Positive electrode active material and preparation method thereof, positive electrode plate, secondary battery, battery module, battery pack, and electric apparatus
US-2024429384-A1 · Dec 26, 2024 · US
US11145859B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11145859-B2 |
| Application number | US-201816234646-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 28, 2018 |
| Priority date | Oct 27, 2017 |
| Publication date | Oct 12, 2021 |
| Grant date | Oct 12, 2021 |
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The present disclosure relates to a metal oxide nanosheet-sulfur nanocomposite containing sulfur nanoparticles grown directly on each of exfoliated metal oxide nanosheets, and a lithium-sulfur battery including a sulfur cathode containing the metal oxide nanosheet-sulfur nanocomposite.
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We claim: 1. A metal oxide nanosheet-sulfur nanocomposite, comprising elemental sulfur nanoparticles chemically grown directly on each of exfoliated 2-dimensional metal oxide nanosheets, wherein the exfoliated metal oxide nanosheets comprise a nanosheet of titanium oxide selected from the group consisting of lepidocrocite, trititanate, tetratitanate, and pentatitanate. 2. The metal oxide nanosheet-sulfur nanocomposite of claim 1 , wherein the exfoliated metal oxide nanosheets further comprise a nanosheet of oxide of metal selected from the group consisting of Co, Cu, Zn, Mn, V, Mo, and combinations thereof. 3. The metal oxide nanosheet-sulfur nanocomposite of claim 1 , wherein the sulfur content is at least 80 parts by weight based on 100 parts by weight of the metal oxide nanosheet-sulfur nanocomposite. 4. A lithium-sulfur battery, comprising a sulfur cathode comprising the metal oxide nanosheet-sulfur nanocomposite according to claim 1 . 5. The lithium-sulfur battery of claim 4 , wherein the sulfur content is at least 80 parts by weight based on 100 parts by weight of the metal oxide nanosheet-sulfur nanocomposite. 6. The lithium-sulfur battery of claim 4 , wherein dissolution of lithium polysulfide in the sulfur cathode is suppressed by the metal oxide nanosheet-sulfur nanocomposite. 7. The lithium-sulfur battery of claim 4 , wherein the exfoliated metal oxide nanosheets further comprise a nanosheet of oxide of metal selected from the group consisting of Cu, Zn, V, Mo, and combinations thereof.
of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates · CPC title
Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title
of elements or alloys · CPC title
as layered products · CPC title
Li-accumulators · CPC title
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