Aqueous dispersion, coating film, and laminate

Patent metadata

Field	Value
Publication number	US-11149162-B2
Application number	US-201716300146-A
Country	US
Kind code	B2
Filing date	May 10, 2017
Priority date	May 13, 2016
Publication date	Oct 19, 2021
Grant date	Oct 19, 2021

Abstract

The present invention provides an aqueous dispersion comprising, (A) a highly modified polyolefin of a polyolefin (a) having a structural unit derived from ethylene and a structural unit derived from propylene and having a melting peak observed by differential scanning calorimetric analysis, by an α,β-unsaturated carboxylic acid compound, (B) a polyolefin (B-1) having a structural unit derived from at least one olefin selected from the group consisting of ethylene and α-olefins having 3 to 20 carbon atoms, and/or a lowly modified polyolefin (B-2) of the polyolefin (B-1) by an α,β-unsaturated carboxylic acid compound, and (C) a basic compound, wherein a mass ratio ((A)/(B)) of the component (A) and the component (B) is 60/40 to 97.5/2.5.

First claim

The invention claimed is:

1. An aqueous dispersion comprising:
(A) a highly modified polyolefin of a polyolefin (a) having a structural unit derived from ethylene and a structural unit derived from propylene and having a melting peak observed by differential scanning calorimetric analysis, by an α,β-unsaturated carboxylic acid compound;
(B) a polyolefin (B-1) having a structural unit derived from at least one olefin selected from the group consisting of ethylene and α-olefins having 3 to 20 carbon atoms, and/or a lowly modified polyolefin (B-2) of the polyolefin (B-1) by an α,β-unsaturated carboxylic acid compound; and
(C) a basic compound;
wherein a mass ratio ((A)/(B)) of the component (A) and the component (B) is 60/40 to 97.5/2.5; and
wherein a melting point of the component (A), as measured by differential scanning calorimetric analysis, is 110° C. or less.

2. The aqueous dispersion according to claim 1 , wherein the component (A) is a highly graft-modified polyolefin of the polyolefin (a) by an α,β-unsaturated carboxylic acid compound, and the component (B-2) is a lowly graft-modified polyolefin of the polyolefin (B-1) by an α,β-unsaturated carboxylic acid compound.

3. The aqueous dispersion according to claim 1 , wherein an amount of a structural unit derived from an α,β-unsaturated carboxylic acid compound chemically bound to the polyolefin (a) in the component (A) is 2.0 to 50 parts by mass relative to 100 parts by mass of the component (A).

4. The aqueous dispersion according to claim 1 , wherein the structural unit derived from ethylene in the polyolefin (a) occupies 5 to 30 mol % based on the total structural unit forming the polyolefin (a).

5. The aqueous dispersion according to claim 1 , wherein a weight average molecular weight of the component (A) is 20000 to 200000.

6. The aqueous dispersion according to claim 1 , wherein an amount of a structural unit derived from an α,β-unsaturated carboxylic acid compound chemically bound to the polyolefin (B-1) in the polyolefin (B-2) is 0.001 parts by mass or more and less than 2.0 parts by mass relative to 100 parts by mass of the polyolefin (B-2).

7. The aqueous dispersion according to claim 1 , wherein a weight average molecular weight of the component (B) is 5000 to 450000.

8. The aqueous dispersion according to claim 1 , wherein a volume-based average particle size of a dispersoid in the aqueous dispersion is 2 μm or less.

9. The aqueous dispersion according to claim 1 , wherein a proportion of a dispersoid having a particle size of 2 μm or more in the total dispersoid in the aqueous dispersion is 5% or less.

10. The aqueous dispersion according to claim 1 , wherein the component (C) is an organic amine compound.

11. A coating film comprising:
(A) a highly modified polyolefin of a polyolefin (a) having a structural unit derived from ethylene and a structural unit derived from propylene and having a melting peak observed by differential scanning calorimetric analysis, by an α,β-unsaturated carboxylic acid compound;
(B) a polyolefin (B-1) having a structural unit derived from at least one olefin selected from the group consisting of ethylene and α-olefins having 3 to 20 carbon atoms, and/or a lowly modified polyolefin (B-2) of the polyolefin (B-1) by an α,β-unsaturated carboxylic acid compound; and
(C) a basic compound;
wherein a mass ratio ((A)/(B)) of the component (A) and the component (B) is 60/40 to 97.5/2.5; and
wherein a melting point of the component (A), as measured by differential scanning calorimetric analysis, is 110° C. or less.

12. A coating film formed from the aqueous dispersion according to claim 1 .

13. A laminate comprising, a substrate having a non-polar surface, and the coating film according to claim 11 , laminated on the non-polar surface of the substrate.

14. The laminate according to claim 13 , wherein the substrate having a non-polar surface is a substrate made of polyolefin.

15. The laminate according to claim 13 , further comprising a substrate having a polar surface, laminated on a surface of the coating film opposite to the substrate having the non-polar surface.

Assignees

• Sumitomo Chemical Co

Inventors

• Nakajima Hideto
• Morimoto Junji

Classifications

• C09D151/06 Primary

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08K5/17 Primary

  Amines; Quaternary ammonium compounds · CPC title

• C08L23/26

  modified by chemical after-treatment (saponified copolymers C08L23/0861; unsaturated acid salts C08L23/0876) · CPC title

• C08L23/08

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title