Alkylene oxide polymerization using a double metal cyanide catalyst complex and a magnesium, group 3-group 15 metal or lanthanide series metal compound

Patent metadata

Field	Value
Publication number	US-11149117-B2
Application number	US-201916354114-A
Country	US
Kind code	B2
Filing date	Mar 14, 2019
Priority date	Dec 27, 2010
Publication date	Oct 19, 2021
Grant date	Oct 19, 2021

Abstract

Alkylene oxide polymerizations are performed in the presence of a double metal cyanide polymerization catalyst and certain magnesium, Group 3-Group 15 metal or lanthanide series metal compounds. The presence of the magnesium, Group 3-Group 15 metal or lanthanide series metal compound provides several benefits including more rapid catalyst activation, faster polymerization rates and the reduction in the amount of ultra high molecular weight polymers that are formed. The catalyst mixture is unexpectedly useful in making polyethers having low equivalent weights.

First claim

What is claimed is:

1. A method for producing a polyether monol or polyether polyol product, comprising polymerizing at least one alkylene oxide in the presence of a double metal cyanide catalyst complex and a metal compound in which a metal selected from the group consisting of magnesium, scandium, yttrium, lanthanum, titanium, zirconium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, silver, gold, zinc, cadmium, mercury, tellurium, germanium, tin, lead, antimony, bismuth, and the lanthanide series metals including those having atomic numbers from 58 to 71 is bonded to at least one alkoxide, aryloxy, carboxylate, acyl, pyrophosphate, phosphate, thiophosphate, dithiophosphate, phosphate ester, thiophosphate ester, amide, siloxide, hydride, carbamate or hydrocarbon anion, and wherein the metal compound is devoid of halide anions.

2. The method of claim 1 which includes the steps of:
combining (a) the double metal cyanide catalyst complex (b) the metal compound, (c) at least one initiator compound, and (d) at least one alkylene oxide to form a starting reaction mixture,
heating the starting reaction mixture to polymerization conditions until the double metal cyanide catalyst complex becomes activated, and then
feeding additional alkylene oxide to the reaction mixture under polymerization conditions.

3. The method of claim 1 which includes the steps of:
establishing steady-state concentrations of 1) the DMC catalyst, 2) the metal compound, 3) at least one initiator, 4) at least one alkylene oxide and 5) polymerizate in a continuous reactor under polymerization conditions,
continuously adding additional initiator, alkylene oxide, DMC catalyst complex, additional metal compound, or a catalyst mixture formed by combining the DMC catalyst complex and metal compound, to the continuous reactor under polymerization conditions and continuously withdrawing a product stream containing polyether monol or polyether polyol product from the continuous reactor.

4. The method of claim 1 wherein the metal compound is a separately added material not present during a preparation of the double metal cyanide catalyst.

Assignees

• Dow Global Technologies Llc

Inventors

• Laitar David S
• Babb David A
• Villa Carlos M
• Keaton Richard
• Masy Jean-Paul

Classifications

• C08G65/34

  from hydroxy compounds or their metallic derivatives {(C08G65/26 takes precedence)} · CPC title

• C08G65/269

  Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ · CPC title

• C07C41/02

  from oxiranes · CPC title

• C08G65/2663 Primary

  Metal cyanide catalysts, i.e. DMC's · CPC title

• C08G65/00 Primary

  Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule · CPC title