Syn-gas system for generating power and hydrogen

Patent metadata

Field	Value
Publication number	US-11155463-B2
Application number	US-201916240543-A
Country	US
Kind code	B2
Filing date	Jan 4, 2019
Priority date	Jun 22, 2017
Publication date	Oct 26, 2021
Grant date	Oct 26, 2021

Abstract

A power generation system that includes a membrane reformer assembly, wherein syngas is formed from a steam reforming reaction of natural gas and steam, and wherein hydrogen is separated from the syngas via a hydrogen-permeable membrane, a combustor for an oxy-combustion of a fuel, an expander to generate power, and an ion transport membrane assembly, wherein oxygen is separated from an oxygen-containing stream to be combusted in the combustor. Various embodiments of the power generation system and a process for generating power using the same are provided.

First claim

The invention claimed is:

1. A syn-gas power generation system, comprising:
a membrane reformer assembly comprising
a first vessel with a first internal cavity having a heating zone with a heating zone inlet and a heating zone outlet, a reaction zone with a reaction zone inlet and a reaction zone outlet, and a sweep zone with a sweep zone inlet and a sweep zone outlet, wherein the reaction zone and the sweep zone are separated by a hydrogen-permeable membrane and the reaction zone contains a nickel-doped aluminum oxide catalyst;

a combustor comprising
a plurality of combustor feed inlets, and
an exhaust outlet,

wherein the combustor is located downstream of the membrane reformer assembly and at least one of said combustor feed inlets is fluidly connected to the reaction zone outlet via a syngas line; and
an expander located downstream of the combustor and fluidly connected to the exhaust outlet via an exhaust line,
wherein a natural gas/H 2 O stream is converted into a syngas stream in the reaction zone in the presence of the nickel-doped aluminum oxide catalyst, and at least a portion of molecular hydrogen present in the syngas stream is transported across the hydrogen-permeable membrane to the sweep zone leaving behind a hydrogen-depleted syngas stream in the reaction zone,
wherein the hydrogen-depleted syngas stream is combusted in the combustor to form an exhaust stream, and
wherein the exhaust stream is expanded in the expander to generate power,
the power generation system further comprising:
an ion transport membrane assembly comprising
a second vessel with a second internal cavity, and
an ion transport membrane that divides the second internal cavity into a feed zone and a permeate zone, wherein the feed zone has an ITM feed inlet and an ITM feed outlet and the permeate zone has a permeate zone inlet and a permeate zone outlet,

wherein at least a portion of molecular oxygen present in an oxygen-containing stream that is delivered to the feed zone is transported across the ion transport membrane to the permeate zone,
wherein the ion transport membrane assembly is located downstream of the membrane reformer assembly and the permeate zone inlet is fluidly connected to the heating zone outlet via a sweep gas line, and
wherein the ion transport membrane assembly is located upstream of the combustor and the permeate zone outlet is fluidly connected to one of said combustor feed inlets via an oxygen line.

2. The power generation system of claim 1 , further comprising:
a heat recovery steam generator located downstream of and fluidly connected to the expander via a second exhaust line, wherein the heat recovery steam generator generates steam by heat exchanging between a second water stream and the exhaust stream.

3. The power generation system of claim 1 , further comprising:
an exhaust recycle line that fluidly connects the exhaust line to the heating zone inlet of the membrane reformer assembly.

4. The power generation system of claim 2 , further comprising:
a high-pressure steam line fluidly connected to the heat recovery steam generator;
a gas mixer fluidly connected to a natural gas line and the high-pressure steam line, wherein the gas mixer mixes a natural gas stream with steam to form the natural gas/H 2 O stream; and
a reformer fuel line that fluidly connects the gas mixer to the reaction zone inlet of the membrane reformer assembly, wherein the reformer fuel line delivers the natural gas/H 2 O stream to the reaction zone.

5. The power generation system of claim 4 , wherein the gas mixer operates in a pressure range of 2 to 20 bars, and the system further comprises
a first compressor fluidly connected to the natural gas line, wherein the first compressor pressurizes the natural gas stream to a pressure range of 2 to 20 bars.

6. The power generation system of claim 4 , further comprising:
a second high-pressure steam line that fluidly connects the high-pressure steam line to the sweep zone inlet of the membrane reformer assembly, wherein the second high-pressure steam line delivers steam to the sweep zone to sweep the molecular hydrogen and to form a H 2 /H 2 O stream; and
a first condenser located downstream of the membrane reformer assembly and fluidly connected to the sweep zone outlet via a hydrogen line, wherein the first condenser condenses the H 2 /H 2 O stream to form a hydrogen stream and a first purified water stream.

7. The power generation system of claim 1 , further comprising:
an ITM compressor located upstream of the ion transport membrane assembly and fluidly connected to the ITM feed inlet via an ITM feed line, wherein the ITM compressor pressurizes the oxygen-containing stream; and
a turbine located downstream of the ion transport membrane assembly and fluidly connected to the ITM feed outlet via an oxygen-depleted line, wherein the turbine expands an oxygen-depleted stream that egresses the feed zone to generate power.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• MOKHEIMER Esmail Mohamed Ali
• Sanusi Yinka Sofihullahi
• Habib Mohamed A

Classifications

• C01B2203/041

  In-situ membrane purification during hydrogen production · CPC title

• C01B13/0251

  by making use of membranes · CPC title

• C01B2203/1058

  Nickel catalysts · CPC title

• C01B2203/0283

  containing a CO-shift step, i.e. a water gas shift step · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title