Multi-component polar olefin copolymer and method for producing the same

Patent metadata

Field	Value
Publication number	US-11168166-B2
Application number	US-201816497556-A
Country	US
Kind code	B2
Filing date	Mar 28, 2018
Priority date	Mar 28, 2017
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

An object of the present invention is to provide a multi-component polar olefin copolymer which has sufficiently improved solvent solubility without impairing mechanical properties and the like. The present invention relates to a multi-component polar olefin copolymer containing: one kind of unit of nonpolar monomer (X1) that is ethylene or an α-olefin having 3 to 10 carbon atoms; one or two or more kinds of units of polar monomers (formula (1), Z1); and structural unit(s) of one or two or more kinds of units of nonpolar monomers (X2) that are different from the above X1 and/or one or two or more kinds of units of polar monomers (formula (2), Z2):H2C═CH—COOQT1  (1)H2C═CH-T2  (2).

First claim

The invention claimed is:

1. A multi-component polar olefin copolymer comprising:
one kind of unit of nonpolar monomer (X1) that is ethylene or an α-olefin having 3 to 10 carbon atoms; and
one or two or more kinds of units of polar monomers (Z1) that are a compound represented by the following general formula (1),
wherein the multi-component polar olefin copolymer comprises at least any one structural unit of
one or two or more kinds of units of nonpolar monomers (X2) that are different from the nonpolar monomer (X1) and are selected from the group consisting of ethylene and an α-olefin having 3 to 10 carbon atoms; and
one or two or more kinds of units of polar monomers (Z2) that are a compound represented by the following general formula (2),
wherein the multi-component polar olefin copolymer has a ratio (Mw/Mn) of 1.5 to 3.5, which is a ratio of weight-average molecular weight (Mw) to number-average molecular weight (Mn), as determined by gel permeation chromatography (GPC):
H 2 C═CH—COO Q T1  1

H 2 C═CH-T2  2

wherein, in the general formula (1),
Q represents a divalent hydrocarbon group having 2 to 10 carbon atoms, a divalent hydrocarbon group having 2 to 10 carbon atoms, which is substituted with a hydroxyl group, a divalent hydrocarbon group having 3 to 20 carbon atoms, which is substituted with an alkoxy group having 1 to 10 carbon atoms, a divalent hydrocarbon group having 4 to 20 carbon atoms, which is substituted with an ester group having 2 to 10 carbon atoms, a divalent hydrocarbon group having 5 to 28 carbon atoms, which is substituted with a substituted silyl group having 3 to 18 carbon atoms, a divalent hydrocarbon group having 2 to 10 carbon atoms, which is substituted with an ether group, or a divalent hydrocarbon group having 2 to 10 carbon atoms, which is substituted with a halogen atom, and T1 represents a methacryloyloxy group;
in the general formula (2),
T2 represents a hydrocarbon group having 1 to 10 carbon atoms, which is substituted with a hydroxyl group, a hydrocarbon group having 2 to 20 carbon atoms, which is substituted with an alkoxy group having 1 to 10 carbon atoms, a hydrocarbon group having 3 to 20 carbon atoms, which is substituted with an ester group having 2 to 10 carbon atoms, a hydrocarbon group having 4 to 28 carbon atoms, which is substituted with a substituted silyl group having 3 to 18 carbon atoms, a hydrocarbon group having 1 to 10 carbon atoms, which is substituted with a halogen atom, an alkoxy group having 1 to 10 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, a carboxyl group, an ester group having 2 to 10 carbon atoms, an acyloxy group having 2 to 10 carbon atoms, an amino group, a substituted amino group having 1 to 12 carbon atoms, a substituted silyl group having 3 to 18 carbon atoms, or a halogen atom.

2. The multi-component polar olefin copolymer according to claim 1 , which has a degree of methyl branching of 5.0 or less per 1,000 carbons of the main chain, which is calculated by 13 C-NMR.

3. The multi-component polar olefin copolymer according to claim 1 , wherein the copolymer is formed by polymerization using a transition metal catalyst of a metal of Group-5 to Group-10 of the periodic table.

4. The multi-component polar olefin copolymer according to claim 3 , wherein the transition metal catalyst is a transition metal catalyst which contains nickel metal or palladium metal, and a chelatable phosphine compound coordinated thereto.

5. A method for producing the multi-component polar olefin copolymer according to claim 1 , comprising copolymerizing X1, X2, Z1, and Z2 in the presence of a transition metal catalyst of a metal of Group-5 to Group-10 of the periodic table.

6. The method for producing the multi-component polar olefin copolymer according to claim 5 , wherein the transition metal catalyst is a transition metal catalyst which contains nickel metal or palladium metal, and a chelatable phosphine compound coordinated thereto.

Assignees

• Japan Polyethylene Corp
• Japan Polypropylene Corp

Inventors

• Kobayashi Minoru
• Satou Tomohiko
• Uematsu Masahiro
• Yamada Yoshika

Classifications

• C08F210/02 Primary

  Ethene · CPC title

• C08F222/102

  of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate · CPC title

• C08F4/619

  Component covered by group C08F4/60 containing a transition metal-carbon bond {(C08F4/60003 - C08F4/60196 take precedence)} · CPC title

• C08F222/02 Primary

  Acids; Metal salts or ammonium salts thereof {, e.g. maleic acid or itaconic acid} · CPC title

• C08F2410/04

  Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene · CPC title