Thermal analysis for source rocks

Patent metadata

Field	Value
Publication number	US-11150206-B2
Application number	US-201916569468-A
Country	US
Kind code	B2
Filing date	Sep 12, 2019
Priority date	Sep 12, 2019
Publication date	Oct 19, 2021
Grant date	Oct 19, 2021

Abstract

A system and method for evaluating a geological formation including subjecting a source-rock sample from the geological formation to atomic force microscopy (AFM) to determine a thermal property or material property of the source-rock sample. The properties determined may include thermal conductivity or material transition temperature.

First claim

What is claimed is:

1. A method of evaluating a geological formation, comprising:
preparing a source-rock sample from the geological formation;
acquiring a topography map of a region of the source-rock sample at a resolution less than 1 micrometer (μm);
selecting measurement areas of the region based on the topography map; and
determining material transition temperature of the source-rock sample at the measurement areas at a scale less than 1 millimeter via atomic force microscopy (AFM) with an AFM instrument, wherein the AFM instrument comprises a cantilever comprising a cantilever tip.

2. The method of claim 1 , comprising determining thermal expansion of the source-rock sample at the measurement areas at the scale less than 1 millimeter via the AFM instrument.

3. The method of claim 1 , comprising determining crosslink density of the source-rock sample at the measurement areas at the scale less than 1 millimeter via the AFM instrument.

4. The method of claim 1 , wherein the material transition temperature comprises glass transition temperature (Tg).

5. The method of claim 1 , wherein the material transition temperature comprises melting point temperature (Tm).

6. The method of claim 1 , wherein the measurement areas each comprise a width in a range of 10 μm to 500 μm and a length in a range of 10 μm to 500 μm.

7. The method of claim 1 , comprising sensing deflection of the cantilever as affected by interaction of the cantilever tip with a surface of the source-rock sample.

8. The method of claim 1 , comprising applying voltage to the cantilever tip.

9. The method of claim 1 , comprising measuring a diameter of the cantilever tip.

10. The method of claim 1 , comprising generating a calibration curve with the AFM instrument by measuring material transition temperature of standards samples each having a known material transition temperature.

11. The method of claim 1 , comprising choosing the region as a region of interest identified based on a reflected-light optical image of the source-rock sample.

12. The method of claim 1 , comprising selecting the region as a region of interest identified based on analysis of the source-rock sample, the analysis comprising scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), fluorescence, AFM-infrared red (IR), or Fourier-transform infrared spectroscopy (FTIR), or any combinations thereof.

13. The method of claim 1 , comprising identifying organic domains of the region based on the topography map, wherein selecting comprises selecting measurement areas of the region based on the organic domains and on the topography map.

14. The method of claim 1 , wherein the AFM comprises nanothermal analysis (nanoTA), and wherein the AFM instrument is in nanoTA mode.

15. The method of claim 14 , wherein determining the material transition temperature comprises collecting nanoTA data at each measurement area over a temperature ramp of the cantilever tip from a first temperature to a second temperature.

16. The method of claim 15 , wherein the first temperature comprises room temperature, and wherein the second temperature comprises less than 500° C.

17. The method of claim 15 , wherein the nanoTA data comprises deflection of the cantilever versus temperature of the cantilever tip, wherein the deflection is in response to contact of the cantilever tip with the sample.

18. The method of claim 15 , comprising performing a topography scan and measuring height, indention, and lateral extent of thermal damage of the region caused by collecting the nanoTA data.

19. The method of claim 1 , comprising determining material differences in organic domains in the measurement areas based on deflection of the cantilever tip versus temperature of the cantilever tip.

20. A method of evaluating a geological formation, comprising:
mounting a source-rock sample from the geological formation to a sample holder of an atomic force microscopy (AFM) instrument, the source-rock sample mounted with a specified orientation relative to bedding of the source-rock sample;
identifying a region of interest of the source-rock sample by analysis of the source-rock sample; and
determining a material property of organic domains of the region via the AFM instrument in nanothermal analysis (nanoTA) mode.

21. The method of claim 20 , wherein the analysis is via a reflected-light optical image of the source-rock sample.

22. The method of claim 20 , wherein determining the material property comprises collecting nanoTA data for the region at a resolution less than 1 micrometer at a selected ramp rate for temperature of the source-rock sample, wherein the region comprises a width and length each less than 1 millimeter.

23. The method of claim 22 , comprising collecting topography of the region at the resolution.

24. The method of claim 20 , comprising checking diameter of a cantilever tip of the AFM instrument.

25. The method of claim 20 , wherein the material property comprises material transition temperature comprising glass transition temperature (Tg) or melting point (Tm).

26. The method of claim 20 , wherein the material property comprises crosslink density.

27. The method of claim 20 , wherein the material property comprises thermal expansion.

28. The method of claim 20 , wherein determining the material property comprises determining thermal damage of the organic domains.

Assignees

• Saudi Arabian Oil Co

Inventors

• Eichmann Shannon L
• Hull Katherine Leigh
• Abousleiman Younane N
• Jacobi David

Classifications

• G01N25/18 Primary

  by investigating thermal conductivity (by calorimetry G01N25/20; by measuring change of resistance of an electrically-heated body G01N27/18) · CPC title

• G01N33/241

  for hydrocarbon content · CPC title

• G01Q60/58 Primary

  SThM [Scanning Thermal Microscopy] or apparatus therefor, e.g. SThM probes · CPC title

• G01Q60/42

  Functionalisation · CPC title