Porous polyester material

Patent metadata

Field	Value
Publication number	US-11154635-B2
Application number	US-201816470821-A
Country	US
Kind code	B2
Filing date	Jan 19, 2018
Priority date	Jan 31, 2017
Publication date	Oct 26, 2021
Grant date	Oct 26, 2021

Abstract

A polymeric material that includes a thermoplastic composition containing a continuous phase that includes a polyester and a copolyetherester elastomer is provided. The copolyetherester elastomer is dispersed within the continuous phase in the form of discrete domains. A porous network is defined within the thermoplastic composition that includes a plurality of nanopores.

First claim

What is claimed is:

1. A polymeric material in the form of a film, fiber, or molded article, wherein the polymeric material comprises a thermoplastic composition, the composition containing a continuous phase that contains a polyester, wherein a copolyetherester elastomer is dispersed within the continuous phase in the form of discrete domains and wherein the copolyetherester elastomer is present in the thermoplastic composition in an amount of from about 0.01 wt. % to about 15 wt. %, and wherein a porous network is defined within the thermoplastic composition that includes a plurality of nanopores, wherein the nanopores are distributed homogenously throughout the polymeric material.

2. The polymeric material of claim 1 , wherein the copolyetherester elastomer constitutes from about 0.05 wt. % to about 10 wt. % of the thermoplastic composition.

3. The polymeric material of claim 1 , wherein the polyester is polylactic acid.

4. The polymeric material of claim 1 , wherein the polyester is an aromatic polyester.

5. The polymeric material of claim 4 , wherein the aromatic polyester is polyethylene terephthalate.

6. The polymeric material of claim 1 , wherein the polyester has a glass transition temperature of about 0° C. or more.

7. The polymeric material of claim 1 , wherein the copolyetherester elastomer is a segmented block copolymer that has recurring long chain ester units and short chain ester units.

8. The polymeric material of claim 7 , wherein the long chain units are represented by the formula:
—OGO—C(O)—R—C(O)—

and the short chain ester units are represented by the structure:
—ODO—C(O)—R—C(O)—

wherein,
G is a divalent group that is derived from one or more high molecular weight alcohols;
R is a hydrocarbon group derived from one or more dicarboxylic acids; and
D is a divalent group derived from one or more low molecular weight diols.

9. The polymeric material of claim 7 , wherein the long chain units are formed from the reaction product of a high molecular weight alcohol with a dicarboxylic acid.

10. The polymeric material of claim 9 , wherein the alcohol is a polymeric glycol.

11. The polymeric material of claim 7 , wherein the short chain ester units are formed from the reaction of a low molecular weight diol with a dicarboxylic acid.

12. The polymeric material of claim 11 , wherein the low molecular weight diol includes ethylene glycol, propylene glycol, 1,4-butanediol, 1,6-hexamethylene glycol, dihydroxycyclohexane, cyclohexane dimethanol, resorcinol, hydroquinone, 1,5-dihydroxynaphthalene, bisphenol A, or an ester derivative thereof.

13. The polymeric material of claim 8 , wherein the dicarboxylic acid includes an aromatic dicarboxylic acid.

14. The polymeric material of claim 1 , wherein the nanopores have an average cross-sectional dimension of about 800 nanometers or less.

15. The polymeric material of claim 1 , wherein nanopores have an average axial dimension of from about 100 to about 5000 nanometers.

16. The polymeric material of claim 1 , wherein the continuous phase constitutes from about 60 wt. % to about 99 wt. % of the thermoplastic composition.

17. The polymeric material of claim 1 , wherein the copolyetherester elastomer is dispersed in the form of nano-scale domains.

18. The polymeric material of claim 1 , wherein the composition further comprises a microinclusion additive dispersed within the continuous phase in the form of discrete domains.

19. The polymeric material of claim 1 , wherein the porous network further includes micropores.

20. A fiber comprising the polymeric material of claim 1 .

21. A nonwoven web comprising the fiber of claim 20 .

22. An absorbent article that includes a substantially liquid-impermeable layer, liquid-permeable layer, and an absorbent core, wherein the substantially liquid-impermeable layer, the liquid-permeable layer, or both include the polymeric material of claim 1 .

23. A method for forming a polymeric material in the form of a fiber, film, or molded article, the method comprising:
forming a thermoplastic composition that contains a continuous phase that includes a polyester and a copolyetherester elastomer that is dispersed within the continuous phase in the form of discrete domains wherein the copolyetherester elastomer is present in the thermoplastic composition in an amount of from about 0.01 wt. % to about 15 wt. %; and
solid state drawing the thermoplastic composition to form a porous network therein, the porous network including a plurality of nanopores, wherein the nanopores are distributed homogenously throughout the polymeric material.

24. The method of claim 23 , wherein the thermoplastic composition is drawn to a stretch ratio of from about 1.1 to about 25.

25. The method of claim 23 , wherein the thermoplastic composition is drawn at a temperature of from about −50° C. to about 150° C.

26. A method for forming a fiber, the method comprising:
forming a thermoplastic composition that contains a continuous phase that includes a polyester and a copolyetherester elastomer that is dispersed within the continuous phase in the form of discrete domains wherein the copolyetherester elastomer is present in the thermoplastic composition in an amount of from about 0.01 wt. % to about 15 wt. %;
extruding the composition through a capillary to form the fiber; and
drawing the fiber at a temperature that is lower than the melting temperature of the polyester, thereby forming a porous network that includes a plurality of nanopores, wherein the nanopores are distributed homogenously throughout the fiber.

Assignees

• Kimberly Clark Co

Inventors

• Mceneany Ryan J
• Xu Yuewen

Classifications

• D04H3/005 Primary

  Synthetic yarns or filaments (D04H3/013 takes precedence) · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08J9/00

  Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof (mechanical aspects of shaping of plastics or substances in a plastic state for the production of porous or cellular articles B29C) · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title