Simple route to highly conductive porous graphene from carbon nanodots for supercapacitor applications

Patent metadata

Field	Value
Publication number	US-11133134-B2
Application number	US-201816033266-A
Country	US
Kind code	B2
Filing date	Jul 12, 2018
Priority date	Jul 14, 2017
Publication date	Sep 28, 2021
Grant date	Sep 28, 2021

Abstract

Disclosed herein are methods and compositions directed to a promising class of nanomaterials called organic nanoparticles, or carbon nanodots. The present disclosure provides a facile method for the conversion of biomolecule-based carbon nanodots into high surface area three-dimensional graphene networks with excellent electrochemical properties.

First claim

What is claimed is:

1. An energy storage device comprising:
a. a first electrode; and
b. a second electrode separated from the first electrode by a dielectric, wherein at least one of the first electrode and the second electrode comprises a 3D turbostratic graphene network comprising a plurality of carbon nanodots interconnected through carbon-carbon bonds, and wherein the energy storage device has a charge-discharge cycling rate time constant of at most about 8 milliseconds.

2. The energy storage device of claim 1 , wherein the 3D turbostratic graphene network is porous.

3. The energy storage device of claim 2 , wherein the 3D turbostratic graphene network has an average pore size of about 10 nanometers (nm) to about 10,000 nm.

4. The energy storage device of claim 3 , wherein the 3D turbostratic graphene network has an elemental composition of about 90% carbon, about 8% oxygen, and nitrogen.

5. The energy storage device of claim 2 , wherein the 3D turbostratic graphene network comprises a spongy hierarchical porous structure.

6. The energy storage device of claim 2 , wherein the pores are separated by carbon walls consisting of layers of graphene.

7. The energy storage device of claim 1 , wherein the at least one of the first electrode and the second electrode has an active surface area of at least about 100 square meters per gram.

8. The energy storage device of claim 1 , wherein the at least one of the first electrode and the second electrode has an electrical conductivity of at least about 200 siemens per meter.

9. The energy storage device of claim 1 , having an energy density of at least about 3 watt-hours per kilogram at a power density of at least about 860 kilowatts.

10. The energy storage device of claim 1 , having a specific gravimetric capacitance of at least about 4 farads per gram.

11. The energy storage device of claim 1 , having a specific volumetric capacitance of at least about 30 millifarads per cubic centimeter.

12. The energy storage device of claim 1 , retaining at least about 94% capacitance after about 20,000 charge-discharge cycles.

13. The energy storage device of claim 1 , wherein the 3D turbostratic graphene network has a Raman spectrum comprising a D band at about 1323 cm −1 , a G band at about 1570 cm −1 , a D′ band at about 1604 cm −1 , and a G′ band 2636 cm −1 .

14. The energy storage device of claim 13 , wherein G′ band has a full width at half maximum of about 74 cm −1 .

15. The energy storage device of claim 13 , wherein the at least one of the first electrode and the second electrode comprises an amorphous carbon structure having a Raman spectrum comprising a D band at about 1324 cm −1 , a D** band at about 1468 cm −1 , and a G band at about 1574 cm −1 .

16. The energy storage device of claim 1 , wherein the 3D turbostratic graphene network has a Raman spectrum comprising a D band at about 1324 cm −1 , a G band at about 1582 cm −1 , a D′ band at about 1617 cm −1 , and a G′ band 2655 cm −1 .

17. The energy storage device of claim 16 , wherein the Raman spectrum further comprises a D+D″ band at about 2461 cm −1 and a D+G band at about 2922 cm −1 .

18. A 3D turbostratic graphene network comprising a plurality of carbon nanodots interconnected through carbon-carbon bonds, having an active surface area of at least about 230 square meters per gram and an electrical conductivity of at least about 200 siemens per meter, wherein the 3D turbostratic graphene network is configured to provide an energy storage device with a charge-discharge cycling rate time constant of at most about 8 milliseconds.

19. The 3D turbostratic graphene network of claim 18 , wherein the 3D turbostratic graphene network is porous and has an average pore size of about 10 nanometers (nm) to about 100,000 nm.

20. The 3D turbostratic graphene network of claim 18 , wherein the 3D turbostratic graphene network has an elemental composition of about 89% carbon, about 8% oxygen, and nitrogen.

21. The 3D turbostratic graphene network of claim 18 , wherein the 3D turbostratic graphene network comprises a spongy hierarchical porous structure.

22. The 3D turbostratic graphene network of claim 18 , wherein the 3D turbostratic graphene network is porous and has pores separated by carbon walls consisting of layers of graphene.

23. The 3D turbostratic graphene network of claim 18 , having an active surface area of at least about 240 square meters per gram.

24. The 3D turbostratic graphene network of claim 18 , having an electrical conductivity of at least about 220 siemens per meter.

25. The 3D turbostratic graphene network of claim 18 , having a Raman spectrum comprising a D band at about 1323 cm −1 , a G band at about 1570 cm −1 , a D′ band at about 1604 cm −1 , and a G′ band 2636 cm −1 .

26. The 3D turbostratic graphene network of claim 18 , wherein the 3D turbostratic graphene network has a Raman spectrum comprising a D band at about 1324 cm −1 , a G band at about 1582 cm −1 , a D′ band at about 1617 cm −1 , and a G′ band 2655 cm −1 .

27. The 3D turbostratic graphene network of claim 26 , wherein the Raman spectrum further comprises a D+D″ band at about 2461 cm −1 and a D+G band at about 2922 cm −1 .

Assignees

• Univ California

Inventors

• Strauss Volker
• Kaner Richard B
• El-Kady Maher F

Classifications

• H01G11/86 Primary

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title

• H01G11/36 Primary

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• H01G11/32

  Carbon-based · CPC title

• C01B2204/22

  Electronic properties · CPC title

• C01B2204/32

  Size or surface area · CPC title