Curable composition, manufacturing method of curable composition, cured film, manufacturing method of cured film, color filter, solid-state imaging element, solid-state imaging device, and infrared sensor

Patent metadata

Field	Value
Publication number	US-11155703-B2
Application number	US-201916283107-A
Country	US
Kind code	B2
Filing date	Feb 22, 2019
Priority date	Aug 25, 2016
Publication date	Oct 26, 2021
Grant date	Oct 26, 2021

Abstract

A curable composition contains a resin containing a curable group, a colorant, a polymerization inhibitor, and a polymerization initiator. A manufacturing method of the curable composition includes a colorant dispersing step of mixing together the resin containing a curable group, the colorant, and the polymerization inhibitor and a mixing step of mixing together the colorant dispersion and the polymerization initiator so as to obtain the curable composition. A cured film is obtained by curing the curable composition. A color filter, a solid-state imaging element, and an infrared sensor have the cured film. A manufacturing method of the cured film includes a curable composition layer-forming step, an exposure step, and a development step.

First claim

What is claimed is:

1. A curable composition comprising:
a resin containing a curable group;
a colorant;
a polymerization inhibitor; and
a polymerization initiator,
wherein the resin contains a structural unit A containing a polymer chain and a structural unit B containing an acidic group,

the polymer chain contains a structural unit GF, and
the structural unit GF is selected from the group consisting of a structural unit formed of an oxyalkylene carbonyl group and a structural unit formed of an oxyalkylene group.

2. The curable composition according to claim 1 ,
wherein the resin contains an ethylenically unsaturated group,
a content of the ethylenically unsaturated group in the resin is 0.1 to 3.0 mmol/g, and
the ethylenically unsaturated group is a (meth)acryloyl group or a styryl group.

3. The curable composition according to claim 1 ,
wherein the polymer chain contains two or more kinds of the structural units GF.

4. The curable composition according to claim 1 ,
wherein the resin further contains at least one kind of structural unit selected from the group consisting of Formula A1 and Formula B1,

in Formula A1, R 1 represents a hydrogen atom or an alkyl group, X 1 represents a single bond or a divalent linking group, L 1 and L 2 represent the structural units GF that may be the same as or different from each other, p and q each represent an integer equal to or greater than 1, and Z 1 represents a group containing the curable group,
in Formula B1, R 1 represents a hydrogen atom or an alkyl group, X 2 represents a single bond or a divalent linking group, and Z 2 represents a group containing the curable group.

5. The curable composition according to claim 1 ,
wherein the resin further contains at least one kind of structural unit selected from the group consisting of Formula A1 and Formula B2,

in Formula A1, R 1 represents a hydrogen atom or an alkyl group, X 1 represents a single bond or a divalent linking group, L 1 and L 2 represent the structural units GF that may be the same as or different from each other, p and q each represent an integer equal to or greater than 1, and Z 1 represents a group containing the curable group,
in Formula B2, R 1 represents a hydrogen atom or an alkyl group, X 2 represents a single bond or a divalent linking group, and Z 2 represents a group containing the curable group.

6. The curable composition according to claim 1 ,
wherein the structural unit A is represented by Formula A0,

in Formula A0, R 1 represents a hydrogen atom or an alkyl group, X 3 represents a single bond or a divalent linking group, p represents an integer equal to or greater than 1, q represents 0 or an integer equal to or greater than 1, L 3 and L 4 each independently represent a linear or branched cyclic alkyl group having 2 to 6 carbon atoms, and Z 5 represents a hydrogen atom or a monovalent organic group.

7. The curable composition according to claim 1 ,
wherein a mass ratio of an amount of the resin contained in the curable composition to an amount of the colorant contained in the curable composition is 0.1 to 0.5.

8. The curable composition according to claim 1 ,
wherein the colorant contains a black pigment; and
a content of the black pigment with respect to a total solid content of the curable composition is equal to or greater than 50% by mass.

9. The curable composition according to claim 8 ,
wherein the black pigment contains at least one kind of compound selected from the group consisting of titanium oxynitride, titanium nitride, niobium oxynitride, niobium nitride, zirconium oxynitride, and zirconium nitride.

10. The curable composition according to claim 1 ,
wherein the polymerization initiator contains a photopolymerization initiator, and
a mass ratio of an amount of the photopolymerization initiator contained in the curable composition to an amount of the resin contained in the curable composition is 0.1 to 2.0.

11. The curable composition according to claim 1 ,
wherein the polymerization inhibitor is a free radical-based polymerization inhibitor.

12. The curable composition according to claim 11 ,
wherein the free radical-based polymerization inhibitor is a hindered amine compound.

13. The curable composition according to claim 1 , comprising:
two or more kinds of the polymerization inhibitors.

14. The curable composition according to claim 1 ,
wherein a total content of the polymerization inhibitors in the curable composition is 0.05% to 0.5% by mass.

15. The curable composition according to claim 1 ,
wherein in a cured film obtained by curing the curable composition, an optical density per film thickness of 1.0 μm is equal to or higher than 3.0 in a wavelength range of 400 to 1,100 nm.

16. The curable composition according to claim 1 , further comprising:
a polymerizable compound containing a cardo-skeleton.

17. A manufacturing method of the curable composition according to claim 1 , comprising:
a colorant dispersing step of mixing together the resin containing a curable group, the colorant, and the polymerization inhibitor so as to obtain a colorant dispersion; and
a mixing step of mixing together the colorant dispersion and the polymerization initiator so as to obtain the curable composition.

18. A cured film obtained by curing the curable composition according to claim 1 .

19. A color filter comprising:
the cured film according to claim 18 .

20. A solid-state imaging element comprising:
the cured film according to claim 18 .

21. A solid-state imaging device comprising;
the solid-state imaging element according to claim 20 .

22. An infrared sensor comprising:
the cured film according to claim 18 .

23. A manufacturing method of a cured film, comprising:
a curable composition layer-forming step of forming a curable composition layer by using the curable composition according to claim 1 ;
an exposure step of performing exposure by irradiating the curable composition layer with actinic rays or radiation; and
a development step of developing the curable composition layer having undergone exposure so as to form a cured film.

24. The manufacturing method of a cured film according to claim 23 , further comprising:
a heating step of heating the curable composition layer having undergone exposure between the exposure step and the development step.

Assignees

• Fujifilm Corp

Inventors

• OGAWA Michihiro
• FUKAMI Yutaro
• Ito Junichi
• Kaneko Yushi
• Idei Hiroaki
• Hamada Daisuke
• Ishikawa Tatsuo

Classifications

• H04N25/70

  SSIS architectures; Circuits associated therewith · CPC title

• G03F7/004 Primary

  Photosensitive materials (G03F7/12, G03F7/14 take precedence) · CPC title

• H04N23/12

  with one sensor only · CPC title

• H10F39/12

  Image sensors · CPC title

• G03F7/0007

  Filters, e.g. additive colour filters; Components for display devices · CPC title