Process for the preparation of a sterilized ceramic body comprising or essentially consisting of stabilized zirconia of a defined colour

Patent metadata

Field	Value
Publication number	US-11135331-B2
Application number	US-201616065885-A
Country	US
Kind code	B2
Filing date	Dec 22, 2016
Priority date	Dec 24, 2015
Publication date	Oct 5, 2021
Grant date	Oct 5, 2021

Abstract

A process for the preparation of a sterilized ceramic body including or essentially consisting of stabilized zirconia of a defined colour, including the steps of: providing a ceramic primary body including or essentially consisting of stabilized zirconia of a first colour A, and sterilizing the primary body using radiation sterilization whereby the primary body undergoes a colour change to a colour B. The process includes the further step of irradiating the sterilized primary body with electromagnetic radiation of at least one wavelength lying in the wavelength band ranging from 150 nm to 700 nm to induce an at least partial reversal of the colour change to obtain a colour C of the sterilized ceramic body, the colour C complying with the following requirements in the CIELAB colour space: L* being from 54 to 95, a* being from −15 to 15 and b* being from −15 to 15.

First claim

The invention claimed is:

1. A process for the preparation of a sterilized ceramic body comprising stabilized zirconia of a defined colour, the process comprising
a) providing a ceramic primary body comprising stabilized zirconia of a first colour A,
b) sterilizing the ceramic primary body using radiation sterilization to form a sterilized ceramic primary body whereby the ceramic primary body undergoes a colour change to a colour B, and
c) irradiating the sterilized ceramic primary body with electromagnetic radiation of at least one wavelength lying in a wavelength band ranging from 150 nm to 700 nm to induce an at least partial reversal of the colour change of step b) to obtain a colour C of the sterilized ceramic primary body, the colour C complying with the following requirements in the International Commission on Illumination L*a*b* (CIELAB) colour space:
L* being from 54 to 95,
a* being from −15 to 15 and
b* being from −15 to 15,

wherein step c) is carried out at a temperature below 60° C.

2. The process according to claim 1 , wherein in step c) the sterilized ceramic primary body is irradiated with electromagnetic radiation of at least one wavelength lying in the wavelength band ranging from 150 nm to 600 nm.

3. The process according to claim 1 , wherein the stabilized zirconia comprises vacancies in the oxygen-sublattice of its crystal structure.

4. The process according to claim 1 , wherein the stabilized zirconia is yttria-stabilized zirconia.

5. The process according to claim 1 , wherein the stabilized zirconia comprises extrinsic defects in the lattice of its crystal structure.

6. The process according to claim 1 , wherein in step b) the ceramic primary body is sterilized using ionizing radiation sterilization.

7. The process according to claim 1 , wherein in step b) an activation of colour centers in the stabilized zirconia occurs, and in step c) a transition of electrons of the colour centers from an excited state into a relaxed state is induced.

8. The process according to claim 1 , wherein the wavelength band according to step c) ranges from 200 nm to 650 nm.

9. The process according to claim 1 , wherein in step c) the sterilized ceramic precursor body is irradiated with electromagnetic radiation of two or more different wavelengths both lying in the wavelength band ranging from 150 to 700 nm.

10. The process according to claim 1 , wherein the ceramic primary body provided in step a) is a dental article in pre-assembled and packaged form.

11. The process according to claim 1 , wherein after step c) any heat treatment step is omitted.

12. The process according to claim 1 , wherein the colour C complies with the requirement that L* is from 63 to 90.

13. The process according to claim 1 , wherein:
in step a), the ceramic primary body comprises yttria-stabilized zirconia of the first colour A, the ceramic primary body being in the form of a dental article containing two or more dental article components that are pre-assembled with one another and contained in an at least partially translucent packaging,
in step b), the ceramic primary body is sterilized using gamma-sterilization whereby the ceramic primary body undergoes the colour change to the colour B, and
in step c), the sterilized primary body is irradiated with electromagnetic radiation of at least one wavelength lying in the wavelength band ranging from 320 nm to 500 nm to induce the at least partial reversal of the colour change of step b) to the colour C, the colour C complying with the following requirements in the CIELAB colour space:
L* being from 68 to 85,
a* being from −10 to 10 and
b* being from −5 to 15.

14. The process according to claim 1 , wherein the colour C complies with the requirement that L* is from 70 to 75.

15. A sterilized ceramic body obtained by the process according to claim 1 .

16. A dental implant system comprising a dental article composed of the sterilized ceramic body according to claim 15 .

Assignees

• Straumann Holding Ag

Inventors

• Rohner Adrian
• Berner Simon
• Stephan Marc

Classifications

• A61L2103/05

  Living organisms or biological materials · CPC title

• A61C13/082 Primary

  Cosmetic aspects, e.g. inlays; Determination of the colour (A61C19/10 takes precedence) · CPC title

• C04B2235/665

  Local sintering, e.g. laser sintering · CPC title

• C04B2235/3225

  Yttrium oxide or oxide-forming salts thereof · CPC title

• B65B55/16

  by irradiation · CPC title