Optical device comprising a switchable layer and at least one optical layer

Patent metadata

Field	Value
Publication number	US-11137639-B2
Application number	US-201816612235-A
Country	US
Kind code	B2
Filing date	May 8, 2018
Priority date	May 9, 2017
Publication date	Oct 5, 2021
Grant date	Oct 5, 2021

Abstract

The invention relates to a switchable optical device (10) having a layer structure comprising at least one switchable layer (15) and at least one optical layer (20, 22). The at least one switchable layer (15) comprises a liquid-crystalline material and at least one dye. The at least one optical layer (20, 22) has at least one reflection band (32) which includes at least a first part of the visible spectrum and has at least one transmission band (30, 34) which includes at least a second part of the visible spectrum. The absorption spectrum of the at least one switchable layer (15) is adjusted by means of the at least one dye such that the light transmission through the switchable optical device (10) for incident light in the visible light spectrum for at least one of the states of the switchable layer (15) is set to a predetermined transmission spectrum.

First claim

The invention claimed is:

1. A switchable window, comprising in said switchable window at least one switchable optical device ( 10 ) having a layer structure comprising at least one switchable layer ( 15 ) and at least one optical layer ( 20 , 22 ), wherein the at least one switchable layer ( 15 ) comprises a liquid-crystalline material and at least one dye, chosen such that the transmission spectrum of the switchable optical device ( 10 ) is color neutral for the visible light spectrum for at least one of the states of the at least one switchable layer ( 15 ), and the absorption spectrum of the at least one dye is complementary to the at least one transmission band of the at least one optical layer ( 20 , 22 ) in order to obtain the color neutral transmission spectrum, the at least one optical layer ( 20 , 22 ) having at least one reflection band ( 32 ) which includes at least a first part of the visible spectrum and has at least one transmission band ( 30 , 34 ) which includes at least a second part of the visible spectrum and that the absorption spectrum of the at least one switchable layer ( 15 ) is, due to the at least one dye, such that the light transmission through the switchable optical device ( 10 ) for incident light in the visible spectrum for at least one of the states of the switchable layer ( 15 ) has a predetermined transmission spectrum, with at least 5% of light having a wavelength within the at least one reflective band being reflected by the at least one optical layer ( 20 , 22 ).

2. The switchable window comprising the optical device ( 10 ) according to claim 1 , wherein the at least one switchable layer ( 15 ) comprises at least a bright state and a dark state, wherein for light in the visible spectrum the contrast C defined by C(λ)=(1−R(λ))·(T B (λ) T D (λ)) averaged over the visible spectrum is at least 0.5, wherein R is the intensity of light reflected by the switchable optical device ( 10 ), T B is the intensity of light transmitted through the switchable optical device ( 10 ) in the bright state and T D is the intensity of the light transmitted through the switchable optical device ( 10 ) in the dark state.

3. The switchable window comprising the optical device ( 10 ) according to claim 1 , wherein the layer structure comprises in this order a first transparent substrate ( 12 ), a first transparent electrode layer ( 24 ), the at least one switchable layer ( 15 ), a second transparent electrode layer ( 26 ) and a second transparent substrate ( 14 ).

4. The switchable window comprising the optical device ( 10 ) according to claim 1 , wherein the reflection of the at least one optical layer ( 20 , 22 ) in the at least one reflection band is polarization dependent wherein light of a first linear polarization is reflected stronger than light of a second linear polarization.

5. The switchable window comprising the optical device ( 10 ) according to claim 4 , wherein the polarization contrast of the at least one optical layer ( 20 , 22 ) in the at least one reflection band defined as the ratio of the intensity of reflected light of the first polarization and the intensity of reflected light of the second polarization is at least 2.

6. The switchable window comprising the optical device ( 10 ) according to claim 4 , wherein the at least one switchable layer ( 15 ) has a dichroic contrast defined as the ratio of the intensity of transmitted light of a first polarization and the intensity of transmitted light of a second polarization which is orthogonal to the first polarization of more than 2 for the visible spectrum in at least one state and wherein the polarization which is mostly transmitted by the at least one optical layer ( 20 , 22 ) is in the same polarization for which the most absorption occurs in the at least one switchable layer ( 15 ).

7. The switchable window comprising the optical device ( 10 ) according to claim 1 , wherein the at least one optical layer ( 20 , 22 ) is a cholesteric layer, the reflection of light in the at least one reflection band being polarization dependent, wherein light of a first circular polarization is reflected stronger than light of a second circular polarization.

8. The switchable window comprising the optical device ( 10 ) according to claim 7 , wherein the cholesteric layer and a quarter wave retarder layer are arranged on one side of the at least one switchable layer ( 15 ), the quarter wave retarder layer facing the at least one switchable layer ( 15 ), the quarter wave retarder changing the transmitted second circular polarization to a linear polarization.

9. The switchable window comprising the optical device ( 10 ) according to claim 1 , wherein at least 90% of light having a wavelength within the at least one transmission band is transmitted by the at least one optical layer ( 20 , 22 ).

10. The switchable window comprising the optical device ( 10 ) according to claim 1 , wherein the switchable optical device ( 10 ) comprises at least two optical layers ( 20 , 22 ).

11. The switchable window comprising the optical device ( 10 ) according to claim 1 , wherein the at least one optical layer having at least one reflection band which includes at least a first part of the visible spectrum and having at least one transmission band which includes at least a second part of the visible spectrum, is a reflective layer.

12. The switchable window comprising the optical device ( 10 ) according to claim 1 , as a window in a building or a vehicle.

Assignees

• Merck Patent Gmbh

Inventors

• De Jong Ties
• Van Oosten Casper

Classifications

• G02F1/133638

  Waveplates, i.e. plates with a retardation value of lambda/n · CPC title

• G02F1/13725 Primary

  based on guest-host interaction (G02F1/13762, G02F1/13737, take precedence) · CPC title

• G02F1/133553 Primary

  Reflecting elements (associated to illuminating devices G02F1/133605) · CPC title

• G02F1/155

  Electrodes · CPC title