Hydrogen production from hydrocarbons with near zero greenhouse gas emissions

Patent metadata

Field	Value
Publication number	US-11155462-B2
Application number	US-201916505378-A
Country	US
Kind code	B2
Filing date	Jul 8, 2019
Priority date	Apr 8, 2019
Publication date	Oct 26, 2021
Grant date	Oct 26, 2021

Abstract

Methods and systems for producing hydrogen substantially without greenhouse gas emissions, the method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

First claim

What is claimed is:

1. A method for producing hydrogen substantially without greenhouse gas emissions, the method comprising the steps of:
producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source;
separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream comprising CO 2 ;
disposing the byproduct stream comprising CO 2 in an aqueous phase as a water soluble gas to form a CO 2 -rich water phase with a density greater than ambient groundwater;
injecting the byproduct stream into a reservoir containing mafic rock; and
allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

2. The method according to claim 1 , where the mafic rock comprises basaltic rock.

3. The method according to claim 1 , where before the step of injecting the byproduct stream into the reservoir, the byproduct stream is further treated to separate and purify CO 2 from other components to increase CO 2 concentration of the byproduct stream for injection into the reservoir.

4. The method according to claim 3 , further comprising the step of liquefying CO 2 in the byproduct stream for injection into the reservoir.

5. The method according to claim 1 , where the byproduct stream further comprises H 2 S.

6. The method according to claim 1 , further comprising the step of reacting the separated hydrogen with nitrogen to form compressed liquid ammonia.

7. The method according to claim 6 , further comprising the steps of transporting the compressed liquid ammonia and returning the compressed liquid ammonia to hydrogen and nitrogen via electrolysis for use of hydrogen as a hydrogen fuel source.

8. The method according to claim 1 , where the step of producing a product gas includes steam reforming or partial oxidation.

9. The method according to claim 1 , where the step of allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate produces precipitates selected from the group consisting of: calcium carbonates, magnesium carbonates, iron carbonates, and combinations thereof.

10. The method according to claim 1 , where the reservoir is between about 250 m and about 2,200 m below the surface and is between about 30° C. and about 325° C.

11. The method according to claim 1 , where the reservoir is between about 350 m and about 1,500 m below the surface and is less than about 325° C.

12. The method according to claim 1 , wherein a ratio of water in the aqueous phase to CO 2 in the byproduct stream comprising CO 2 is about 27 tons of H 2 O per 1 ton of CO 2 .

Assignees

• Saudi Arabian Oil Co

Inventors

• Arkadakskiy Serguey Viktorov
• Al-Utaibi Humoud W
• Kunnummal Noushad
• Ahmed Zeyad Tareq
• Al-Jar Faisal Salman
• Stapp Christopher Ellis

Classifications

• C01B2203/86

  Carbon dioxide sequestration · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/06

  Integration with other chemical processes · CPC title

• C01B2203/025

  containing a partial oxidation step · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title