Composition and method for powder bed fusion

Patent metadata

Field	Value
Publication number	US-11141913-B2
Application number	US-201816645903-A
Country	US
Kind code	B2
Filing date	Sep 21, 2018
Priority date	Sep 22, 2017
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

A composition for use in powder bed fusion includes a thermoplastic powder that itself includes an induced crystalline polycarbonate or an induced crystalline polyetherimide. The thermoplastic powder is recycled powder, which means that it is recovered from a powder bed that had undergone a powder bed fusion process. Also described is a method of making an article, the method including: placing an induced crystalline polymeric (polycarbonate or polyetherimide) powder in a powder bed, fusing a portion of the induced crystalline polymeric powder in the powder bed, recovering a least a portion of the crystalline polymeric powder from the powder bed, wherein the recovered powder is not fused, placing the recovered induced crystalline polymeric powder in a second powder bed, and fusing at least a portion of the recovered induced crystalline polymeric powder in the second powder bed to form an amorphous polymer article.

First claim

The invention claimed is:

1. A method of making an article, the method comprising:
a) converting an amorphous polymer to an induced crystalline polymeric powder wherein the amorphous polymer is polycarbonate or polyetherimide,
b) placing the induced crystalline polymeric powder in a powder bed,
c) fusing a portion of the induced crystalline polymeric powder in the powder bed,
d) recovering a least a portion of the crystalline polymeric powder from the powder bed, wherein the recovered powder is not fused,
e) placing the recovered induced crystalline polymeric powder in a second powder bed, and
f) fusing at least a portion of the recovered induced crystalline polymeric powder in the second powder bed to form an amorphous polymer article.

2. The method of claim 1 , wherein the amorphous polymer is polycarbonate.

3. The method of claim 2 , wherein the induced crystalline polymeric powder comprises, based on the weight of the induced crystalline polymeric powder, 0.5 to 100 parts per million by weight of methanol.

4. The method of claim 2 , wherein the induced crystalline polymeric powder comprises, based on the weight of the induced crystalline polymeric powder, 0.5 to 100 parts per million by weight of methanol; and 0.5 to 100 parts per million by weight of acetone.

5. The method of claim 1 , wherein the amorphous polymer is polyetherimide.

6. The method of claim 5 , wherein the induced crystalline polymeric powder has a weight average molecular weight of 15,000 to 50,000 grams/mole, determined by gel permeation chromatography using poly[2,2′-bis(4-(3,4-dicarboxyphenoxy)phenylpropane)-1,3-phenylene bisimide] standards; and wherein the induced crystalline polymeric powder comprises, based on the weight of the induced crystalline polymeric powder, 10 to 500 parts per million by weight of ortho-dichlorobenzene.

7. The method of claim 1 , wherein the induced crystalline polymeric powder has a particle size distribution, determined by laser diffraction according to ISO 13320-1, characterized by a Dv10 value in a range of 10 to 50 micrometers; a Dv50 value in a range of 30 to 90 micrometers; and a Dv90 value in a range of 100 to 150 micrometers.

8. The method of claim 1 , further comprising, after said recovering a least a portion of the crystalline polymeric powder from the powder bed, and before said placing the recovered induced crystalline polymeric powder in a second powder bed:
crushing and sieving the recovered portion of the crystalline polymeric powder to yield a recovered and sieved portion of the crystalline polymeric powder;
wherein said placing the recovered induced crystalline polymeric powder in a second powder bed comprises placing the recovered and sieved portion of the crystalline polymeric powder in the second powder bed.

Assignees

• Sabic Global Technologies Bv
• Shpp Global Tech Bv

Inventors

• Miloskovska Elena
• Jofore Bruke

Classifications

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B29C64/153 Primary

  using layers of powder being selectively joined, e.g. by selective laser sintering or melting · CPC title

• B33Y40/10

  Pre-treatment · CPC title

• C08G2140/00

  Compositions for moulding powders · CPC title

• C08G64/06

  not containing aliphatic unsaturation · CPC title