Ecofriendly and biodegradable lubricant formulation and process for preparation thereof

Patent metadata

Field	Value
Publication number	US-11142718-B2
Application number	US-201816760963-A
Country	US
Kind code	B2
Filing date	Apr 26, 2018
Priority date	Nov 3, 2017
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

The present invention discloses with the development of ecofriendly and biodegradable lubricant formulation useful for micro electro mechanical systems and process thereof. The new generation Mineral oil free lubricant formulations were developed by esterification of polyols such as 2,2-dimethyl, 1,3-Propanediol, 2,2-diethyl-1,3-propane diol, and aliphatic di carboxylic acids like adipic and azelaic and with mono alcohol, using heterogeneous catalyst Indion 140 with cation exchange properties. The said formulation has a viscosity in the range of 31 to 47 cSt at 40° C., a high viscosity index of 139-196, pour point of approximately <−39° C. with a multifunctional EP additive of recommended dose of 1.5-4%. These new generation lubricants exhibited excellent biodegradability, a high viscosity index, and a low pour point, a high flash point, good lubricity, good oxidative stability, very good protection, against wear, no evaporation loss, good adherence to metal, corrosion inhibiting characteristics and suitability for use with commercial additives. In addition the products are non toxic to the sewage bacteria.

First claim

We claim:

1. A lubricant, wherein the lubricant comprises:
polyol complex ester selected from the group consisting of 2,2-diethyl-1,3-propane-di-azelaic-2-ethyl-1-hexanoate; 2,2-dimethyl-1,3-propane-di-adipic-2-ethyl-1-hexanoate, and a mixture thereof, wherein the polyol complex is in the range of 94% to 100%;
an antioxidant in the range of 0-2%; and
an additive in the range of 0 to 4%; and
wherein the lubricant is free of mineral oil.

2. The lubricant as claimed in claim 1 , wherein the ratio of polyol complex esters is in the range of 1:1 to 1:3.

3. The lubricant as claimed in claim 1 , wherein the ratio of polyol complex ester is 1:1.

4. The lubricant as claimed in claim 1 , wherein the antioxidant is selected from the group consisting of 2,6-di tertiary butyl 4, methyl Phenol (BHT), alkylated diphenylamine, 3,7-di-t-octylphenothiazine, alkylated PANA, and di-t-butyl-p-cresol (DBPC).

5. The lubricant as claimed in claim 1 , wherein the additive is selected from the group consisting of Zinc dialkyl dithio phosphate (ZDDP), 5,5-dithiobis-(1,3,4-thiadiazole-2(3H)-thione), Di Methyl Hydrogen Phosphite, Di Butyl Hydrogen Phosphite, Di-n-Octyl Hydrogen Phosphite, Di-2-Ethylhexyl Hydrogen Phosphite, Di Oleyl Hydrogen Phosphite, Di Lauryl Hydrogen Phosphite, Tri-Lauryl Tri Thiophosphite, Tri-Lauryl Phosphite, Tri-C 12 -C 14 Phosphite, and Tri-C 12 -C 14 Phosphite.

6. A process for synthesizing the mineral oil free lubricant wherein the process comprises the steps of:
(i) reacting a mixture of polyol of C 3 -C 5 carbon, dicarboxylic acid of C 6 -C 10 carbon in a ratio of 1:2 in presence of a heterogeneous catalyst and a solvent at refluxing temperature for a period ranging between 2 to 4 hours to obtain a reaction mixture;
(ii) removing water from said reaction mixture and allowing the mixture to cool to obtain cooled mixture;
(iii) reacting the cooled mixture obtained at step (ii) with at least 2 moles of mono alcohol under reflux condition until all remaining carboxylic groups are esterified, and completing the reaction in a period ranging from 8 to 12 hours, until water is removed to obtain Polyol complex esters as base oil; and
(iv) blending the base oil obtained at step (iii), wherein the base oil is 94% to 100% with antioxidant 1-2% and an additive 1.5 to 4%, to obtain the mineral oil free lubricant.

7. The process as claimed in claim 6 , wherein the polyol is selected from the group consisting of 2, 2-dimethyl 1, 3-propane diol, and 2, 2-diethyl-1, 3-propane diol.

8. The process as claimed in claim 6 , wherein the dicarboxylic acid (C 6 -C 10 ) is selected from the group consisting of adipic acid, and azelaic acid.

9. The process as claimed in claim 6 , wherein the mono alcohol in step (iii) is selected from the group consisting of 2-ethyl-1-hexanol, isooctanol, nonanol, and isodecanol.

10. The process as claimed in claim 6 , wherein the solvent is selected from toluene or xylene.

11. The process as claimed in claim 6 , wherein the antioxidant is selected from the group consisting of 2,6-di tertiary butyl 4, methyl Phenol (BHT), alkylated diphenylamine, 3,7-di-t-octylphenothiazine, alkylated PANA, and di-t-butyl-p-cresol (DBPC).

12. The process as claimed in claim 6 , wherein the additive is selected from the group consisting of Zinc dialkyl dithio phosphate (ZDDP), 5,5-dithiobis-(1,3,4-thiadiazole-2(3H)-thione), Di Methyl Hydrogen Phosphite, Di Butyl Hydrogen Phosphite, Di-n-Octyl Hydrogen Phosphite, Di-2-Ethylhexyl Hydrogen Phosphite, Di Oleyl Hydrogen Phosphite, Di Lauryl Hydrogen Phosphite, Tri-Lauryl Tri Thio-phosphite, Tri-Lauryl Phosphite, Tri-C 12 -C 14 Phosphite, and Tri-C 12 -C 14 Phosphite.

13. The process as claimed in claim 6 , wherein the heterogeneous catalyst is Styrene di-vinyl benzene copolymer resin with sulphonic acid functionality.

14. The process as claimed in claim 6 , wherein the reaction temperature in steps (i) and (ii) is in the range of 107-115° C. at atmospheric pressure.

15. A polyol complex ester selected from the group consisting of:
(i) 2, 2-diethyl 1, 3-propane di adipic 2 ethyl 1 hexanoate (DEADEH),
(ii) 2, 2-diethyl 1, 3-propane diazelaic 2 ethyl 1 hexanoate (DEAZEH),
(iii) 2, 2-diethyl 1, 3-propane disebacic 2 ethyl 1 hexanoate (DESEH),
(iv) 1, 1, 1-trishydroxymethyl propane triazilaic 2 ethyl 1 hexanoate (THAZEH),
(v) 1,1, 1-trishydroxymethyl propane trisebacic 2 ethyl 1 hexanoate (THSEH), and
(vi) 1, 1, 1-trishydroxymethyl propane triadipic 2 ethyl 1 hexanoate (THADEH).

Assignees

• Council Scient Ind Res

Inventors

• Nagendramma Ponnekanti
• Ray Anjan
• Thakre Gananath Doulat
• Atray Neeraj

Classifications

• C10N2040/06

  Instruments or other precision apparatus, e.g. damping fluids · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10M2207/023

  having hydroxy groups bound to carbon atoms of six-membered aromatic rings · CPC title

• C10M169/04

  Mixtures of base-materials and additives · CPC title

• C10M135/28

  containing sulfur atoms bound to a carbon atom of a six-membered aromatic ring · CPC title