Ways to prevent pump-around heat exchanger fouling and extend run lengths on a benzene hydrogenation unit

Patent metadata

Field	Value
Publication number	US-11142490-B2
Application number	US-202016848325-A
Country	US
Kind code	B2
Filing date	Apr 14, 2020
Priority date	Feb 19, 2018
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

A process for hydrogenation of an aromatic hydrocarbon including introducing a hydrocarbon feed comprising the aromatic hydrocarbon, a hydrogen feed comprising hydrogen, and a hydrogenation catalyst into a hydrogenation reactor operable with a liquid phase and a gas phase to produce a hydrogenation product; removing a gas phase product stream comprising the hydrogenation product; withdrawing a portion of the liquid phase; subjecting the withdrawn portion to heat exchange to provide a reduced-temperature withdrawn portion; introducing the reduced-temperature withdrawn portion back into the hydrogenation reactor; and at least one of: (a) providing at least two heat exchangers to effect the subjecting of the withdrawn portion of the liquid phase to heat exchange; (b) separating a decomposition product of the hydrogenation catalyst, the hydrogenation catalyst, or both, from the withdrawn portion of the liquid phase prior to the heat exchange; and (c) reducing exposure of the hydrogenation catalyst to an oxygen-containing species.

First claim

What is claimed is:

1. A system for liquid phase hydrogenation, the system comprising:
a hydrogenation reactor operable with a liquid phase and a gas phase to convert an aromatic hydrocarbon in a hydrocarbon feed to a hydrogenation product by contacting the aromatic hydrocarbon with hydrogen in a hydrogen feed in the presence of a hydrogenation catalyst;
a pump-around loop comprising a pump configured to move a withdrawn portion of the liquid phase from the hydrogenation reactor through the pump-around loop and back to the hydrogenation reactor;
at least one primary heat exchanger after the pump in the pump-around loop wherein the primary heat exchanger is configured to reduce the temperature of at least a portion of the liquid phase withdrawn from the hydrogenation reactor, thus providing a reduced-temperature withdrawn portion, prior to introduction of the reduced-temperature withdrawn portion into the hydrogenation reactor; and
(a) at least one additional heat exchanger in parallel with the at least one primary heat exchanger, wherein the additional heat exchanger is configured such that the at least one primary heat exchanger can be placed offline while the at least one additional heat exchanger is placed online; and
(b) a separator upstream of the at least one primary heat exchanger, wherein the separator is configured to separate a decomposition product of the hydrogenation catalyst, the hydrogenation catalyst, or both from the withdrawn portion of the liquid phase; and
(c) a source of a component that will react with an oxygen-containing species in the hydrocarbon feed, the hydrogen feed, or both.

2. The system of claim 1 wherein the system also comprises a dryer operable to dry the hydrocarbon feed, the hydrogen feed, or a mixture of the hydrocarbon feed and the hydrogen feed prior to contacting the hydrocarbon feed and the hydrogen feed with the catalyst.

3. The system of claim 1 , wherein the aromatic hydrocarbon comprises benzene and the hydrogenation product comprises cyclohexane; and wherein the hydrogenation catalyst comprises nickel and at least one aluminum alkyl; or both.

4. The system of claim 1 , wherein the separator comprises a cyclone upstream or downstream of the pump.

5. The system of claim 1 further comprising a recycle line whereby at least a portion of the separated hydrogenation catalyst can be reintroduced into the hydrogenation reactor.

6. The system of claim 1 further comprising piping whereby the hydrocarbon feed and the hydrogen feed can be combined to provide a combined feed prior to introduction of the combined feed into the hydrogenation reaction and piping whereby the component can be added from the source of the component to the combined feed.

7. The system of claim 1 wherein the primary heat exchanger and the additional heat exchanger are substantially identical.

8. The system of claim 1 wherein the primary heat exchanger is larger than the additional heat exchanger.

9. The system of claim 1 wherein the component is an aluminum alkyl.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Snell Ryan W
• Garcia Israel

Classifications

• C07C5/10 Primary

  of aromatic six-membered rings · CPC title

• B01J19/2465

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title

• B01J2219/00103

  in a heat exchanger separate from the reactor · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C07C2531/14

  of aluminium or boron · CPC title