Method for recycling carbon dioxide

Patent metadata

Field	Value
Publication number	US-11142461-B2
Application number	US-202016842210-A
Country	US
Kind code	B2
Filing date	Apr 7, 2020
Priority date	Apr 10, 2019
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

The method for recycling carbon dioxide according to the present invention includes: injecting a reaction gas containing carbon dioxide and a carbon raw material into a rotary heating furnace; reacting the reaction gas and the carbon raw material with each other in the rotary heating furnace to generate a hydrocarbon precursor containing carbon monoxide; and converting the hydrocarbon precursor into a hydrocarbon compound, thereby exhibiting excellent conversion rate of carbon dioxide.

First claim

What is claimed is:

1. A method for recycling carbon dioxide comprising:
injecting a reaction gas containing carbon dioxide and a carbon raw material into a rotary heating furnace;
reacting the reaction gas and the carbon raw material with each other in the rotary heating furnace to generate a hydrocarbon precursor containing carbon monoxide; and
converting the hydrocarbon precursor into a hydrocarbon compound,
wherein the rotary heating furnace includes a heating unit configured to directly heat the rotary heating furnace, and
a ratio of an injection rate of the carbon raw material in g/hr relative to an injection rate of the reaction gas in g/hr is from 2 to 5.

2. The method for recycling carbon dioxide according to claim 1 , wherein, in the injecting the reaction gas and the carbon raw material, the carbon raw material is injected into a front section in a length direction of the rotary heating furnace, and the reaction gas is injected into a rear section in the length direction of the rotary heating furnace.

3. The method for recycling carbon dioxide according to claim 1 , wherein, in the injecting the reaction gas and the carbon raw material, the reaction gas and the carbon raw material are injected together into a front section in a length direction of the rotary heating furnace.

4. The method for recycling carbon dioxide according to claim 1 , wherein the reaction gas is injected so that a retention time in the rotary heating furnace is 10 to 60 minutes.

5. The method for recycling carbon dioxide according to claim 1 , wherein the carbon raw material includes coke, carbon black or graphite.

6. The method for recycling carbon dioxide according to claim 1 , wherein a reaction temperature in the rotary heating furnace is 900 to 1,200° C.

7. The method for recycling carbon dioxide according to claim 1 , wherein a reaction pressure in the rotary heating furnace is 0.1 to 10 bar.

8. The method for recycling carbon dioxide according to claim 1 , wherein the producing the hydrocarbon precursor includes rotating the rotary heating furnace by an axis in a length direction, while moving the carbon raw material and the reaction gas in the length direction of the rotary heating furnace.

9. The method for recycling carbon dioxide according to claim 8 , wherein a rotational speed of the rotary heating furnace is 0.5 to 30 rpm.

10. The method for recycling carbon dioxide according to claim 1 , wherein a ratio of an inner length relative to an inner diameter of the rotary heating furnace is 5 to 30.

11. The method for recycling carbon dioxide according to claim 1 , wherein the rotary heating furnace is inclined by a predetermined slope ratio so that a front section in a length direction is higher than a rear section in the length direction.

12. The method for recycling carbon dioxide according to claim 11 , wherein the slope ratio is 1 to 10%.

13. The method for recycling carbon dioxide according to claim 1 , wherein producing the hydrocarbon precursor included reacting carbon dioxide self-generated in the rotary heating furnace with the carbon raw material.

14. The method for recycling carbon dioxide according to claim 1 , further including removing nitrogen and water vapor from the hydrocarbon precursor before converting the hydrocarbon precursor into the hydrocarbon compound.

15. The method for recycling carbon dioxide according to claim 1 , wherein the converting the hydrocarbon precursor into the hydrocarbon compound includes reacting the hydrocarbon precursor with a metal catalyst.

16. The method for recycling carbon dioxide according to claim 15 , wherein the metal catalyst includes iron oxide.

17. The method for recycling carbon dioxide according to claim 1 , wherein the converting the hydrocarbon precursor into the hydrocarbon compound includes reacting carbon monoxide with hydrogen to be converted into hydrocarbon.

Assignees

• Sk Innovation Co Ltd

Inventors

• Koo Min Su

Classifications

• B01J2219/1943

  cylindrical · CPC title

• C01B2203/02

  Processes for making hydrogen or synthesis gas · CPC title

• C07C1/041

  Reactors · CPC title

• B01J2219/187

  inclined at an angle to the horizontal or to the vertical plane · CPC title

• C10G2/332

  of the iron-group · CPC title