Method of treating a neutralized aralkyl hydroperoxide cleavage stream

Patent metadata

Field	Value
Publication number	US-11148987-B2
Application number	US-201816640615-A
Country	US
Kind code	B2
Filing date	Aug 22, 2018
Priority date	Aug 23, 2017
Publication date	Oct 19, 2021
Grant date	Oct 19, 2021

Abstract

A method of reducing the salt content of a neutralized aralkyl hydroperoxide cleavage mass stream comprising passing the neutralized stream into a vessel, the vessel having an inlet, two outlets, an aqueous layer and a hydrocarbon layer wherein the neutralized stream enters the vessel through a first inlet and a hydrocarbon stream exits the vessel through a first outlet that is in fluid communication with the hydrocarbon layer.

First claim

That which is claimed is:

1. A method of reducing the salt content of a neutralized aralkyl hydroperoxide cleavage mass stream comprising passing the neutralized stream into a vessel, the vessel having an inlet, two outlets, an aqueous layer and a hydrocarbon layer wherein the neutralized stream enters the vessel through a first inlet and a hydrocarbon stream exits the vessel through a first outlet that is in fluid communication with the hydrocarbon layer.

2. The method of claim 1 wherein the neutralized aralkyl hydroperoxide cleavage mass stream comprises one or more of phenol, acetone, alpha-methyl styrene, cumene, cumyl phenol, dimethylbenzyl alcohol, acetophenone, alpha-methyl styrene dimers, tars, heavies.

3. The method of claim 2 wherein the neutralized aralkyl hydroperoxide cleavage mass stream further comprises salts produced in a neutralization step.

4. The method of claim 1 wherein the hydrocarbon layer is less dense than the aqueous layer.

5. The method of claim 1 wherein the first inlet is in fluid communication with the aqueous layer.

6. The method of claim 1 wherein the first inlet is a diffuser with a plurality of openings to allow the neutralized stream to enter the vessel at a plurality of locations.

7. The method of claim 1 wherein the second outlet is in fluid communication with the aqueous layer.

8. The method of claim 1 wherein the first outlet is located vertically above the first inlet.

9. The method of claim 1 wherein the first outlet is a floating suction that is positioned at or near the top of the hydrocarbon layer.

10. The method of claim 1 wherein the first outlet is located on a wall of the vessel.

11. The method of claim 10 further comprising controlling the level in the vessel such that the first outlet is in fluid communication with the hydrocarbon layer.

12. The method of claim 11 wherein the vessel further comprises additional outlets at lower levels that can be used as outlets for the hydrocarbon stream.

13. The method of claim 12 wherein one additional outlet is positioned between the top of the hydrocarbon layer and the interface between the hydrocarbon layer and the aqueous layer.

14. The method of claim 12 wherein one additional outlet is positioned at or near the interface between the hydrocarbon layer and the aqueous layer.

15. The method of claim 1 further comprising controlling the level of the interface between the hydrocarbon layer and the aqueous layer.

16. The method of claim 15 wherein the level of the interface is controlled by controlling the flow through the second outlet.

17. The method of claim 1 wherein the neutralized stream enters the vessel, passes through the aqueous layer and at least a portion of the stream passes into the hydrocarbon layer.

18. The method of claim 17 wherein the portion of the neutralized stream that passes into the hydrocarbon layer has a lower salt content than the neutralized stream that enters the vessel.

19. The method of claim 1 further comprising cooling or heating the neutralized aralkyl hydroperoxide cleavage mass stream before it enters the first inlet into the vessel.

20. The method of claim 1 further comprising adding an aqueous stream to the neutralized aralkyl hydroperoxide cleavage mass stream.

21. The method of claim 1 wherein an aqueous stream is recirculated from the vessel to be combined with the neutralized aralkyl hydroperoxide cleavage mass stream.

22. The method of claim 1 further comprising washing the neutralized aralkyl hydroperoxide cleavage mass stream in a wash step and/or washing the hydrocarbon stream that exits the vessel through the first outlet.

Assignees

• Shell Oil Co

Inventors

• Mccauley Garry Morgan
• Juliette Jamie Jerrick
• Faske David Randall
• Porter Thomas Robert

Classifications

• C07C37/72 Primary

  by liquid-liquid treatment · CPC title

• C07C45/80

  by liquid-liquid treatment · CPC title

• C07C49/08

  Acetone · CPC title

• C07C39/04

  Phenol · CPC title