Porous support-zeolite membrane composite, and method for producing porous support-zeolite membrane composite

Patent metadata

Field	Value
Publication number	US-11141703-B2
Application number	US-201916445450-A
Country	US
Kind code	B2
Filing date	Jun 19, 2019
Priority date	Nov 25, 2014
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

An object of the present invention is to provide a porous support-zeolite membrane composite ensuring that at the time of separation or concentration with a zeolite membrane, both sufficient throughput and high separation performance are achieved in practice and the present invention relates to a porous support-zeolite membrane composite having a porous support and a zeolite membrane formed on the porous support, wherein part of the zeolite membrane penetrates into the inside of the porous support and the distance from the surface of the porous support to the inside into which the zeolite film penetrates is 5.0 μm or less on average.

First claim

The invention claimed is:

1. A production method of a porous support-zeolite membrane composite, comprising:
attaching inorganic particles other than zeolite to a porous support; and
forming a zeolite membrane on the porous support, wherein:
a zeolite constituting the zeolite membrane comprises Si and Al, and has a SiO 2 /Al 2 O 3 molar ratio of 20 or more;
the zeolite has a pore structure of not more than oxygen 8 members ring; and
the inorganic particle is at least one inorganic particle selected from the group consisting of fumed silica, colloidal silica, alumina sol, sodium aluminate, aluminum hydroxide, pseudo boehmite, aluminum sulfate, aluminum nitrate, aluminum oxide, and amorphous aluminosilicate gel.

2. The production method according to claim 1 , wherein from 0.1 to 15 g of the inorganic particle is attached onto 1 m 2 of the porous support.

3. The production method according to claim 1 , wherein an average pore size of the porous support is from 0.3 μm to 5 μm.

4. The production method according to claim 1 , wherein an average primary particle diameter of the inorganic particle is from 1 nm to 10 μm.

5. The production method according to claim 1 , wherein the SiO 2 /Al 2 O 3 molar ratio of the zeolite is from 20 to 2,000.

6. The production method according to claim 1 , wherein the SiO 2 /Al 2 O 3 molar ratio of the zeolite is from 20 to 100.

7. The production method according to claim 1 , wherein the zeolite constituting the zeolite membrane is CHA.

8. The production method according to claim 1 , wherein a distance from a surface of the porous support to an inside into which the zeolite membrane penetrates is from 0.01 to 5.0 μm on average.

9. The production method according to claim 1 , wherein a distance from a surface of the porous support to an inside into which the zeolite membrane penetrates is from 0.02 to 3.2 μm on average.

10. The production method according to claim 1 , wherein a distance from a surface of the porous support to an inside into which the zeolite membrane penetrates is from 0.03 to 1.7 μm on average.

11. The production method according to claim 1 , wherein the inorganic particle is at least one selected from the group consisting of fumed silica, colloidal silica, and alumina sol.

12. The production method according to claim 1 , wherein the inorganic particle is fumed silica.

Assignees

• Mitsubishi Chem Corp

Inventors

• ONOZUKA Ayuko
• Yamada Miki
• Hayashi Mikio
• Takewaki Takahiko

Classifications

• B01D71/0281

  Zeolites · CPC title

• B01D2325/02834

  more than 0.1 and up to 1 µm · CPC title

• B01D69/108

  Inorganic support material · CPC title

• C01B39/38

  Type ZSM-5 · CPC title

• B01D69/12 Primary

  Composite membranes; Ultra-thin membranes · CPC title