Coating material for coating layer of injection mold and method of manufacturing coating layer of injection mold

Patent metadata

Field	Value
Publication number	US-11130877-B2
Application number	US-201816180671-A
Country	US
Kind code	B2
Filing date	Nov 5, 2018
Priority date	Jul 11, 2018
Publication date	Sep 28, 2021
Grant date	Sep 28, 2021

Abstract

Disclosed is a coating material for a coating layer of an injection mold, the coating material including 100 parts by weight of a resin composition and about 30 to 40 parts by weight of a curing agent. The resin composition includes an amount of about 40 to 50 wt % of a first acrylic resin, an amount of about 5 to 15 wt % of a second acrylic resin having a weight average molecular weight less than a weight average molecular weight of the first acrylic resin, an amount of about 10 to 15 wt % of a carbon component, an amount of about 0.5 to 2 wt % of a matting agent, an amount of about 0.1 to 0.3 wt % of a catalyst and an amount of about 20 to 35 wt % of a solvent, all the wt % are based on the total weight of the resin composition.

First claim

What is claimed is:

1. A coating composition for a coating layer of an injection mold, comprising:
100 parts by weight of a resin composition; and
about 30 to 40 parts by weight of a curing agent,
wherein the resin composition comprises:
an amount of about 40 to 50 wt % of a first acrylic resin;
an amount of about 5 to 15 wt % of a second acrylic resin having a weight average molecular weight less than a weight average molecular weight of the first acrylic resin;
an amount of about 10 to 15 wt % of carbon component;
an amount of about 0.5 to 2 wt % of a matting agent;
an amount of about 0.1 to 0.3 wt % of a catalyst; and
an amount of about 20 to 35 wt % of a solvent, wherein all the wt % based on the total weight of the resin composition,
wherein the first acrylic resin has a weight average molecular weight of about 90,000 to 110,000.

2. The coating composition of claim 1 , wherein the first acrylic resin has an acid value of about 1 to 4 mg/KOH and a hydroxyl group content of about 0.5 to 1.0 mol %.

3. The coating composition of claim 1 , wherein the second acrylic resin has an acid value of about 3 to 10 mg/KOH and a hydroxyl group content of about 3 to 6 mol %.

4. The coating composition of claim 1 , wherein the second acrylic resin has a weight average molecular weight of about 8,000 to 15,000.

5. The coating composition of claim 1 , wherein the carbon component comprises a carbon particle having a size of about 150 to 300 nm.

6. The coating composition of claim 1 , wherein the matting agent comprises a particle having a size of about 1.0 to 2.0 μm.

7. The coating composition of claim 1 , wherein the catalyst comprises a urethane-based catalyst.

8. The coating composition of claim 1 , wherein the curing agent comprises an amount of about 90 to 99 wt % of hexamethylene diisocyanate and an amount of about 1 to 10 wt % of a silicone-based curing agent comprising isophorone diisocyanate and triethoxysilane, based on the total weight of the curing agent.

9. The coating material of claim 1 , wherein the solvent comprises at least one of an ester-based solvent and a ketone-based solvent.

10. A method of manufacturing a coating layer of an injection mold, comprising:
preparing a coating composition comprising 100 parts by weight of a resin composition and about 30 to 40 parts by weight of a curing agent;
applying the coating composition on the injection mold; and
curing the coating composition,
wherein the resin composition comprises an amount of about 40 to 50 wt % of a first acrylic resin, an amount of about 5 to 15 wt % of a second acrylic resin having a weight average molecular weight less than a weight average molecular weight of the first acrylic resin, an amount of about 10 to 15 wt % of a carbon component, an amount of about 0.5 to 2 wt % of a matting agent, an amount of about 0.1 to 0.3 wt % of a reaction catalyst, and an amount of about 20 to 35 wt % of a solvent, wherein all the wt % are based on the total weight of the resin composition,
wherein the first acrylic resin has a weight average molecular weight of about 90,000 to 110,000.

11. The method of claim 10 , wherein the curing the coating film is performed at a temperature of about 80 to 100° C. for about 30 to 40 min using a light having a wavelength of about 700 to 1050 nm.

12. The method of claim 10 , wherein the coating composition is applied on the injection mold by spraying.

13. The method of claim 12 , further comprising admixing the coating composition with about 150 to 200 parts by weight of the solvent based on 100 parts by weight of the resin composition before the applying the coating composition on the injection mold.

14. The method of claim 10 , wherein the curing agent comprises an amount of about 90 to 99 wt % of hexamethylene diisocyanate and an amount of about 1 to 10 wt % of a silicone-based curing agent comprising isophorone diisocyanate and triethoxysilane, based on the total weight of the curing agent.

15. The method of claim 10 , wherein the solvent comprises at least one of an ester-based solvent or a ketone-based solvent.

16. The method of claim 10 , wherein the first acrylic resin has an acid value of about 1 to 4 mg/KOH and a hydroxyl group content of about 0.5 to 1.0%.

17. The method of claim 10 , wherein the second acrylic resin has an acid value of about 3 to 10 mg/KOH and a hydroxyl group content of about 3 to 6%.

18. The method of claim 10 , wherein the second acrylic resin has a weight average molecular weight of about 8,000 to 15,000.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Noroo Bee Chemical Co Ltd
• Moltex Co Ltd

Inventors

• Jang Kyeong Hoon
• Han In Soo
• Kim Dae Sik
• An Jae Hyun
• Yi Seul
• Jung Ik Jin
• Park Ju Seong
• Jung Soon Joon
• Han Seung Sik
• Ahn Jae Beom
• Lee Yong Chul
• Sung Kie Moon
• Kim Soon Gi
• Choi Hak Soon

Classifications

• C09D133/02 Primary

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• B29C45/26

  Moulds · CPC title

• C09D7/61

  inorganic · CPC title

• C09D7/42

  Gloss-reducing agents · CPC title

• C09D133/00 Primary

  Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers · CPC title