Inorganic oxide material

Patent metadata

Field	Value
Publication number	US-11154840-B2
Application number	US-201415106480-A
Country	US
Kind code	B2
Filing date	Dec 23, 2014
Priority date	Dec 23, 2013
Publication date	Oct 26, 2021
Grant date	Oct 26, 2021

Abstract

The present teachings are directed to inorganic oxide materials that include Al2O3, CeO2, and at least one of MgO and Pr6O11. The present teachings are also directed to catalysts having at least one noble metal supported on these inorganic oxide materials, as well as methods for treating exhaust gases from internal combustion engines using such catalysts.

First claim

The invention claimed is:

1. An inorganic oxide material, consisting of:
Al 2 O 3 , CeO 2 , MgO and optionally oxides of one or more dopants; or
Al 2 O 3 , CeO 2 , MgO, Pr 6 O 11 and optionally oxides of one or more dopants;
wherein the dopant(s) being one or more selected from the group consisting of yttrium (Y), lanthanum (La), neodymium (Nd), samarium (Sa), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho) and erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), and scandium (Sc);
with the following proportions:
(a) from about 25 to about 90 pbw Al 2 O 3 ;
(b) from about 5 to about 35 pbw CeO 2 ;
(c)(i) from about 5 to about 35 pbw MgO, or
(c)(iii) from about 5 to about 35 pbw MgO, and from about 2 to about 20 pbw Pr 6 O 11 ; and
(d) optionally up to about 10 pbw of the oxides of one or more dopants; and
wherein the inorganic oxide material has:
a specific surface area after calcining at 900° C. for 2 hours of greater than or equal to 150 m 2 /g; or
a specific surface area after calcining at 1000° C. for 4 hours of greater than or equal to 85 m 2 /g; or
a specific surface area after calcining at 1100° C. for 5 hours of greater than or equal to 40 m 2 /g.

2. The inorganic oxide material of claim 1 , wherein the material comprises from about 40 to about 80 pbw Al 2 O 3 and from about 10 to about 30 pbw CeO 2 .

3. The inorganic oxide material of claim 1 , wherein the material comprises from about 10 to about 30 pbw MgO.

4. The inorganic oxide material of claim 1 , wherein the material comprises from about 5 to about 15 pbw Pr 6 O 11 .

5. The inorganic oxide material of claim 1 , wherein the material comprises from about 10 to about 30 pbw MgO and from about 5 to about 15 pbw Pr 6 O 11 .

6. The inorganic oxide material of claim 1 , wherein the material comprises from about 1 to about 10 pbw of an oxide or a mixture of oxides selected from Y 2 O 3 , La 2 O 3 , Nd 2 O 3 and Gd 2 O 3 .

7. The inorganic oxide material of claim 1 , wherein the material comprises from about 1 to about 4 pbw La 2 O 3 .

8. The inorganic oxide material of claim 1 , wherein the inorganic oxide material comprises (i) first crystallites comprising Al 2 O 3 and at least one oxide selected from MgO and Pr 6 O 11 , and (ii) second crystallites comprising CeO 2 , wherein the second crystallites have an average size after calcining at 1000° C. for 4 hours of less than or equal to 15 nm.

9. The inorganic oxide material of claim 1 , wherein the inorganic oxide material comprises (i) first crystallites comprising Al 2 O 3 and at least one oxide selected from MgO and Pr 6 O 11 , and (ii) second crystallites comprising CeO 2 , wherein the first crystallites comprise (i) Al 2 O 3 and MgO, and have an average size after calcining at 1000° C. for 4 hours of less than or equal to 13 nm or (ii) Al 2 O 3 and Pr 6 O 11 , and have an average size after calcining at 1000° C. for 4 hours of less than or equal to 39 nm, or (iii) a combination of (i) and (ii).

10. The inorganic oxide material of claim 1 , wherein the specific surface area of the inorganic oxide material after calcining at 900° C. for 2 hours is greater than or equal to about 160 m 2 /g.

11. The inorganic oxide material of claim 1 , wherein a total pore volume of the inorganic oxide material after calcining at 900° C. for 2 hours is greater than or equal to about 1.10 cm 3 /g.

12. A catalyst, comprising one or more noble metals supported on the inorganic oxide material of claim 1 .

13. A method for treating an exhaust gas from an internal combustion engine, the method comprising contacting the exhaust gas with the catalyst of claim 12 , such that the exhaust gas is treated.

14. The method of claim 13 , wherein CO, NO X , unburnt hydrocarbon, or any combination thereof, from the exhaust gas is eliminated.

15. A method for making a porous inorganic composite oxide comprising the inorganic oxide material of claim 1 , the method comprising:
(a) forming (i) particles comprising aluminum hydrate and at least one of magnesium hydrate and praseodymium hydrate and (ii) particles comprising cerium hydrate:
(1) simultaneously by forming (i) and (ii) in an aqueous medium at a temperature of greater than about 40° C. and a pH of from about 4 to about 10.5, or
(2) sequentially by forming (i) in an aqueous medium at a temperature of greater than 40° C., adjusting the pH of the aqueous medium to a pH of from about 4 to about 9, and forming (ii) in the aqueous medium; and

calcining the dried particles to form the porous inorganic composite oxide comprising the inorganic oxide material of claim 1 .

Assignees

• Rhodia Operations

Inventors

• Zhao Qiang
• Larcher Olivier
• Southward Barry W L
• Francis Francis
• English Thomas
• Ocampo Fabien

Classifications

• B01J23/63

  with rare earths or actinides · CPC title

• B01J37/03

  Precipitation; Co-precipitation · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01D2255/40

  Mixed oxides · CPC title