Method for fabricating heterogeneous nickel-based catalyst on aluminum oxide support, heterogeneous nickel-based catalyst on aluminum oxide support and method for synthesizing polyetheramine

Patent metadata

Field	Value
Publication number	US-11141715-B2
Application number	US-201916407770-A
Country	US
Kind code	B2
Filing date	May 9, 2019
Priority date	Nov 6, 2018
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

The present disclosure provides a method for fabricating a heterogeneous nickel-based catalyst on an aluminum oxide support. The method includes a solution preparation step, a drop-cast step, a first calcining step, and a second calcining step. The solution preparation step is provided for preparing a precursor solution. The drop-cast step is provided for dropping the precursor on the support. The first calcining step is provided for obtaining an oxidation state catalyst. The second calcining step is provided for obtaining the heterogeneous nickel-based catalysts on aluminum oxide support.

First claim

What is claimed is:

1. A method for fabricating a heterogeneous nickel-based catalyst on an aluminum oxide support, comprising:
performing a solution preparation step, wherein a catalytically active precursor is used as a precursor solution, the precursor solution contains a nickel ion and a cerium ion, and a concentration of the nickel ion is 15 wt %, a concentration of the cerium ion is in a range of from greater than 5.0 wt % to 15 wt %;
performing a drop-cast step, wherein the precursor solution is dropped on a support so as to obtain a catalyst precursor, and the support is an aluminum oxide support;
performing a first calcining step, wherein the catalyst precursor is calcined so as to obtain an oxidation state catalyst; and
performing a second calcining step, wherein the oxidation state catalyst is calcined under a reducing gas so as to obtain the heterogeneous nickel-based catalyst on the aluminum oxide support, the reducing gas is hydrogen, and a temperature of the second calcining step is 400° C.

2. The method for fabricating the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 1 , wherein the precursor solution is a mixed solution of nickel nitrate and cerium nitrate.

3. The method for fabricating the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 1 , wherein the support is dried at a temperature of 353 K to 393 K first, and reserved overnight.

4. The method for fabricating the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 1 , wherein a temperature of the first calcining step ranges from 300° C. to 400° C.

5. The method for fabricating the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 1 , further comprising a passivation step, wherein the passivation step is performed by introducing an air so as to passivate the heterogeneous nickel-based catalyst on the aluminum oxide support at a temperature of 180° C. to 220° C.

6. The method for fabricating the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 5 , wherein the passivation step further comprises cooling the heterogeneous nickel-based catalyst on the aluminum oxide support at the temperature of 200° C. to 400° C. with nitrogen.

7. A heterogeneous nickel-based catalyst on an aluminum oxide support fabricated by the method for fabricating the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 1 .

8. The heterogeneous nickel-based catalyst on the aluminum oxide support of claim 7 , wherein the heterogeneous nickel-based catalyst on the aluminum oxide support is a nickel-cerium oxide catalyst on the aluminum oxide support.

9. A method for synthesizing polyetheramine, comprising:
providing the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 7 ; and
performing a reductive amination reaction of polypropylene glycol step, wherein polypropylene glycol is reductively aminated by the heterogeneous nickel-based catalyst on the aluminum oxide support used as a catalyst so as to obtain polyetheramine in an environment containing hydrogen and ammonia.

10. The method for synthesizing polyetheramine of claim 9 , wherein a molar ratio of hydrogen to polypropylene glycol ranges from 1 to 1.5.

11. The method for synthesizing polyetheramine of claim 9 , wherein a molar ratio of ammonia to polypropylene glycol ranges from 38 to 40.6.

12. The method for fabricating the heterogeneous nickel-based catalyst on the aluminum oxide support of claim 1 , wherein the concentration of the cerium ion is 15 wt %.

Assignees

• Chang Chun Petrochemical Co Ltd
• Chang Chun Plastics Co Ltd
• Dairen Chemical Corp
• Univ Nat Tsing Hua
• Darien Chemical Corp

Inventors

• Tsai De-Hao
• Chang Hung-Yen
• Lai Guan-Hung
• Lin Chih-Yuan
• Lee Chun-Yu
• Chia Chih-Cheng
• Hwang Chuen-Lih
• Chang Huan-Ming

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/393

  Metal or metal oxide crystallite size · CPC title

• B01J35/77

  Compounds characterised by their crystallite size · CPC title

• B01J2235/15

  X-ray diffraction · CPC title