Diaryl carbonate and method for producing the same, and method for producing an aromatic polycarbonate resin

Patent metadata

Field	Value
Publication number	US-11142506-B2
Application number	US-202016738226-A
Country	US
Kind code	B2
Filing date	Jan 9, 2020
Priority date	Oct 14, 2015
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

Disclosed are a diaryl carbonate containing a compound of the following formula (I) in an amount of less than 1,000 ppm by mass, and a method for producing the same:wherein Rl represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryl group, or an aryloxy group. Disclosed methods include reacting urea with an alkyl alcohol to provide a dialkyl carbonate; reacting the dialkyl carbonate with an aryl alcohol to provide an alkylaryl carbonate; subjecting the alkylaryl carbonate to disproportionation to yield a mixture comprising a diaryl carbonate; and purifying the mixture.

First claim

What is claimed is:

1. A method for producing a diaryl carbonate composition containing a compound of the following formula (I) in an amount of less than 1,000 ppm by mass:

wherein R l represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryl group, or an aryloxy group, the method comprising:
(A) reacting urea with an alkyl alcohol to yield a first reaction mixture containing a dialkyl carbonate;
(B) reacting the dialkyl carbonate in the first reaction mixture with an aryl alcohol to yield a second reaction mixture containing an alkylaryl carbonate;
(C) subjecting the alkylaryl carbonate in the second reaction mixture to disproportionation to yield a third reaction mixture containing a diaryl carbonate wherein the third reaction mixture contains the compound of the formula (I) in an amount of 1,000 ppm by mass or more;
(D) purifying the third reaction mixture by using a distillation column, thereby obtaining the diaryl carbonate containing the compound of the formula (I) in an amount of less than 1,000 ppm by mass from the top of the distillation column and obtaining a concentrated mixture comprising the compound of the formula (I) from the bottom of the distillation column, wherein the distillation is conducted under the following conditions (a) and (b):
(a) the pressure at the top of the distillation column is 0.01 to 10 kPa, and
(b) the reflux ratio is 2 to 20;

(E) filtering off the compound of the formula (I) which is precipitated from the concentrated mixture at a temperature in the range of from 80 to 230° C., and
(F) recovering the compound of the chemical formula (I) filtered off in (E) and bringing the filtrate back to (D).

2. The method according to claim 1 , wherein the alkyl alcohol used in (A) is an alkyl alcohol having 3 to 6 carbon atoms.

3. A method for producing an aromatic polycarbonate resin, the method comprising producing the diaryl carbonate according to claim 1 , and performing melt polycondensation of the diaryl carbonate and an aromatic dihydroxy compound in the presence of a transesterification catalyst that catalyzes the melt polycondensation.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Harada Hidefumi
• Taguchi Jungo
• Isahaya Yoshinori

Classifications

• B01D3/4211

  of columns · CPC title

• C07D265/26 Primary

  Two oxygen atoms, e.g. isatoic anhydride · CPC title

• C07C69/96

  Esters of carbonic or haloformic acids · CPC title

• C07C68/06

  from organic carbonates · CPC title

• C07C68/08

  Purification; Separation; Stabilisation · CPC title