Alumina abrasive particles used for automotive finishing compositions

Patent metadata

Field	Value
Publication number	US-11130682-B2
Application number	US-201815897117-A
Country	US
Kind code	B2
Filing date	Feb 14, 2018
Priority date	Feb 15, 2017
Publication date	Sep 28, 2021
Grant date	Sep 28, 2021

Abstract

The present disclosure is directed to an alpha alumina powder having a specific surface area, a specific crystallite size, and a specific particle size distribution for use in abrasive polishes, and method of making such powder. The method of making the alpha alumina powder can include calcining an aluminum oxide precursor powder at a temperature of 800-1500° C. and milling the calcined powder to the specific particle size distribution. The alpha alumina powder disclosed herein can quickly enable high removal rate with undiminished aesthetic quality when used in abrasive polishes.

First claim

The invention claimed is:

1. An alumina powder comprising at least 75 wt % alpha alumina, wherein the alumina powder has:
a specific surface area of 5-12 m 2 /g; and
a particle size distribution with a D5 of 0.01-5 microns, a D50 of 5-50 microns, and a D95 of 30-120 microns,

wherein particles in the alumina powder comprise a plurality of crystallites having an average primary crystallite size of less than 2 microns.

2. The alumina powder of claim 1 , wherein the alumina powder comprises at least 85 wt % alpha alumina.

3. The alumina powder of claim 1 , wherein the particle size distribution of the alumina powder has a D5 of 0.1-1 microns, a D50 of 10-45 microns, and a D95 of 60-150 microns.

4. The alumina powder of claim 1 , wherein the particle size distribution has a D0 of 0.1-1 microns.

5. The alumina powder of claim 1 , wherein the particle size distribution has a D100 of 65-200 microns.

6. The alumina powder of claim 1 , wherein the surface area of the alumina powder is 7-10 m 2 /g.

7. The alumina powder of claim 1 , wherein the alumina powder has a density of at least 3 g/cm 3 .

8. The alumina powder of claim 7 , wherein the density is at least 3.8 g/cm 3 .

9. The alumina powder of claim 1 , wherein the average primary crystallite size is 0.1-0.5 microns.

10. The alumina powder of claim 1 , wherein each of the crystallites have a primary crystallite size of less than 2 microns.

11. The alumina powder of claim 10 , wherein each of the crystallites have a primary crystallite size of less than 1 micron.

12. The alumina powder of claim 1 , wherein at least a portion of the calcined alumina powder has a pore volume of 0.001-0.5 cm 3 /g and a pore size of about 2-50 nm.

13. The alumina powder of claim 1 , wherein at least a portion of the calcined alumina powder has a pore volume of 0.01-0.2 cm 3 /g and a pore size of 50-500 nm.

14. The alumina powder of claim 1 , wherein the particle size distribution has a D100 of less than 200 microns.

15. A method of forming a milled alumina powder, the method comprises:
calcining a powder comprising aluminum hydroxide at a temperature of 800-1500° C. to form an alumina powder comprising at least 75 wt % alpha alumina; and
milling the alumina powder to a have a particle size distribution with a D5 of 0.01-5 microns, a D50 of 5-20 microns, and a D95 of 65-110 microns to form the milled alumina powder.

16. The method of claim 15 , wherein the temperature is 900-1400° C.

17. The method of claim 16 , wherein the temperature is 1100-1300° C.

18. The method of claim 15 , wherein the powder comprising aluminum hydroxide is calcined for 1-48 hours.

19. The method of claim 15 , wherein the powder comprising aluminum hydroxide is calcined in a rotary kiln, a static kiln, or a pusher kiln.

20. The method of claim 15 , wherein the alumina powder comprises at least 85 wt % alpha alumina.

21. The method of claim 15 , wherein the alumina powder is milled to a have a particle size distribution with a D5 of 0.1-1 microns, a D50 of 10-15 microns, and a D95 of 75-100 microns.

22. The method of claim 15 , wherein the alumina powder is milled to a have a particle size distribution with a D0 of 0.01-0.2 microns.

23. The method of claim 15 , wherein the alumina powder is milled to a have a particle size distribution with a D100 of 100-200 microns.

24. The method of claim 15 , wherein the alumina powder is milled using a vertical agitator, a horizontal agitator, a roll mill, a jet mill, or a planetary mill.

25. The method of claim 15 , wherein the particle size distribution has a D100 of less than 200 microns.

26. A slurry comprising the alumina powder of claim 1 , and at least one fluid for suspending the alumina powder.

27. An abrasive polish comprising the alumina powder of claim 1 , and at least one of a dispersant, a surfactant, a stabilizer, and a rheology modifier.

28. A method of making an abrasive polish comprising:
adding the alumina powder of claim 1 to a container;
adding at least one of a dispersant, a surfactant, a stabilizer, and a rheology modifier to the container; and
mixing the alumina powder and the at least one of the dispersant, the surfactant, the stabilizer, and the rheology modifier.

Assignees

• Saint Gobain Ceramics

Inventors

• Mulder Carlijn Lucinde
• Berberian James
• Bottiglieri Stephen
• Salvatore James A

Classifications

• C01P2006/16

  Pore diameter · CPC title

• C01P2002/60

  Compounds characterised by their crystallite size · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01F7/441

  by calcination · CPC title

• C01P2006/14

  Pore volume · CPC title