Method for producing syngas, as well as syngas cooling assembly and use

Patent metadata

Field	Value
Publication number	US-11167997-B2
Application number	US-201816497494-A
Country	US
Kind code	B2
Filing date	Mar 27, 2018
Priority date	Apr 5, 2017
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

A method of producing synthesis gas in a dual pressure level ammonia plant having a first synthesis section operated in once through fashion at a first relatively lower high pressure and having a second synthesis section operated in recirculating fashion at a second relatively higher high pressure. In the first synthesis section downstream of an OT reactor of the first synthesis section the synthesis gas is cooled using cooling medium at a pressure below the first high pressure, wherein the cooling medium is provided at a pressure below the first high pressure level by means of a medium pressure steam generator or wherein the cooling is effected by means of the medium pressure steam generator. The disclosure further relates to a synthesis gas cooling assembly in such a dual pressure level ammonia plant and at least one plant component for providing or for utilizing the cooling medium.

First claim

What is claimed is:

1. A method of producing synthesis gas in a dual pressure level ammonia plant, comprising:
operating, in once through fashion, a first synthesis section at a first high pressure level,
operating, in recirculating fashion, a second synthesis section at a second high pressure level, wherein the pressure of the second high pressure level is higher than the first high pressure level,
cooling the synthesis gas in the first synthesis section downstream of an OT reactor of the first synthesis section using a cooling medium at a pressure level below the first high pressure level, and
providing, by a medium pressure steam generator, said cooling medium at a pressure level below the first high pressure level or wherein the cooling is effected by the medium pressure steam generator.

2. The method of claim 1 , wherein the pressure level is in the range from about 50 to about 75 bar.

3. The method of claim 1 , wherein the cooling medium is steam.

4. The method of claim 3 , wherein the steam is from boiler feed water.

5. The method of claim 1 , wherein in the first synthesis section the synthesis gas is passed to at least one further OT reactor of the first synthesis section after cooling.

6. The method of claim 1 , wherein the cooling medium is provided at or by the medium pressure steam generator comprising at least one dual phase heat exchanger which is traversed by synthesis gas upstream of the OT reactor or a further OT reactor, and/or wherein steam is generated from boiler feed water by the medium pressure steam generator when during the cooling of synthesis gas in the medium pressure steam generator heat is transferred to the boiler feed water.

7. The method of claim 1 , wherein the cooling medium is passed to a process condensate stripper of the ammonia plant once heat exchange with the synthesis gas has been effected and/or wherein the cooling medium is passed to a primary reformer of the ammonia plant once heat exchange with the synthesis gas has been effected.

8. The method of claim 1 , wherein the cooling medium is diverted from the first synthesis section to a condensate drum of the ammonia plant downstream of the medium pressure steam generator.

9. A synthesis gas cooling assembly for heat removal from synthesis gas, comprising:
two synthesis sections,
a first one of the two synthesis sections having a relatively lower high pressure level of a dual pressure level ammonia plant relative to the second one of the two synthesis sections,
the cooling assembly configured to provide cooling medium at a pressure level below the high pressure level of the first synthesis section,
a medium pressure steam generator configured to provide the cooling medium at the pressure level below the high pressure level of the first synthesis section, and
two discharge conduits,
wherein one of the two discharge conduits is configured to provide the cooling medium to a process condensate stripper of the ammonia plant and the other of the two discharge conduits is configured to provide the cooling medium to a condensate drum of the ammonia plant.

10. The synthesis gas cooling assembly of claim 9 , further comprising a cooling arrangement that is configured to provide the cooling medium in vaporous form.

11. The synthesis gas cooling assembly of claim 9 , further comprising a cooling arrangement that is configured to provide the cooling medium downstream of a first OT reactor of the first synthesis section and upstream of a second OT reactor of the first synthesis section.

12. The synthesis gas cooling assembly of claim 9 , wherein the synthesis gas cooling arrangement comprises the medium pressure steam generator comprising at least one dual phase heat exchanger.

13. The synthesis gas cooling assembly of claim 9 , wherein the medium pressure steam generator of the cooling assembly which provides the cooling medium is connectable to a primary reformer of the ammonia plant; and/or wherein the medium pressure steam generator of the cooling assembly which provides the cooling medium is couplable/coupled to a process condensate stripper of the ammonia plant.

14. A dual pressure level ammonia plant having a first synthesis section comprising at least one OT reactor and having a second synthesis section having a plurality of loop reactors and having at least one synthesis gas cooling assembly according to claim 9 .

Assignees

• Thyssenkrupp Ind Solutions Ag
• Thyssenkrupp Ag

Inventors

• Tenbrink Norbert
• Berger Maximilian

Classifications

• B01J19/245

  placed in series · CPC title

• B01J2219/00103

  in a heat exchanger separate from the reactor · CPC title

• C01C1/0452 Primary

  Heat exchangers · CPC title

• C01C1/0405 Primary

  from N2 and H2 in presence of a catalyst · CPC title

• B01J2219/0004

  Processes in series · CPC title