Non-aqueous liquid anti-shrinkage cement additives

Patent metadata

Field	Value
Publication number	US-11124452-B2
Application number	US-202016906852-A
Country	US
Kind code	B2
Filing date	Jun 19, 2020
Priority date	May 19, 2016
Publication date	Sep 21, 2021
Grant date	Sep 21, 2021

Abstract

The present disclosure relates to a method of cementing comprising: providing a cement composition comprising: water, a cement, and a non-aqueous liquid anti-shrinkage cement additive comprising calcined magnesium oxide and a non-aqueous liquid; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. Non-aqueous liquid anti-shrinkage cement additives, cement compositions, and systems are also provided.

First claim

What is claimed is:

1. A cement composition comprising:
water;
a cement; and
a suspension of calcined magnesium oxide in a hydrocarbon liquid.

2. The composition of claim 1 wherein the calcined magnesium oxide is present in an amount of about 1% to about 50% by weight in the suspension.

3. The composition of claim 1 wherein the hydrocarbon liquid is selected from the group consisting of natural gas liquids, liquid parrafins, naphthas, mineral oils, crude oils, synthesized hydrocarbon liquids, fuel oils, diesels, gasolines, biomass derived hydrocarbon liquids, coal derived hydrocarbon liquids, kerosene, or combinations thereof.

4. The composition of claim 1 wherein the suspension further comprises a dispersant selected from the group consisting of sulfonated naphthalene condensate, sulfonated acetone formaldehyde condensate, polycarboxylate ethers, or combinations thereof wherein the dispersant is present in an amount of about 0.01% to about 5% by weight in the suspension.

5. The composition of claim 1 wherein the suspension further comprises a viscosifying additive selected from the group consisting of organophilic clay, hydrophobically modified silica, hydrophobically modified bio-polymers, hydrophobically modified synthetic polymers, or combinations thereof wherein the viscosifying additive is present in an amount of about 0.01% to about 10% by weight in the suspension.

6. The composition of claim 1 wherein the suspension further comprises an emulsifying additive comprising a polysorbate, sorbitan esters, or combinations thereof wherein the emulsifying additive is present in an amount of about 0.01% to about 10% by weight in the suspension.

7. The composition of claim 1 wherein the suspension is present in an amount of about 0.01% to about 10% by weight of the cement.

8. A non-aqueous liquid anti-shrinkage cement additive comprising:
a non-aqueous liquid;
calcined magnesium oxide; and
a viscosifying additive selected from the group consisting of organophilic clay, hydrophobically modified silica, hydrophobically modified bio-polymers, hydrophobically modified synthetic polymers, or combinations thereof wherein the viscosifying additive is present in an amount of about 0.01% to about 10% by weight in the suspension.

9. The additive of claim 8 wherein the non-aqueous liquid comprises a hydrocarbon liquid.

10. The additive of claim 8 further comprising a dispersant.

11. The additive of claim 10 wherein the dispersant selected from the group consisting of sulfonated naphthalene condensate, sulfonated acetone formaldehyde condensate, polycarboxylate ethers, and any combination thereof.

12. The additive of claim 8 further comprising an emulsifying additive comprising a polysorbate, sorbitan esters, or combinations thereof wherein the emulsifying additive is present in an amount of about 0.01% to about 10% by weight in the suspension.

13. A method of preparing a non-aqueous liquid anti-shrinkage cement additive, the method comprising:
providing calcined magnesium oxide and a non-aqueous liquid comprising a hydrocarbon liquid;
adding the calcined magnesium oxide and a non-aqueous liquid to a container to form a mixture; and
shearing the mixture until a homogenous solution is obtained.

14. The method of claim 13 wherein the calcined magnesium oxide is present in an amount of about 1% to about 50% by weight in the mixture.

15. The method of claim 13 wherein calcined magnesium oxide is at least one or light burned magnesium oxide or dead-burned magnesium oxide.

16. The method of claim 13 wherein the hydrocarbon liquid is selected from the group consisting of natural gas liquids, liquid parrafins, naphthas, mineral oils, crude oils, synthesized hydrocarbon liquids, fuel oils, diesels, gasolines, biomass derived hydrocarbon liquids, coal derived hydrocarbon liquids, kerosene, or combinations thereof.

17. The method of claim 16 wherein the viscosifying additive is present in an amount of about 0.01% to about 10% by weight in the mixture.

18. The method of claim 13 wherein the mixture further comprises an emulsifying additive comprising a polysorbate, sorbitan esters, or combinations thereof.

19. The method of claim 18 wherein the emulsifying additive is present in an amount of about 0.01% to about 10% by weight in the mixture.

20. The method of claim 13 wherein the mixture further comprises a dispersant selected from the group consisting of sulfonated naphthalene condensate, sulfonated acetone formaldehyde condensate, polycarboxylate ethers, or combinations thereof, wherein the dispersant is present in an amount of about 0.01% to about 5% by weight in the mixture, and wherein the mixture further comprises a viscosifying additive selected from the group consisting of organophilic clay, hydrophobically modified silica, hydrophobically modified bio-polymers, hydrophobically modified synthetic polymers, or combinations thereof.

Assignees

• Halliburton Energy Services Inc

Inventors

• Lewis Samuel J
• Sodhi Thomas Singh
• Agapiou Kyriacos
• Kolasnikov Aleksey

Classifications

• C04B28/02 Primary

  containing hydraulic cements other than calcium sulfates · CPC title

• C04B40/0039

  Premixtures of ingredients · CPC title

• C04B2103/44

  Thickening, gelling or viscosity increasing agents · CPC title

• C04B24/36

  Bituminous materials, e.g. tar, pitch {(C04B24/243 takes precedence)} · CPC title

• C04B2111/346

  Materials exhibiting reduced plastic shrinkage cracking · CPC title