Redox flow battery electrode, and redox flow battery

Patent metadata

Field	Value
Publication number	US-11139481-B2
Application number	US-201716482521-A
Country	US
Kind code	B2
Filing date	Nov 15, 2017
Priority date	Jan 31, 2017
Publication date	Oct 5, 2021
Grant date	Oct 5, 2021

Abstract

A redox flow battery electrode includes an aggregate of a base containing carbon. When, on a cross section of the base, a circle that is centered at a center of gravity of the base and that has a diameter which is 95% of an isoarea equivalent circle diameter of the base is defined as a reference circle, the base includes a plurality of penetrating holes which extend from a surface toward an interior of the base and whose paths along extension directions of the penetrating holes are partially present within the reference circle.

First claim

The invention claimed is:

1. A redox flow battery electrode comprising an aggregate of a base containing carbon,
wherein the base includes a plurality of penetrating holes which extend from a surface toward an interior of the base, and the redox flow battery electrode has a capacitance of 0.05 F/g or more.

2. The redox flow battery electrode according to claim 1 , wherein the base includes a carbon fiber having a cross section with an isoarea equivalent circle diameter of 3 μm or more and 100 μm or less.

3. The redox flow battery electrode according to claim 1 , wherein at least one of the plurality of penetrating holes has an opening on the surface of the base, the opening having an isoarea equivalent circle diameter of 50 nm or more and 2,000 nm or less.

4. The redox flow battery electrode according to claim 1 ,
wherein the redox flow battery electrode has a BET specific surface area of 0.1 m 2 /g or more.

5. The redox flow battery electrode according to claim 1 , wherein at least one of the plurality of penetrating holes has a metal oxide at a bottom thereof.

6. A redox flow battery that performs charging and discharging by supplying a positive electrolyte and a negative electrolyte to a battery cell that includes a positive electrode, a negative electrode, and a membrane disposed between the positive electrode and the negative electrode,
wherein the positive electrode is the redox flow battery electrode according to claim 1 .

7. A redox flow battery electrode comprising an aggregate of a base containing carbon,
wherein the base includes a plurality of penetrating holes which extend from a surface toward an interior of the base, and
wherein at least one of the plurality of penetrating holes extends from the surface to the interior in a meandering manner.

8. A redox flow battery electrode comprising an aggregate of a base containing carbon,
wherein the base includes a plurality of penetrating holes which extend from a surface toward an interior of the base, and
wherein at least one of the plurality of penetrating holes extends through the base.

9. The redox flow battery electrode according to claim 7 , wherein the base includes a carbon fiber having a cross section with an isoarea equivalent circle diameter of 3 μm or more and 100 μm or less.

10. The redox flow battery electrode according to claim 7 , wherein at least one of the plurality of penetrating holes has an opening on the surface of the base, the opening having an isoarea equivalent circle diameter of 50 nm or more and 2,000 nm or less.

11. The redox flow battery electrode according to claim 7 ,
wherein the redox flow battery electrode has a BET specific surface area of 0.1 m 2 /g or more.

12. The redox flow battery electrode according to claim 7 ,
wherein the redox flow battery electrode has a capacitance of 0.05 F/g or more.

13. The redox flow battery electrode according to claim 7 , wherein at least one of the plurality of penetrating holes has a metal oxide at a bottom thereof.

14. A redox flow battery that performs charging and discharging by supplying a positive electrolyte and a negative electrolyte to a battery cell that includes a positive electrode, a negative electrode, and a membrane disposed between the positive electrode and the negative electrode,
wherein the positive electrode is the redox flow battery electrode according to claim 7 .

15. The redox flow battery electrode according to claim 8 , wherein the base includes a carbon fiber having a cross section with an isoarea equivalent circle diameter of 3 μm or more and 100 μm or less.

16. The redox flow battery electrode according to claim 8 , wherein at least one of the plurality of penetrating holes has an opening on the surface of the base, the opening having an isoarea equivalent circle diameter of 50 nm or more and 2,000 nm or less.

17. The redox flow battery electrode according to claim 8 ,
wherein the redox flow battery electrode has a BET specific surface area of 0.1 m 2 /g or more.

18. The redox flow battery electrode according to claim 8 ,
wherein the redox flow battery electrode has a capacitance of 0.05 F/g or more.

19. The redox flow battery electrode according to claim 8 , wherein at least one of the plurality of penetrating holes has a metal oxide at a bottom thereof.

20. A redox flow battery that performs charging and discharging by supplying a positive electrolyte and a negative electrolyte to a battery cell that includes a positive electrode, a negative electrode, and a membrane disposed between the positive electrode and the negative electrode,
wherein the positive electrode is the redox flow battery electrode according to claim 8 .

Assignees

• Sumitomo Electric Industries

Inventors

• Oya Masayuki
• Ito Kenichi

Classifications

• H01M2004/8689

  Positive electrodes · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/8626 Primary

  characterised by the form · CPC title

• H01M4/96 Primary

  Carbon-based electrodes · CPC title

• Y02E60/50

  Fuel cells · CPC title