Reducing fluctuations in tail gas flow from an adsorption unit

Patent metadata

Field	Value
Publication number	US-11167240-B2
Application number	US-201916421543-A
Country	US
Kind code	B2
Filing date	May 24, 2019
Priority date	May 24, 2019
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

Pressure swing adsorption process for reducing fluctuations in the flow rate of tail gas from the adsorption unit. The flow rate of the stream of blowdown gas is regulated responsive signals from a sensor measuring the pressure and/or flow rate of the tail gas comprising the blowdown gas and purge gas effluent before the tail gas is introduced into a surge vessel.

First claim

The invention claimed is:

1. A process for producing a product gas and a by-product gas from a feed gas mixture in an adsorption separation unit comprising a plurality of adsorption beds, the feed gas mixture comprising a primary gas component and secondary gas components, each adsorption bed containing an adsorbent selective for the secondary gas components, the product gas enriched with the primary gas component, the by-product gas depleted of the primary gas component, where each of the plurality of adsorption beds is subjected to a repetitive cycle of steps, the process comprising:
a production step, which comprises introducing a stream of the feed gas mixture into an adsorption bed undergoing the production step and adsorbing the secondary gas components on the adsorbent in the adsorption bed undergoing the production step while simultaneously withdrawing a product gas stream from the adsorption bed undergoing the production step;
a supply purge gas step, which comprises co-currently withdrawing a stream of purge gas from an adsorption bed undergoing the supply purge gas step, and passing the stream of purge gas from the adsorption bed undergoing the supply purge gas step to an adsorption bed undergoing a purge step;
a blowdown step, which comprises counter-currently withdrawing a stream of blowdown gas from an adsorption bed undergoing the blowdown step;
the purge step, which comprises counter-currently introducing the stream of purge gas from the adsorption bed undergoing the supply purge gas step into an adsorption bed undergoing the purge step and counter-currently withdrawing a stream of purge gas effluent from the adsorption bed undergoing the purge step;
a repressurization step, which comprises increasing the pressure in an adsorption bed undergoing the repressurization step by at least one of (i) co-currently introducing a second stream of the feed gas mixture into the adsorption bed undergoing the repressurization step, or (ii) counter-currently introducing a portion of the product gas stream from the adsorption bed undergoing the production step into the adsorption bed undergoing the repressurization step;
wherein at least one adsorption bed undergoes at least part of the purge step simultaneously with at least one other adsorption bed undergoing at least part of the blowdown step, and the stream of purge gas effluent from the adsorption bed undergoing the purge step is combined with the stream of blowdown gas from the adsorption bed undergoing the blowdown step to form a by-product gas stream;
introducing the by-product gas stream into a surge vessel;
withdrawing the by-product gas stream from the surge vessel;
periodically obtaining signals from a sensor operatively disposed to sense a pressure and/or a flow rate of the by-product gas stream before the by-product gas stream is introduced into the surge vessel;
regulating the flow rate of the stream of blowdown gas that is combined with the stream of purge gas effluent during at least a portion of the blowdown step, where the flow rate of the stream of blowdown gas is regulated responsive to the signals from the sensor, wherein regulating the flow rate of the stream of blowdown gas comprises
increasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor to increase the pressure or flow rate of the by-product gas stream; and
decreasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor to decrease the pressure or flow rate of the by-product gas stream.

2. The process according to claim 1
wherein it is determined from the signals to increase the pressure of the by-product gas stream when the pressure of the by-product gas stream is less than a target lower limit set point for the pressure of the by-product gas stream or it is determined from the signals to increase the flow rate of the by-product gas stream when the flow rate of the by-product gas stream is less than a target lower limit set point for the flow rate of the by-product gas stream; and
wherein it is determined from the signals to decrease the pressure of the by-product gas stream when the pressure of the by-product gas stream is greater than a target upper limit set point for the pressure of the by-product gas stream or it is determined from the signals to decrease the flow rate of the by-product gas stream when the flow rate of the by-product gas stream is greater than a target upper limit set point for the flow rate of the by-product gas stream.

3. The process according to claim 1 wherein the flow rate of at least one of (i) the stream of purge gas introduced into the adsorption bed undergoing the purge step or (ii) the stream of purge gas effluent withdrawn from the adsorption bed undergoing the purge step is regulated.

4. The process according to claim 1 wherein the sensor is operatively disposed to sense the pressure of the by-product gas stream before the by-product gas stream is introduced into the surge vessel; and
wherein regulating the flow rate of the stream of blowdown gas comprises
increasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor to increase the pressure of the by-product gas stream; and
decreasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor to decrease in the pressure of the by-product gas stream.

5. The process according to claim 4
wherein it is determined from the signals to increase the pressure of the by-product gas stream when the pressure of the by-product gas stream is less than a target lower limit set point for the pressure of the by-product gas stream; and
wherein it is determined from the signals to decrease the pressure of the by-product gas stream when the pressure of the by-product gas stream is greater than a target upper limit set point for the pressure of the by-product gas stream.

6. The process according to claim 1 further comprising:
periodically obtaining signals from a flow rate sensor operatively disposed to sense a flow rate of the by-product gas stream after the by-product gas stream is withdrawn from the surge vessel;
wherein regulating the flow rate of the stream of blowdown gas comprises
increasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor and the signals from the flow rate sensor to increase the pressure or flow rate of the by-product gas stream; and
decreasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor and the signals from the flow rate sensor to decrease the pressure or flow rate of the by-product gas stream.

7. The process according to claim 1 further comprising:
periodically obtaining signals from a pressure sensor operatively disposed to sense a pressure of the stream of blowdown gas withdrawn from the adsorption bed undergoing the blowdown step;
wherein regulating the flow rate of the stream of blowdown gas comprises
increasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor and the signals from the pressure sensor to increase the pressure or flow rate of the by-product gas stream; and
decreasing the flow rate of the stream of blowdown gas when it is determined from the signals from the sensor and the signals from the pressure sensor to decrease the pressure or flow rate of the by-product gas stream.

Assignees

• Air Prod & Chem

Inventors

• D'Addio Elizabeth M
• Wood Christopher H
• Shao Quan Min

Classifications

• C01B2203/043

  Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration · CPC title

• C01B2203/0827

  at least part of the fuel being a recycle stream · CPC title

• B01D2259/40009

  using sensors or gas analysers · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D2259/40064

  Five · CPC title