, or 0-95 mol-%, or 0-90 mol-%, or 0-85 mol-%, or 0-80 mol-%, or 0-70 mol-%, of a monoatomic cation of Na.

8. The detecting device of claim 1 , wherein M′ represents a combination of at least two monoatomic cations of different alkali metals selected from a group consisting of Li, Na, K, and Rb.

9. The detecting device of claim 1 , wherein M″ represents a trivalent monoatomic cation of a metal selected from a group consisting of Al and Ga, or a combination of such cations.

10. The detecting device of claim 1 , wherein M″ represents a trivalent monoatomic cation of B.

11. The detecting device of claim 1 , wherein M′” represents a monoatomic cation of an element selected from a group consisting of Si and Ge, or a combination of such cations.

12. The detecting device of claim 1 , wherein X represents an anion of an element selected from a group consisting of O, S, Se, and Te, or any combination of such anions.

13. The detecting device of claim 1 , wherein X represents an anion of an element selected from a group consisting of F, Cl, Br, and I, or any combination of such anions.

14. The detecting device of claim 1 , wherein M′“′ represents a cation of an element selected from a group consisting of Eu and Tb, or a combination of such cations.

15. The detecting device of claim 1 , wherein M′”′ represents a cation of an element selected from a group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, or any combination of such cations.

16. A method for indicating an intensity of a predetermined type of radiation present in incident electromagnetic radiation, wherein the method comprises:
filtering off electromagnetic radiation with a wavelength of above 590 nm from the incident electromagnetic radiation;
converging the incident electromagnetic radiation for increasing a density of photons of the predetermined type of radiation present in the incident electromagnetic radiation;
subsequent to the filtering and converging, exposing a sensor element comprising a material to the incident electromagnetic radiation, wherein the material is represented by formula (I), comprising:
(M′) 8 (M″M′”) 6 O 24 (X,S) 2 :M′”′;

determining a change of a color of the sensor element as a result of the material being exposed to the incident electromagnetic radiation; and
comparing the color of the sensor element with a reference indicating a correlation of the intensity of the predetermined type of radiation with the color of the sensor element.

17. The method of claim 16 , wherein the filtering and the converging steps are carried out one after the other in any order or wherein the filtering and converging steps are carried out simultaneously.

18. A method comprising:
using the detecting device of claim 1 for indicating an intensity of a predetermined type of radiation present in electromagnetic radiation.

19. The method of claim 18 , further comprising:
subjecting the detecting device to the electromagnetic radiation.

Assignees

• Turun Yliopisto

Inventors

• Lastusaari Mika
• Norrbo Isabella
• Laukkanen Pekka

Classifications

• C09K9/00 Primary

  Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy · CPC title

• G02B5/208

  for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation · CPC title

• G01J1/50

  using change in colour of an indicator, e.g. actinometer · CPC title

• C01P2006/60

  Optical properties, e.g. expressed in CIELAB-values · CPC title

• G01J1/0488 Primary

  with spectral filtering · CPC title