Polymer having polyether and polysiloxane segments

Patent metadata

Field	Value
Publication number	US-11142607-B2
Application number	US-201816632937-A
Country	US
Kind code	B2
Filing date	Jul 23, 2018
Priority date	Jul 26, 2017
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

The invention relates to a polymer having a) a polymer backbone and b) one or more polymeric side chains covalently linked to the polymer backbone, wherein the polymeric side chains comprise a polyether segment and a polysiloxane segment, said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, and said polyether segment being positioned between the polymer backbone and the polysiloxane segment.

First claim

The invention claimed is:

1. A polymer having
a) a polymer backbone and
b) one or more polymeric side chains covalently linked to the polymer backbone, wherein the polymeric side chains comprise a polyether segment and a polysiloxane segment,
said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, and said polyether segment having a number average molecular weight in the range of 450 to 5000 and being positioned between the polymer backbone and the polysiloxane segment,
wherein the polymer has a weight average molecular weight ranging from 4,500 to 15,000.

2. The polymer according to claim 1 , wherein the polysiloxane segment has a number average molecular weight in the range of 1100 to 6000.

3. The polymer according to claim 1 , wherein the polymer backbone is a (co)polymer of polymerizable ethylenically unsaturated monomers.

4. The polymer according to claim 1 , wherein the polyether segment comprises polymerized units of alkylene oxides comprising one or more of ethylene oxide, propylene oxide, and combinations thereof.

5. The polymer according to claim 1 , wherein the polymer further comprises functional groups.

6. The polymer according to claim 5 , wherein the functional groups comprise one or more of hydroxyl groups, carboxylic acid groups, amino groups, etherified amino groups, amide groups, epoxide groups, alkoxysilyl groups, and combinations thereof.

7. A process for preparing a polymer, the process comprising copolymerizing
a) a macromonomer MM having one polymerizable ethylenically unsaturated group, a polyether segment, and a polysiloxane segment, said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, and said polyether segment having a number average molecular weight in the range of 450 to 5000 and being positioned between the polymerizable ethylenically unsaturated group and the polysiloxane segment, and
b) at least one other further monomer having at least one polymerizable ethylenically unsaturated group,
the resulting polymer comprising a backbone and one or more polymeric side chains covalently linked to the polymer backbone, wherein the polymeric side chains comprise a polyether segment and a polysiloxane segment, said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, said polyether segment being positioned between the polymer backbone and the polysiloxane segment, and the resulting polymer having a weight average molecular weight ranging from 4,500 to 15,000.

8. The process according to claim 7 , wherein the macromonomer MM is prepared by
i) providing
a) a monomer having one polymerizable ethylenically unsaturated group and one further functional group which is different from the polymerizable ethylenically unsaturated group, and
b) a molecule having a group which is reactive towards said at least one further functional group, a polyether segment, and a polysiloxane segment, said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, and said polyether segment being positioned between said group which is reactive towards said at least of further functional group and the polysiloxane segment,
ii) forming a covalent bond between the monomer a) and the molecule b) by reacting the at least one further functional group with the group which is reactive towards said at least one further functional group.

9. The process according to claim 7 , wherein the macromonomer MM is prepared by
i) providing
a) a monomer having one polymerizable ethylenically unsaturated group, a polyether segment, and one further ethylenically unsaturated functional group which is different from the polymerizable ethylenically unsaturated group, and wherein the polyether segment is located between the polymerizable ethylenically unsaturated group and the further ethylenically unsaturated functional group,
b) a molecule having a polysiloxane segment having a number average molecular weight in the range of 1050 to 6000 and one Si—H group, and

ii) forming a covalent bond between the monomer a) and the molecule b) by a hydrosylilation reaction of the Si—H group on the further ethylenically unsaturated functional group.

10. A process for preparing a polymer, comprising the steps of:
i) providing
a) a polymer backbone having at least one functional group and
b) a molecule having a group which is reactive towards said at least one functional group, a polyether segment, and a polysiloxane segment, said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, and said polyether segment being positioned between said group which is reactive towards said at least one functional group and the polysiloxane segment, and

ii) forming a covalent bond between the polymer backbone a) and the molecule b) by reacting the at least one functional group with the group which is reactive towards said at least one functional group,
the resulting polymer comprising a backbone and one or more polymeric side chains covalently linked to the polymer backbone, wherein the polymeric side chains comprise a polyether segment and a polysiloxane segment, said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, and said polyether segment having a number average molecular weight in the range of 450 to 5000 and being positioned between the polymer backbone and the polysiloxane segment, and the resulting polymer having a weight average molecular weight ranging from 4,500 to 15,000.

11. The process of claim 10 , the resulting polymer having a weight average molecular weight ranging from 3,500 to 75,000.

12. A composition comprising
a) a polymer in an amout of 0.1 to 15% by weight, based on the total non-volatile content of the composition, the polymer having a polymer backbone and one or more polymeric side chains covalently linked to the polymer backbone, wherein the polymeric side chains comprise a polyether segment and a polysiloxane segment, said polysiloxane segment having a number average molecular weight in the range of 1050 to 6000, and said polyether segment being positioned between the polymer backbone and the polysiloxane segment, and
b) a binder, which is different from said polymer a).

13. The composition according to claim 12 , wherein the composition is liquid at a temperature of 20° C. and comprises a volatile diluent.

14. A multilayer coating system on a substrate comprising at least one undercoat layer and a one top-coat layer, wherein at least one layer is based on a composition according to claim 12 .

15. The multilayer coating system according to claim 14 , wherein the substrate is a motor vehicle or a part thereof.

16. The composition of claim 12 , the polyether segment having a number average molecular weight in the range of 450 to 5000.

17. A process of forming a multilayer coating system on a substrate comprising the steps of
i) applying a coating composition a) to a substrate to form a coating layer a) and
ii) applying a coating composition b) to form a coating layer b) on top of coating layer a),
wherein at least one of the coating composition a) or the coating composition b) comprises a polymer in an amount of 0.1 to 15% by weight, based on the total non-volatile content of the coating composition, the polymer having a polymer backbone and one or more polymeric side chains covalently linked to the polymer backbone, wherein the polymeric side chains comprise a polyether segment and a polysiloxane segment, said polysiloxane segment having a number avera

Assignees

• Byk Chemie Gmbh

Inventors

• Jaunky Guillaume Wojciech
• Eberhardt Marc
• Heekeren Mark
• Tenbusch Sven
• Muschiolik Olaf
• HARTMANN JüRGEN
• Della Valentina Petra

Classifications

• C08G77/46

  containing polyether sequences · CPC title

• C08L83/12

  containing polyether sequences · CPC title

• B05D7/14

  to metal, e.g. car bodies (involving a chemical reaction between the metal and the coating C23) · CPC title

• C08F290/062 Primary

  Polyethers · CPC title

• C08F290/06 Primary

  Polymers provided for in subclass C08G · CPC title