Thermoplastic polyurethane film and preparation method thereof

Patent metadata

Field	Value
Publication number	US-11161929-B2
Application number	US-201816490757-A
Country	US
Kind code	B2
Filing date	Mar 16, 2018
Priority date	Mar 17, 2017
Publication date	Nov 2, 2021
Grant date	Nov 2, 2021

Abstract

A thermoplastic polyurethane film including a cured product of a polyurethane resin composition is provided. The polyurethane resin composition includes a polyurethane resin, a first isocyanate-based curing agent, and an organic solvent. The thermoplastic polyurethane film has a tensile strength of 0.2 MPa to 1.5 MPa at an initial elongation of 5% to 10%. A method for preparing the thermoplastic polyurethane film is also provided.

First claim

The invention claimed is:

1. A thermoplastic polyurethane film comprising: a cured product of a polyurethane resin composition wherein the polyurethane resin composition comprises a polyurethane resin, a first isocyanate-based curing agent, and an organic solvent, wherein the polyurethane resin is a copolymer of a mixture comprising: a polyol having a number average molecular weight of 1,800 g/mol to 2,200 g/mol; a chain extender comprising a diol having 4 to 10 carbon atoms; and a second isocyanate-based curing agent; wherein the thermoplastic polyurethane film has a tensile strength of 0.2 MPa to 1.5 MPa at an initial elongation of 5% to 10%, and wherein the thermoplastic polyurethane film has a thickness of 10 μm to 250 μm, wherein a content of the polyol is 60 wt % to 75 wt % based on the weight of the mixture, wherein a content of the chain extender is 5 wt % to 10 wt % based on a weight of the mixture, and wherein a content of the second isocyanate-based curing agent is 20 wt % to 30 wt % based on a weight of the mixture.

2. The thermoplastic polyurethane film of claim 1 , wherein a content of the first isocyanate-based curing agent is 2.5 parts by weight to 5 parts by weight based on 100 parts by weight of the polyurethane resin.

3. The thermoplastic polyurethane film of claim 1 , wherein the first isocyanate-based curing agent comprises two to six isocyanate functional groups.

4. The thermoplastic polyurethane film of claim 1 , wherein a content of a solid content of the polyurethane resin composition is 20% to 70%.

5. A method for preparing the thermoplastic polyurethane film according to claim 1 , comprising: preparing a polyurethane resin composition comprising: a polyurethane resin, a first isocyanate-based curing agent, and an organic solvent; forming a polyurethane resin layer by applying the polyurethane resin composition onto a substrate film and heat-treating the polyurethane resin composition to form a polyurethane resin layer; and additionally curing the polyurethane resin layer to form the thermoplastic polyurethane film wherein the polyurethane resin is prepared by carrying out a copolymerization reaction of a mixture, wherein the mixture comprises: a polyol having a number average molecular weight of 1,800 g/mol to 2,200 g/mol; a chain extender comprising a diol having 4 to 10 carbon atoms; and a second isocyanate-based curing agent, in an organic solvent.

6. The method of claim 5 , wherein the heat treating is carried out at a temperature of 100° C. to 150° C.

7. The method of claim 5 , wherein the additional curing is carried out at a temperature of 25° C. to 40° C. for 48 hours to 72 hours.

8. The method of claim 5 , wherein the copolymerization reaction is carried out at a temperature of 50° C. to 70° C.

9. The thermoplastic polyurethane film of claim 1 , wherein a content of the polyol is 70 wt % to 75 wt % based on the weight of the mixture.

10. The thermoplastic polyurethane film of claim 9 , wherein a content of the chain extender is 5 wt % to 7.5 wt % based on a weight of the mixture.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Sang Yool
• Hong Joo Hee
• Park Se Jung
• Kim Sang Hwan
• Kim Jang Soon

Classifications

• C08J2475/04

  Polyurethanes · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08J2375/04

  Polyurethanes · CPC title

• C08G18/792

  formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates · CPC title