Acrylic pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet

Patent metadata

Field	Value
Publication number	US-11168236-B2
Application number	US-201816152776-A
Country	US
Kind code	B2
Filing date	Oct 5, 2018
Priority date	Oct 6, 2017
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

The present invention provides an acrylic PSA composition. The acrylic PSA composition comprises an acrylic polymer as its base polymer and at least one species selected among tackifier resins and (meth)acrylic oligomers. The acrylic polymer has a weight average molecular weight higher than 70×10 4 . The acrylic polymer has a dispersity (Mw/Mn) below 15.

First claim

What is claimed is:

1. A pressure-sensitive adhesive sheet having an acrylic pressure-sensitive adhesive layer that comprises an acrylic polymer as its base polymer and at least a tackifier resin or a (meth)acrylic oligomer, wherein
the acrylic polymer is a polymer of a starting monomer mixture that comprises an alkyl (meth)acrylate in an amount of 85% by weight or higher, the alkyl (meth)acrylate is a compound represented by the formula (1)
CH 2 ═C(R 1 )COOR 2   (1)

wherein R 1 is a hydrogen atom or a methyl group, and R 2 is an acyclic alkyl group having 1 to 6 carbon atoms,
the acrylic polymer has a weight average molecular weight of 110×10 4 or higher,
the acrylic polymer has a dispersity (Mw/Mn) below 15,
the pressure-sensitive adhesive layer has a gel fraction of 40% by weight or higher, and
the pressure-sensitive adhesive layer has a storage modulus at 85° C., G′(85° C.), of 0.02 MPa or greater.

2. The pressure-sensitive adhesive sheet according to claim 1 , wherein
the pressure-sensitive adhesive layer has a storage modulus at 25° C., G′(25° C.), of 0.15 MPa or greater; and
the pressure-sensitive adhesive sheet satisfies at least one of the following features: having a 180° peel strength of 8 N/20 mm or greater when determined within one minute after press-bonded at 23° C. at a press-bonding load of 0.1 kg or a 180° peel strength of 8 N/20 mm or greater when determined within one minute after press-bonded at 40° C. at 0.05 MPa for 3 seconds.

3. The pressure-sensitive adhesive sheet according to claim 1 , wherein the acrylic polymer includes an acidic group-containing monomer copolymerized therein.

4. The pressure-sensitive adhesive sheet according to claim 3 , wherein the acidic group-containing monomer is acrylic acid.

5. The pressure-sensitive adhesive sheet according to claim 3 , wherein the acidic group-containing monomer has a copolymerization ratio below 10% by weight in the acrylic polymer.

6. The pressure-sensitive adhesive sheet according to claim 1 , wherein the acrylic polymer is crosslinked.

7. The pressure-sensitive adhesive sheet according to claim 1 , used for fixing parts in mobile electronics.

8. The pressure-sensitive adhesive sheet according to claim 1 , used for fixing a flexible printed circuit.

9. The pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer has a storage modulus at 85° C., G′(85° C.), of 0.03 MPa or greater.

10. The pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer has a storage modulus at 85° C., G′(85° C.), of 0.04 MPa or greater.

11. The pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer has a storage modulus at 85° C., G′(85° C.), of 0.05 MPa or greater.

12. The pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer has the gel fraction of 40% by weight or higher and 70% or lower.

13. The pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer comprises the (meth)acrylic oligomer, the (meth)acrylic oligomer has a weight average molecular weight of 1,000 or larger and smaller than 30,000, and the (meth)acrylic oligomer comprises, as a (meth)acrylate monomer, an alicyclic hydrocarbon group-containing (meth)acrylate in an amount higher than 50% by weight.

14. The pressure-sensitive adhesive sheet according to claim 1 , wherein
the pressure-sensitive adhesive sheet consists of the pressure-sensitive adhesive layer, or the pressure-sensitive adhesive sheet comprises a substrate to support the pressure-sensitive adhesive layer,
the substrate is a resin film, a foam film, paper, a fabric, a metal foil, or a composite thereof, and
the foam film is formed from a foam material selected from the group consisting of a polyester-based resin foam, a polyvinyl chloride-based resin foam, a vinyl acetate-based resin foam, a polyphenylene sulfide resin foam, an amide-based resin foam, a polyimide resin foam, a polyether ether ketone foam, a styrene-based resin foam, a urethane-based resin foam and a rubber-based resin foam.

15. The pressure-sensitive adhesive sheet according to claim 1 , wherein
the pressure-sensitive adhesive sheet consists of the pressure-sensitive adhesive layer, or the pressure-sensitive adhesive sheet comprises a substrate to support the pressure-sensitive adhesive layer,
the substrate is a resin film, a foam film, paper, a fabric, a metal foil, or a composite thereof,
the resin film is a polyester-based resin film, a polyvinylic resin film, a vinyl acetate-based resin film, a polyimide-based resin film, a polyamide-based resin film, a fluororesin film, cellophane, or a rubber-based film, and
the foam film is formed from a foam material selected from the group consisting of a polyester-based resin foam, a polyvinyl chloride-based resin foam, a vinyl acetate-based resin foam, a polyphenylene sulfide resin foam, an amide-based resin foam, a polyimide resin foam, a polyether ether ketone foam, a styrene-based resin foam, a urethane-based resin foam and a rubber-based resin foam.

Assignees

• Nitto Denko Corp

Inventors

• Jozuka Kenta
• Higuchi Naoaki
• Furuta Kenji
• Kato Naohiro
• Buzojima Yasushi

Classifications

• C08F220/1808

  C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate · CPC title

• C09J133/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C09J11/08

  Macromolecular additives · CPC title

• C09J2301/312

  parameters being the characterizing feature · CPC title

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title