Electrolyte formulations for electrochemical cells containing a silicon electrode

Patent metadata

Field	Value
Publication number	US-11133530-B2
Application number	US-201916399636-A
Country	US
Kind code	B2
Filing date	Apr 30, 2019
Priority date	Aug 30, 2016
Publication date	Sep 28, 2021
Grant date	Sep 28, 2021

Abstract

Additives to electrolytes that enable the formation of comparatively more robust SEI films on silicon anodes. The SEI films in these embodiments are seen to be more robust in part because the batteries containing these materials have higher coulombic efficiency and longer cycle life than comparable batteries without such additives.

First claim

The invention claimed is:

1. A method of forming a solid-electrolyte interphase on an anode in a lithium ion battery, comprising:
charging and discharging the lithium ion battery to form the solid-electrolyte interphase, wherein the lithium ion battery comprises: (i) an anode comprising silicon; (ii) a cathode; and (iii) an electrolyte solution;
wherein the electrolyte solution comprises a lithium salt, ethylene carbonate, and an organic additive selected from the group consisting of mono-(trimethylsilyl)phosphite, tris(trimethylsilyl)phosphite, tris(trimethylsilyl)phosphate, tris(trimethylsilyl)borate, tris(trimethylsiloxy)vinylsilane, tris(trimethylsilyl)silane, and tris(trimethylsiloxy) ethylene.

2. The method of claim 1 wherein the battery is charged to at least 4.2 V.

3. The method of claim 1 wherein the battery is charged to greater than 4.2 V.

4. The method of claim 1 wherein the battery is charged to at least 4.45 V.

5. The method of claim 1 wherein the battery is charged and discharged at least 200 times and the solid-electrolyte interphase remains stable as demonstrated by a capacity retention by the battery of at least 60% at cycle 200 .

6. The method of claim 1 wherein the battery is charged and discharged at least 200 times and the solid-electrolyte interphase remains stable as demonstrated by a capacity retention by the battery of at least 70% at cycle 200 .

7. The method of claim 1 wherein the battery is charged and discharged at least 200 times and the solid-electrolyte interphase remains stable as demonstrated by a capacity retention by the battery of at least 80% at cycle 200 .

8. The method of claim 1 wherein the battery is charged and discharged at least 200 times and the solid-electrolyte interphase remains stable as demonstrated by a capacity retention by the battery of at least 90% at cycle 200 .

9. The method of claim 1 wherein the organic additive comprises mono-(trimethylsilyl)phosphite.

10. The method of claim 1 wherein the organic additive comprises tris(trimethylsilyl)phosphite.

11. The method of claim 1 wherein the organic additive comprises tris(trimethylsilyl)phosphate.

12. The method of claim 1 wherein the organic additive comprises tris(trimethylsilyl)borate.

13. The method of claim 1 wherein the organic additive comprises tris(trimethylsiloxy)vinylsilane.

14. The method of claim 1 wherein the organic additive comprises tris(trimethylsilyl)silane.

15. The method of claim 1 wherein the organic additive comprises tris(trimethylsiloxy) ethylene.

16. A method comprising:
generating an electrolyte solution that comprises a lithium salt, ethylene carbonate, and an organic additive, wherein the organic additive contains at least one methylsiloxy functional group ((CH 3 ) 3 SiO—);
constructing a lithium ion battery that comprises: (i) an anode comprising silicon; (ii) a cathode; and (iii) the electrolyte solution; and
charging and discharging the lithium ion battery to form a solid-electrolyte interphase on the anode.

17. The method of claim 16 , wherein the organic additive is selected from the group consisting of mono-(trimethylsilyl)phosphite, tris(trimethylsilyl)phosphite, tris(trimethylsilyl)phosphate, tris(trimethylsilyl)borate, tris(trimethylsiloxy)vinylsilane, and tris(trimethylsiloxy) ethylene.

Assignees

• Wildcat discovery technologies inc

Inventors

• Zhu Ye
• Cheng Gang
• Strand Deidre
• Yang Jen-Hsien

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M2300/0025

  Organic electrolyte · CPC title

• H01M4/1395 Primary

  of electrodes based on metals, Si or alloys · CPC title

• H01M10/0569

  characterised by the solvents · CPC title