Recycling automotive phosphate rinse water stream

Patent metadata

Field	Value
Publication number	US-11136246-B2
Application number	US-201816037817-A
Country	US
Kind code	B2
Filing date	Jul 17, 2018
Priority date	Jul 18, 2017
Publication date	Oct 5, 2021
Grant date	Oct 5, 2021

Abstract

The present disclosure relates to recycling automotive phosphate rinse water. An apparatus and method is disclosed for treating process water containing phosphate. The apparatus may include a process water line. The process water line may be in fluid communication with a sample process water line. The sample process water line may be in fluid communication with a dilution line. The sample process water line, the dilution line, and a phosphate analyzer may be in fluid communication with a diluted process water line. The apparatus may also include a chemical additive feed line in fluid communication with the process water line downstream from the sample process water line.

First claim

What is claimed is:

1. A method of treating water, comprising:
diverting a portion of process water having a flow rate and comprising phosphate;
diluting the portion of the process water with dilution water having a flow rate to form diluted process water;
passing the diluted process water into a phosphate analyzer;
wherein the portion of process water, the dilution water, the diluted process water, and the phosphate analyzer are in fluid communication;
determining a phosphate concentration of the diluted process water, wherein the phosphate concentration of the diluted process water is about 50 ppm or lower; and
determining a phosphate concentration of the process water using a ratio of the dilution water flow rate to the flow rate of the portion of the process water and the phosphate concentration of the diluted process water, wherein the dilution water flow rate and the flow rate of the portion of the process water are controlled by control valves and measured by flow meters, and wherein the phosphate analyzer, control valves, and flow meters are in electrical communication with a controller;
calculating an amount of a phosphate control additive to add to the process water; and
injecting the phosphate control additive into the process water to form treated water.

2. The method of claim 1 , wherein the phosphate control additive is selected from ferric sulfate, ferric chloride, sodium aluminate, aluminum chlorohydrate, aluminum, aluminum chloride, polyaluminum chloride, cerium chloride, calcium-based coagulant, anionic polymer flocculant, and any combination thereof.

3. The method of claim 2 , wherein the phosphate control additive is selected from ferric sulfate, ferric chloride, and any combination thereof.

4. The method of claim 1 , wherein the flow meter is an oval gear meter.

5. The method of claim 1 , further comprising passing the treated water through a filtration system.

6. The method of claim 5 , further comprising passing the treated water through a second filtration system.

7. The method of claim 1 , wherein the phosphate control additive is selected from ferric sulfate or polyaluminum chloride.

8. The method of claim 1 further comprising adjusting the pH of the process water to about 6.5 or above.

9. The method of claim 8 , wherein the pH of the process water is adjusted to between about 6.5 to about 8.0.

10. The method of claim 1 , wherein the process water is used in an automotive phosphating process.

11. A method of treating process water used in an automotive phosphating process, comprising:
passing diluted process water into a phosphate analyzer, wherein the diluted process water is a mixture of a sample of process water and dilution water,
determining a phosphate concentration of the process water using a ratio of a dilution water flow rate to a flow rate of the sample of process water that passed through a gear meter and the phosphate concentration of the diluted process water, wherein the dilution water flow rate and the flow rate of the portion of the process water are controlled by control valves and measured by flow meters, and wherein the phosphate analyzer, control valves and flow meters are in electrical communication with a controller, and
calculating an amount of a phosphate control additive to add to the process water,
wherein the process water, the dilution water, the diluted process water, and the phosphate analyzer are in fluid communication.

12. The method of claim 11 , further comprising injecting the phosphate control additive into the process water to form treated water; and
passing the treated water through a filtration system.

Assignees

• Ecolab Usa Inc

Inventors

• Williams Daniel M
• Mackovski Tony Veljan
• Tait Bruce
• Miknevich Joseph Peter
• Bogda Alex Michael
• Narayanan Aarthi
• Von Drasek William A

Classifications

• C02F2209/18

  PO4-P · CPC title

• C02F2103/44

  from vehicle washing facilities · CPC title

• C02F2301/043

  Treatment of partial or bypass streams · CPC title

• B01D61/145

  Ultrafiltration · CPC title

• C02F2303/22

  Eliminating or preventing deposits, scale removal, scale prevention (C02F1/042, C02F1/4602, C02F5/00 take precedence) · CPC title