Purification of feedstock by heat treatment

Patent metadata

Field	Value
Publication number	US-11142722-B2
Application number	US-201716322835-A
Country	US
Kind code	B2
Filing date	Aug 1, 2017
Priority date	Aug 5, 2016
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

Present invention relates to a novel process for purification of feedstock for further use as a source of fuel or chemicals.

First claim

The invention claimed is:

1. A process for purifying a feedstock, the process comprising:
a) providing a feedstock containing impurities, wherein the feedstock comprises:
one or more of animal fat, tall oil pitch, sludge palm oil or used cooking oil or any combinations thereof;
b) adding to the feedstock phosphoric acid or sulfuric acid forming an admixture, and adjusting a water content of the admixture as a whole to about 0.05 wt % to about 10 wt %;
c) heating the admixture to a temperature of 200° C. to 280° C.;
d) optionally removing water; and
e) removing a separate phase containing impurities from the feedstock from the heated admixture to obtain a purified feedstock.

2. The process according to claim 1 , comprising adjusting the water content of the admixture as a whole to about 0.1 wt % to about 5 wt %.

3. The process according to claim 1 , wherein the feedstock further comprises:
one or more of a residual bottom fraction from tall oil distillation processes, animal based oils, vegetable or plant based oils or fats, microbial or algae oils, free fatty acids, or any lipids containing phosphorous and/or metals, oils originating from yeast or mould products, oils originating from biomass, rapeseed oil, canola oil, colza oil, tall oil, sunflower oil, soybean oil, hemp oil, olive oil, linseed oil, cottonseed oil, mustard oil, palm oil, arachis oil, castor oil, coconut oil, animal fats such as suet, tallow, blubber, recycled alimentary fats, starting materials produced by genetic engineering, or biological starting materials produced by microbes, algae or bacteria or any mixtures of said feedstocks.

4. The process according to claim 1 , wherein the feedstock further comprises:
used or spent lubrication oils.

5. The process according to claim 1 , wherein the impurities are alkali metals or alkali earth metals, phosphorous compounds or iron compounds.

6. The process according to claim 1 , comprising adding a chelator to the admixture in step b).

7. The process according to claim 1 , wherein the acid is phosphoric acid.

8. The process according to claim 1 , wherein the acid is sulfuric acid.

9. The process according to claim 1 wherein an amount of acid is selected to be within a range of about 50 ppm to about 100000 ppm, 500 ppm to about 10000 ppm, about 500 ppm to about 4000 ppm, about 1000 ppm to about 5000 ppm, about 2000 ppm to about 4000 ppm, about 50 ppm, about 1000 ppm, about 2000 ppm, about 3000 ppm, about 4000 ppm, about 5000 ppm, about 6000 ppm, about 7000 ppm, about 8000 ppm, 9000 ppm or about 10000 ppm.

10. The process according to claim 1 , wherein the heating temperature in step c) is selected to be about 200° C., about 230° C., about 260° C., or about 280° C.

11. The process according to claim 1 , comprising:
maintaining the heating in step c) in the admixture for about 1 minute to about 420 minutes, about 10 minutes to about 180 minutes, about 5 minutes to about 60 minutes, about 10 minutes to about 60 minutes, about 20 minutes, about 30 minutes, about 40 minutes, about 50 minutes or about 60 minutes.

12. The process according to claim 1 , comprising:
maintaining the heating in step c) in the admixture for about 5 minutes to about 60 minutes.

13. The process according to claim 1 , comprising:
removing the water in step d), wherein the removing is by flash evaporation or any suitable vapour-liquid separation, or by physical separation wherein a water layer is separated.

14. The process according to claim 1 , comprising:
removing the water in step d), wherein removing the water is before removal of the separate phase in step e).

15. The process according to claim 1 , comprising:
removing in step e) the separate phase by filtration, centrifugation or gravitational sedimentation, bleaching, degumming, water washing, filtering or a combination thereof.

16. The process according to claim 1 , comprising:
reducing the admixture after steps c) or d) in volume by evaporation or flashing prior to the removing in step e).

17. The process according to claim 1 , comprising removing water from the feedstock containing impurities before step a).

18. The process according to claim 1 ,
wherein the feedstock containing impurities contains any of the following:
a) an iron content (Fe) of more than 1 ppm;
b) a sodium content (Na) of more than 1 ppm; or
c) a phosphorous content (P) of more than 20 ppm.

Assignees

• Neste Oyj

Inventors

• Malm Annika

Classifications

• C11B3/04 Primary

  with acids · CPC title

• C11B3/001 Primary

  by a combination of two or more of the means hereafter · CPC title

• C10G17/02

  with acids or acid-containing liquids, e.g. acid sludge · CPC title

• C11B3/12

  by distillation · CPC title

• C11B3/00

  Refining fats or fatty oils · CPC title