Automotive seat made from epoxidized soy oil

Patent metadata

Field	Value
Publication number	US-11168176-B2
Application number	US-201816144220-A
Country	US
Kind code	B2
Filing date	Sep 27, 2018
Priority date	Sep 27, 2018
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

A composition for forming polyurethane foams is provided using epoxidized triglycerides with unopened rings. The composition further includes a polyol, a blowing agent, and a catalyst that catalyzes the reaction of polyols with isocyanates to form polyurethanes. The polyol is a polyoxyalklylene and the epoxidized triglyceride is an epoxidized soybean oil. A method for forming polyurethane foam using the aforementioned composition is also provided.

First claim

What is claimed is:

1. A composition for forming polyurethane foams, the composition comprising:
a polyol;
an epoxidized triglyceride with unopened epoxide rings wherein at least 95% of epoxide rings on the epoxidized triglyceride with unopened epoxide rings are unopened and the weight ratio of the epoxidized triglyceride with unopened epoxide rings are to the polyol is less than 0.5 and wherein the epoxidized triglyceride with unopened epoxide rings is present in an amount from about 2 to 10 weight percent of the total weight of the composition for forming polyurethane foams, the epoxidized triglyceride with unopened epoxide rings including an epoxidized linoleum having formula I:

a blowing agent; and
a catalyst that catalyzes reaction of polyols with isocyanates to form polyurethanes.

2. The composition of claim 1 wherein the weight ratio of the epoxidized triglyceride with unopened epoxide rings to the polyol is from about 0.02 to 0.3.

3. The composition of claim 1 wherein the epoxidized triglyceride with unopened epoxide rings is an epoxidized vegetable oil.

4. The composition of claim 1 wherein the epoxidized triglyceride with unopened epoxide rings is epoxidized soybean oil.

5. The composition of claim 1 wherein the epoxidized triglyceride with unopened epoxide rings is present in an amount from about 2 to 10 weight percent of the total weight of the composition for forming polyurethane foams.

6. The composition of claim 1 wherein the polyol is present in an amount from 80 to 95 weight percent of the total weight of the composition for forming polyurethane foams.

7. The composition of claim 1 wherein the epoxidized triglyceride with unopened epoxide rings includes fatty acid chains including a component selected from the group consisting of epoxidized alpha-linolenic acid, epoxidized linoleic acid, oleic acid, and combinations thereof.

8. The composition of claim 1 further comprising a reaction product of the polyol and the epoxidized triglyceride with unopened epoxide rings.

9. The composition of claim 1 wherein the polyol is a polyol polymer.

10. The composition of claim 1 wherein the polyol is a polyoxyalkylene polyol.

11. The composition of claim 1 further comprising isocyanate added prior to foam formation, selected from the group consisting of aliphatic, cycloaliphatic, arilphatic, aromatic isocyanates, and combinations thereof.

12. The composition of claim 11 wherein the isocyanate is a diisocyanate selected from the group consisting of tri-, tetra-, penta-, hexa-, hepta- and/or octamethylene diisocyanate, 2-methylpentamethylene 1,5-diisocyanate, 2-ethylbutylene 1,4-diisocyanate, pentamethylene 1,5-diisocyanate, butylene 1,4-diisocyanate, and combinations thereof and/or a triisocyanate selected from the group consisting of 1,3,5-triisocyanate, toluene 2,4,6-triisocyanate, triphenylemethane 4,4′,4″ triisocyanate, and combinations thereof.

13. The composition of claim 1 wherein the catalyst to form the polyurethanes is a tertiary amine selected from the group consisting of 1,4-diazabicyclo(2,2,2)octane, bis(2,2-dimethylamino)ethyl ether, N-ethylmorpholine, diethylenetriamine, triethylenediamine/glycol solutions, and combinations thereof.

14. The composition of claim 1 further comprising an additive selected from the group consisting of surfactants, coloring agents, plasticizers, stabilizers, and combinations thereof.

15. The composition of claim 14 wherein the additive is a silicone-based surfactant, present in an amount from about 0.2 to 4 weight percent of the total weight of the composition for forming polyurethane foams.

16. The composition of claim 1 wherein the blowing agent is selected from the group consisting of water, acetone, methanol, halogenated alkenes, ethyl acetate, and combinations thereof.

17. A method for forming polyurethane foams in a molding apparatus, the method comprising:
directing a polyol composition into a mold, the polyol composition including a mixture of an epoxidized triglyceride with unopened rings, a polyol, a blowing agent and a catalyst, wherein at least 95% of epoxide rings on the epoxidized triglyceride with unopened epoxide rings are unopened and the weight ratio of the epoxidized triglyceride with unopened epoxide rings are to the polyol is less than 0.5 and wherein the epoxidized triglyceride with unopened epoxide rings are is present in an amount from about 2 to 10 weight percent of the total weight of the composition for forming polyurethane foams, the epoxidized triglyceride with unopened epoxide rings including an epoxidized linoleum having formula I:

and
directing an isocyanate composition into the mold to form a foamed polyurethane.

Assignees

• Lear Corp

Inventors

• Ali Asad S
• Fielding Paul
• Kowalski Virgil
• Phillips Matthew
• Zhang Zhijie
• Dawe Robert D
• Spivey Calton B

Classifications

• C08J2375/04

  Polyurethanes · CPC title

• C08G18/58

  Epoxy resins {(C08G18/42, C08G18/48 take precedence; reaction products of epoxy resins with at least equivalent amounts of compounds containing active hydrogen C08G18/6407, with at least equivalent amounts of amines C08G18/6415; polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen C08G18/003)} · CPC title

• C08G18/18

  containing secondary or tertiary amines or salts thereof · CPC title

• C08G2110/0083

  prepared using water as the sole blowing agent · CPC title

• C08J9/0028

  containing nitrogen · CPC title