Method for producing golf ball

Patent metadata

Field	Value
Publication number	US-11167458-B2
Application number	US-201816233973-A
Country	US
Kind code	B2
Filing date	Dec 27, 2018
Priority date	Dec 28, 2017
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

An object of the present invention is to provide a method for obtaining a golf ball having excellent impact durability. The present invention provides a method for producing a golf ball, comprising a first step of kneading (a) a base rubber, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinkable compound having two or more polymerizable unsaturated bonds in a molecule thereof, and (d) a crosslinking initiator to prepare a core rubber composition; a second step of producing the spherical core from the core rubber composition at a molding temperature in a range from 100° C. to 150° C.; and a third step of molding the at least one cover layer covering the spherical core on the spherical core.

First claim

The invention claimed is:

1. A method for producing a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the method comprises:
a first step of kneading (a) a base rubber, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinkable compound having two or more polymerizable unsaturated bonds in a molecule thereof which excludes the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and the metal salt thereof, and (d) a crosslinking initiator to prepare a core rubber composition containing at least (a) the base rubber, (b) the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof, (c) the crosslinkable compound, and (d) the crosslinking initiator;
a second step of producing the spherical core from the core rubber composition at a molding temperature in a range from 100° C. to 150° C.; and
a third step of molding the at least one cover layer covering the spherical core on the spherical core,
wherein a temperature difference (Tc-T2) between the molding temperature (T2) in the second step and a self-polymerization temperature (Tc) of (c) the crosslinkable compound by heat is 1° C. or more, and
a temperature difference (Td-T2) between the molding temperature (T2) in the second step and a one-minute half-life temperature (Td) of (d) the crosslinking initiator is 40° C. or less.

2. The method for producing the golf ball according to claim 1 , wherein (c) the crosslinkable compound having two or more polymerizable unsaturated bonds in the molecule thereof is a crosslinkable compound having two or more (meth)acryloyl groups in a molecule thereof.

3. The method for producing the golf ball according to claim 1 , wherein (c) the crosslinkable compound having two or more polymerizable unsaturated bonds in the molecule thereof is at least one member selected from the group consisting of trimethylolpropane tri(meth)acrylate, ethylene glycol di(meth)acrylate, and 1,6-hexanediol di(meth)acrylate.

4. The method for producing the golf ball according to claim 1 , wherein the core rubber composition contains (c) the crosslinkable compound having two or more polymerizable unsaturated bonds in the molecule thereof in an amount of ranging from 2 parts by mass to 39 parts by mass with respect to 100 parts by mass of (a) the base rubber.

5. The method for producing the golf ball according to claim 1 , wherein the core rubber composition contains (d) the crosslinking initiator in an amount of ranging from 0.1 part by mass to 5 parts by mass with respect to 100 parts by mass of (a) the base rubber.

6. The method for producing the golf ball according to claim 1 , wherein the core rubber composition contains (e) a metal compound, and (e) the metal compound is also kneaded in the first step.

7. The method for producing the golf ball according to claim 1 , wherein the core rubber composition contains (f) an organic sulfur compound and/or (g) a carboxylic acid and/or a metal salt thereof, and (f) the organic sulfur compound and/or (g) the carboxylic acid and/or a metal salt thereof is also kneaded in the first step.

8. The method for producing the golf ball according to claim 7 , wherein the core rubber composition contains (g) the carboxylic acid and/or a metal salt thereof, and (g) the carboxylic acid and/or the metal salt thereof is at least one member selected from the group consisting of a saturated fatty acid, a metal salt of a saturated fatty acid, an aromatic carboxylic acid, and a metal salt of an aromatic carboxylic acid.

9. The method for producing the golf ball according to claim 1 , wherein (c) the crosslinkable compound has a molecular weight in a range from 100 to 500.

10. The method for producing the golf ball according to claim 1 , wherein (c) the crosslinkable compound has a self-polymerization temperature by heat (Tc) of 120° C. or more.

11. The method for producing the golf ball according to claim 1 , wherein (d) the crosslinking initiator has a one-minute half-life temperature (Td) of less than 160° C.

12. The method for producing the golf ball according to claim 1 , wherein in the first step, all the materials are kneaded at one time to prepare the rubber composition.

13. The method for producing the golf ball according to claim 1 , wherein in the first step, the components other than the component (c) are kneaded to prepare a mixture, and then the mixture and the component (c) are kneaded to prepare the rubber composition.

14. The method for producing the golf ball according to claim 1 , wherein in the first step, the components other than the component (c) and the component (d) are kneaded to prepare a mixture, and then the mixture, the component (c) and the component (d) are kneaded to prepare the rubber composition.

15. The method for producing the golf ball according to claim 14 , wherein (d) the crosslinking initiator has a one-minute half-life temperature (Td) of less than 160° C.

16. The method for producing the golf ball according to claim 14 , wherein a temperature difference (Td-T1) between a kneading temperature (T1) for preparing the rubber composition and a one-minute half-life temperature (Td) of (d) the crosslinking initiator is 40° C. or more.

17. The method for producing the golf ball according to claim 14 , wherein a temperature difference (Tc-T1) between a kneading temperature (T1) for preparing the rubber composition and a self-polymerization temperature (Tc) of (c) the crosslinkable compound by heat is 10° C. or more.

18. The method for producing the golf ball according to claim 1 , wherein
(c) the crosslinkable compound having two or more polymerizable unsaturated bonds in the molecule thereof is a crosslinkable compound having two or more (meth)acryloyl groups in a molecule thereof, and has a molecular weight in a range from 100 to 500.

Assignees

• Sumitomo Rubber Ind

Inventors

• Sakamine Ryota
• Shiga Kazuyoshi
• Nagakura Hikaru

Classifications

• A63B37/00776

  Slab hardness · CPC title

• B29B7/005

  for mixing in batches · CPC title

• B29B7/90

  Fillers or reinforcements {, e.g. fibres} · CPC title

• A63B37/0063

  Hardness gradient · CPC title

• A63B37/0051

  Materials other than polybutadienes; Constructional details · CPC title