Biodegradable magnesium alloys, methods of manufacture thereof and articles comprising the same
US-2016194738-A1 · Jul 7, 2016 · US
US11148197B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11148197-B2 |
| Application number | US-201816117324-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 30, 2018 |
| Priority date | Aug 31, 2017 |
| Publication date | Oct 19, 2021 |
| Grant date | Oct 19, 2021 |
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A raw material for thixomolding includes a magnesium-based alloy powder which contains calcium in an amount of 0.2 mass % or more and 5 mass % or less and aluminum in an amount of 2.5 mass % or more and 12 mass % or less, wherein the magnesium-based alloy powder includes an oxide layer which has an average thickness of 30 nm or more and 100 nm or less and contains at least one of calcium and aluminum as an outermost layer. The average dendrite secondary arm spacing of crystal structures of the magnesium-based alloy powder is preferably 5 μm or less.
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What is claimed is: 1. A raw material for thixomolding, comprising: a magnesium-based alloy powder which contains calcium in an amount of 0.2 mass % or more and 5 mass % or less and aluminum in an amount of 2.5 mass % or more and 12 mass % or less, wherein the magnesium-based alloy powder is produced by an atomization method, an average particle diameter of the magnesium-based alloy powder is 2.0 mm or more and 5.0 mm or less, an average aspect ratio of the magnesium-based powder that is an average of aspect ratios calculated by ((a minor axis)/(a major axis)) is 0.5 or more and 1 or less, and the magnesium-based alloy powder includes an oxide layer which has an average thickness of 30 nm or more and 100 nm or less and contains at least one of calcium and aluminum as an outermost layer. 2. The raw material for thixomolding according to claim 1 , wherein an average dendrite secondary arm spacing of crystal structures of the magnesium-based alloy powder is 5 μm or less. 3. A molded body, comprising the raw material for thixomolding according to claim 2 . 4. The raw material for thixomolding according to claim 1 , wherein a minimum particle diameter of the magnesium-based alloy powder is 0.5 mm or more. 5. A molded body, comprising the raw material for thixomolding according to claim 4 . 6. A molded body, comprising the raw material for thixomolding according to claim 1 . 7. The raw material for thixomolding according to claim 1 , wherein an average circularity of the magnesium-based alloy powder is 0.5 or more and 1 or less. 8. A molded body, comprising the raw material for thixomolding according to claim 7 . 9. The raw material for thixomolding according to claim 1 , wherein when the oxide layer contains the calcium, a concentration of the calcium in the oxide layer is 2 times or more, and when the oxide layer contains the aluminum, a concentration of the aluminum in the oxide layer is 2 times or more. 10. A molded body, comprising the raw material for thixomolding according to claim 9 . 11. A raw material for thixomolding, comprising: a magnesium-based alloy powder which contains calcium in an amount of 0.2 mass % or more and 5 mass % or less and aluminum in an amount of 2.5 mass % or more and 12 mass % or less, wherein the calcium and aluminum are segregated at a crystal grain boundary; an average particle diameter of the magnesium-based alloy powder is 2.0 mm or more and 5.0 mm or less: an average aspect ratio of the magnesium-based alloy powder that is an average of aspect ratios calculated by ((a minor axis)/(a major axis)) is 0.5 or more and 1 or less; and the magnesium-based alloy powder includes an oxide layer which has an average thickness of 30 nm or more and 100 nm or less and contains a mixture of oxides of magnesium, calcium, and aluminum as an outermost layer; and at locations of a surface of the powder where the crystal grain boundary appears, the thickness of the oxide layer is greater than at locations of the surface of the powder where the crystal grain boundary does not appear.
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