Separation and upcycling of cellulose-containing blended waste

Patent metadata

Field	Value
Publication number	US-11168196-B2
Application number	US-201716471001-A
Country	US
Kind code	B2
Filing date	Dec 20, 2017
Priority date	Dec 20, 2016
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

According to an example aspect of the present invention, there is provided a method of separating cellulose and polyester from a material comprising a blend of cellulose and polyester, said method comprising the steps of mixing the material comprising a blend of cellulose and polyester with a first portion of superbase-based ionic liquid to dissolve a first portion of cellulose and form a first cellulose solution and a first residue comprising polyester, removing the first residue comprising polyester from the first cellulose solution, and directing the first cellulose solution to one or more further processing steps.

First claim

The invention claimed is:

1. A method of producing cellulose filaments comprising:
mixing material comprising a blend of cellulose and polyester with a first portion of a superbase-based ionic liquid to dissolve a first portion of cellulose and form a first cellulose solution and a first residue comprising polyester,
removing the first residue comprising polyester from the first cellulose solution, and
directing the first cellulose solution to one or more further processing steps to provide the cellulose filaments.

2. The method according to claim 1 , wherein the one or more further processing steps to which the first cellulose solution is directed comprises a dry-jet wet spinning step, wherein:
the first cellulose solution is placed in a spinning unit,
heated to a temperature in the range of 30 to 100° C., and
extruded through a spinneret into a coagulation bath to provide the cellulose filaments.

3. The method according to claim 2 , wherein the temperature is in the range of 40 to 95° C.

4. The method according to claim 2 , wherein the cellulose filaments are collected on a godet.

5. The method according to claim 2 , wherein the coagulation bath contains water at a temperature in the range of 5 to 25° C.

6. The method according to claim 1 , further comprising:
carrying out a first polyester purification step, wherein the first residue comprising polyester is mixed with a second portion of the superbase-based ionic liquid to dissolve a second portion of cellulose and form a second cellulose solution and a second residue comprising polyester,
removing the second residue comprising polyester from the second cellulose solution, and
coagulating the second portion of cellulose in the second cellulose solution and directing the coagulated second portion of the cellulose to the one or more further processing steps.

7. The method according to claim 6 , wherein the coagulated second portion of cellulose is directed to the mixing step and mixed with the material comprising a blend of cotton and polyester, and the first portion of superbase-based ionic liquid.

8. The method according to claim 6 , further comprising:
carrying out a second polyester purification step, wherein the second residue comprising polyester is mixed with a third portion of the superbase-based ionic liquid to dissolve a third portion of cellulose and form a third cellulose solution and a third residue comprising polyester,
removing the third residue comprising polyester from the third cellulose solution, and
coagulating the third portion of cellulose in the third cellulose solution and directing the coagulated third portion of cellulose to the one or more further processing steps.

9. The method according to claim 8 , wherein the coagulated third portion of cellulose is directed to the first mixing step and mixed with the material comprising a blend of cotton and polyester, and the first portion of superbase-based ionic liquid.

10. The method according to claim 1 , wherein the material comprising a blend of cellulose and polyester comprises a blend of cellulose and polyester in a ratio of 50:50 to 80:20.

11. The method according to claim 1 , wherein the material is pretreated prior to the first mixing step to adjust the degree of polymerization (DP) of the cellulose.

12. The method according to claim 1 , wherein the mixing step is carried out at a temperature in the range of 25° C. to 95° C.

13. The method according to claim 1 , wherein the mixing step is carried out for a period of time in the range of 30 minutes to 6 hours.

14. The method according to claim 1 , wherein the first residue is removed from the first cellulose solution by press filtration.

15. The method according to claim 1 , wherein the first residue is removed from the first cellulose solution at a temperature in the range of 50° C. to 90° C.

16. The method according to claim 1 , wherein water and the superbase-based ionic liquid used in the method are recovered by thin film evaporation.

17. The method according to claim 1 , wherein the material comprising a blend of cellulose and polyester comprises a cellulose component selected from the group consisting of cotton, viscose, Lyocell fiber, and a mixture thereof.

18. The method according to claim 1 , wherein the superbase-based ionic liquid is selected from the group consisting of DBNH OAc and mTBDH OAc.

19. Microfibers produced by the method according to claim 1 , wherein the microfibers have a titer below 1 dtex.

20. The microfibers according to claim 19 , wherein the microfibers have a tenacity of >35 CNtex −1 and a wet-to-dry strength ratio of 0.8 or higher.

21. The method according to claim 1 , wherein the superbase-based ionic liquid comprises a superbase selected from the group consisting of 1,5-diazabicyclo[4.3.0]non-5-ene (DBN), 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD), 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), N,N,N,N,N,N-hexamethylphosphorimide triamide (HMPI), N,N,N,N-tetramethylguanidinium (TMG), and 1,2-dimethyl-1,1,4,5,6-tetrahydropyrimidine (DMP).

Assignees

• Aalto Univ Foundation Sr

Inventors

• Haslinger Simone
• Hummel Michael
• Sixta Herbert

Classifications

• Y02W30/62

  Plastics recycling; Rubber recycling · CPC title

• C08J11/08 Primary

  using selective solvents for polymer components · CPC title

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• D01F2/02

  from solutions of cellulose in acids, bases or salts · CPC title