Method for manufacturing inkjet printable paper or foil for use as a decor paper or foil

Patent metadata

Field	Value
Publication number	US-11148451-B2
Application number	US-201816620165-A
Country	US
Kind code	B2
Filing date	Jun 12, 2018
Priority date	Jun 14, 2017
Publication date	Oct 19, 2021
Grant date	Oct 19, 2021

Abstract

A method is provided for manufacturing a paper or a thermoplastic foil or a vitrimeric foil printable with an inkjet printer for use as a decor paper, respectively a decor foil in a laminate or laminated panel. The method may involve providing a paper layer, respectively a foil. At least one side of the paper layer, respectively of the foil, may be coated with an inkjet receiver coating that includes at least pigment and binder. The inkjet receiver coating may include an ink reactive compound. The papers and foils may be provided with a printed pattern and used as a decor in the panels.

First claim

The invention claimed is:

1. A method for manufacturing a paper printable with an inkjet printer for use as a decor paper in a laminate panel, the method comprising:
providing a paper layer having mean air resistance with a Gurley value of 30 seconds or below; and
coating at least one side of the paper layer, with an inkjet receiver coating that includes pigment and binder;
wherein the inkjet receiver coating includes an ink reactive compounds; and
wherein the obtained paper has a Gurley value of between 30 and 120 seconds.

2. The method according to claim 1 , wherein the ink reactive compound comprises a polyionic polymer.

3. The method according to claim 1 , wherein the ink reactive compound comprises a substance altering the pH of the inkjet receiver coating.

4. The method according to claim 3 , wherein the substance is chosen from the group consisting of formic acid, tartaric acid, acetic acid, hydrochloric acid, citric acid, phosphoric acid, sulfuric acid, AlCl 3 and boronic acid.

5. The method according to claim 1 , wherein the ink reactive compound comprises a metal salt.

6. The method according to claim 5 , wherein the metal salt is chosen from the group consisting of CaCl 2 , MgCl 2 , CaBr, MgBr 2 , CMA (calcium magnesium acetate), NH 4 Cl, Calcium Acetate, ZrCl 4 and magnesium acetate.

7. The method according to claim 1 , wherein the ink reactive compound comprises a flocculating agent.

8. The method according to claim 7 , wherein the flocculating agent is chosen from the group consisting of sodiumaluminate, a double sulphate salt, polyaluminumchloride, polyacrylate, dicyandiamide and polyacrylamide.

9. The method according to claim 1 , wherein coating with the inkjet receiver coating involves applying a first layer of a first composition, and subsequently applying a second layer of a second composition;
wherein the first and the second compositions include the binder.

10. The method according to claim 9 , wherein the first layer and the second layer differ in that they show one or more of the following properties:
the property that the first layer and the second layer comprise pigment and binder in a different pigment to binder ratio;
the property that the dry weight of material applied for the first layer and the second layer is different;
the property that the first layer and the second layer comprise pigment and binder, wherein the average particle size of the pigments contained in the first layer is larger than the average particle size of the pigments contained in the second layer;
the property that the first layer and the second layer comprise an ink reactive compound in a different composition;
the property that the second layer comprises a higher amount of the ink reactive compound than the first layer;
the property that the first layer comprises pigment and binder, while the second layer is free from pigments, or at least comprises less pigment than the first layer, or comprises less than 10% of the pigment content of the first layer.

11. A method for manufacturing a paper printable with an inkjet printer for use as a decor paper in a laminate panel, the method comprising:
providing a paper layer having a mean air resistance with a Gurley value of 30 seconds or below; and
coating at least one side of the paper layer with a composition to form an inkjet receiver coating;
wherein the composition has a pH of 3 or lower; and
wherein the obtained paper has a Gurley value of between 30 and 120 seconds.

12. A paper having at least one side provided with an inkjet receiver coating comprising at least pigment and binder;
wherein the inkjet receiver coating includes an ink reactive compound;
wherein the inkjet receiver coating has a pigment to binder ratio between 0.1/1 and 25/1 ; and
wherein the paper has a mean air resistance with a Gurley value of between 30 and 120 seconds.

13. The paper according to claim 12 , wherein the paper comprises from 0.2 to 10 g/m 2 dry coating weight of the ink reactive compound.

14. The paper according to claim 12 , wherein the paper comprises from 0.2 to 10 g/m 2 dry coating weight of pigment.

15. The paper according to claim 12 , wherein the paper fad shows one or more of the following properties:
the paper has a surface substantially formed by the binder and/or the ink reactive compound;
the paper is provided with pigment in an amount having a particle surface area between 100 and 16000 m 2 surface of pigment/m 2 surface of paper;
the paper comprises from 0.05 to 5 g/m 2 dry coating weight of a crosslinking agent;
the paper comprises from 0.05 to 5 g/m 2 dry coating weight of a particle surface modifying agent;
the paper comprises from 0.005 to 2 g/m 2 dry coating weight of a wetting agent;
the paper comprises from 0.005 to 2 g/m 2 dry coating weight of a defoaming agent;
the paper comprises from 0.005 to 2 g/m 2 dry coating weight of a fungicide.

Assignees

• Unilin Bv
• Flooring Ind Ltd Sarl

Inventors

• Clement Benjamin
• Ide Matthias
• Ledegen Sam

Classifications

• B44C5/0469

  comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper · CPC title

• B41M5/5263

  characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• B41M5/5254

  characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers · CPC title

• B41M5/5227

  characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants · CPC title

• B41M5/5218

  characterised by inorganic additives, e.g. pigments, clays · CPC title