Electrical wire and wire harness using the same

Patent metadata

Field	Value
Publication number	US-11130312-B2
Application number	US-201815895332-A
Country	US
Kind code	B2
Filing date	Feb 13, 2018
Priority date	Feb 14, 2017
Publication date	Sep 28, 2021
Grant date	Sep 28, 2021

Abstract

An electrical wire includes an aluminum element wire that has an aluminum base material and carbon nanotubes dispersed in the aluminum base material, in which the aluminum element wire has an electrical conductivity of 62% IACS or more and a tensile strength of 130 MPa or more. The aluminum base material is a polycrystal having a plurality of aluminum crystal grains. Further, a carbon nanotube conductive path, which is composed of the carbon nanotube, and forms a conductive path allowing electricity to conduct therethrough in a longitudinal direction of the aluminum element wire by being present in a part of grain boundaries between the plurality of aluminum crystal grains in a transverse cross section of the aluminum base material, and being present along the longitudinal direction of the aluminum element wire, is formed in the aluminum base material.

First claim

The invention claimed is:

1. An electrical wire comprising: an aluminum element wire having an aluminum base material and carbon nanotubes dispersed in the aluminum base material, wherein the aluminum element wire has an electrical conductivity of 62% IACS or more and a tensile strength of 130 MPa or more,
wherein the aluminum base material comprises a polycrystal having a plurality of aluminum crystal grains; and a plurality of carbon nanotube conductive paths composed of the carbon nanotubes, which forms a conductive path allowing electricity to conduct therethrough in a longitudinal direction of the aluminum element wire by being present in a part of grain boundaries between the plurality of aluminum crystal grains in a transverse cross section of the aluminum base material, and is present along the longitudinal direction of the aluminum element wire, wherein the plurality of carbon nanotube conductive paths is formed in the aluminum base material,
wherein each of the plurality of the carbon nanotube conductive paths is spaced apart from one another in the transverse cross section of the aluminum base material
wherein the aluminum base material is disposed in at least a part of a surface of the aluminum element wire,
wherein the carbon nanotube conductive paths formed at grain boundaries of the plurality of aluminum crystal grains have a thickness of from 2 nm to 10 μm,
wherein an average crystal grain size of the plurality of aluminum crystal grains is from 1 μm to 50 μm in both a longitudinal and transverse cross sections of the aluminum element wire from both a longitudinal cross-sectional view and a transverse cross sectional view of the aluminum element wire,
wherein an intensity ratio of G band to D band in a Raman spectrum of the carbon nanotube comprises 5 or more; and
wherein the plurality of carbon nanotube conductive paths is present continuously in the longitudinal direction of the aluminum element wire by being adjacent to one another in the longitudinal direction so as to contact one another.

2. The electrical wire according to claim 1 , wherein, in the aluminum element wire, a content of the carbon nanotubes with respect to the aluminum base material is from 0.1 mass % to 1.25 mass %.

3. The electrical wire according to claim 1 , further comprising a coating material for covering the peripheral edge of the aluminum element wire, wherein the coating material has a volume resistivity of 10 9 Ω·mm or more.

4. The electrical wire according to claim 3 , the aluminum element wire directly contacts with the coating material.

5. A wire harness comprising the electrical wire according to claim 1 .

6. An electrical wire comprising: a plurality of aluminum element wires having an aluminum base material and carbon nanotubes dispersed in the aluminum base material, wherein each of the plurality of the aluminum element wires has an electrical conductivity of 62% IACS or more and a tensile strength of 130 MPa or more,
wherein the aluminum base material comprises a polycrystal having a plurality of aluminum crystal grains; and a plurality of carbon nanotube conductive paths composed of the carbon nanotubes, which forms a conductive path allowing electricity to conduct therethrough in a longitudinal direction of each of the plurality of the aluminum element wires by being present in a part of grain boundaries between the plurality of aluminum crystal grains in a transverse cross section of the aluminum base material, is being present along the longitudinal direction of each of the plurality of the aluminum element wires, wherein the plurality of carbon nanotube conductive paths is formed in the aluminum base material,
wherein each of the plurality of the carbon nanotube conductive paths is spaced apart from one another in the transverse cross section of the aluminum base material,
wherein each of the plurality of the aluminum element wires directly contacts with an adjacent aluminum element wire of the plurality of the aluminum element wires,
wherein the carbon nanotube conductive paths formed at grain boundaries of the plurality of aluminum crystal grains have a thickness of from 2 nm to 10 μm,
wherein an average crystal grain size of the plurality of aluminum crystal grains is from 1 μm to 50 μm in both a longitudinal and transverse cross sections of the aluminum element wire from both a longitudinal cross-sectional view and a transverse cross sectional view of the aluminum element wire;
wherein an intensity ratio of G band to D band in a Raman spectrum of the carbon nanotube comprises 5 or more; and
wherein the plurality of carbon nanotube conductive paths is present continuously in the longitudinal direction of the aluminum element wire by being adjacent to one another in the longitudinal direction so as to contact one another.

Assignees

• Yazaki Corp
• Univ Tokyo

Inventors

• Uchida Youhei
• Gonda Hideo
• Tokutomi Junichirou
• Yanagimoto Jun

Classifications

• H01B1/023 Primary

  Alloys based on aluminium · CPC title

• H01B1/04

  mainly consisting of carbon-silicon compounds, carbon or silicon · CPC title

• B32B2307/202

  Conductive · CPC title

• C08K3/041

  Carbon nanotubes · CPC title

• B32B15/20 Primary

  comprising aluminium or copper {(B32B15/016 and B32B15/017 take precedence)} · CPC title