Methods for methanol-to-gasoline conversion with methanol recycling

Patent metadata

Field	Value
Publication number	US-11118115-B2
Application number	US-202016903220-A
Country	US
Kind code	B2
Filing date	Jun 16, 2020
Priority date	Jun 18, 2019
Publication date	Sep 14, 2021
Grant date	Sep 14, 2021

Abstract

Methanol-to-gasoline (MTG) conversion may be performed with a methanol recycling. Methanol may be fed to a first reactor where it may be catalytically converted under dimethyl ether formation conditions in the presence of a first catalyst to form a product mixture comprising dimethyl ether (DME), methanol, and water. The DME may be separated from the methanol and the water and delivered to a second reactor. In the second reactor, the DME may be catalytically converted under MTG conversion conditions in the presence of a second catalyst to form a second product mixture comprising gasoline hydrocarbons and light hydrocarbon gas. The methanol and the water from the first reactor may be separated further to obtain substantially water-free methanol, which may be returned to the first reactor. The separation of methanol from the water may be performed using the light hydrocarbon gas to effect stripping of the methanol.

First claim

The invention claimed is:

1. A method comprising:
providing a feed comprising methanol to a first reactor;
catalytically converting at least a portion of the feed in the first reactor under dimethyl ether formation conditions in the presence of a first catalyst to form a first product mixture comprising dimethyl ether (DME), methanol, and water;
separating the first product mixture into a first fraction comprising the DME and a second fraction comprising the methanol and the water;
providing the first fraction to a second reactor;
catalytically converting at least a portion of the DME in the second reactor under methanol-to-gasoline (MTG) conversion conditions in the presence of a second catalyst to form a second product mixture comprising gasoline hydrocarbons and light hydrocarbon gas;
separating the second fraction into substantially water-free methanol and an aqueous effluent, wherein separating the second fraction into substantially water-free methanol and the aqueous effluent comprises passing a stripping gas through the second fraction;
returning the substantially water-free methanol to the first reactor;
delivering a first portion of the light hydrocarbon gas to the second fraction to serve as the stripping gas; and
returning a second portion of the light hydrocarbon gas to the second reactor.

2. The method of claim 1 , further comprising:
separating the light hydrocarbon gas from the second product mixture.

3. The method of claim 1 , further comprising:
cooling the first product mixture prior to separating the first product mixture into the first fraction and the second fraction.

4. The method of claim 3 , further comprising:
delivering a third portion of the light hydrocarbon gas to the first product mixture to aid in separating the first product mixture.

5. The method of claim 1 , wherein the feed is provided to the first reactor continuously as part of a flow process.

6. The method of claim 1 , further comprising:
optionally separating the gasoline hydrocarbons from the second product mixture; and
processing the gasoline hydrocarbons,

wherein processing the gasoline hydrocarbons comprises passing the gasoline hydrocarbons through a debutanizer.

7. The method of claim 1 , wherein the first catalyst comprises gamma-alumina.

8. The method of claim 1 , wherein the second catalyst comprises a zeolite.

9. The method of claim 1 , wherein an amount of water in the first fraction provided to the second reactor is less than or equal to 5 wt. %.

10. The method of claim 1 , wherein separating the first product mixture takes place by distillation, and the DME is obtained as an overhead product from the distillation.

11. A method comprising:
providing a feed stream comprising methanol to a first reactor;
catalytically converting at least a portion of the feed stream in the first reactor under dimethyl ether formation conditions in the presence of a first catalyst to form a first product mixture comprising DME, methanol, and water;
delivering the first product mixture in a first stream from the first reactor to a first separation unit;
separating the first product mixture in the first separation unit to obtain a first fraction comprising the DME and a second fraction comprising the methanol and the water;
delivering the first fraction in a second stream to a second reactor;
catalytically converting at least a portion of the DME in the second reactor under MTG conversion conditions in the presence of a second catalyst to form a second product mixture comprising gasoline hydrocarbons and light hydrocarbon gas;
delivering the second fraction in a third stream to a second separation unit;
delivering at least a first portion of the light hydrocarbon gas to the second separation unit;
separating the second fraction in the second separation unit into substantially water-free methanol and an aqueous effluent using the light hydrocarbon gas to effect stripping;
returning the substantially water-free methanol in a fourth stream to the first reactor; and,

optionally separating the gasoline hydrocarbons from the second product mixture; and processing the gasoline hydrocarbons,
wherein processing the gasoline hydrocarbons comprises passing the gasoline hydrocarbons through a debutanizer.

12. The method of claim 11 , further comprising:
separating the light hydrocarbon gas from the second product mixture; and
returning a second portion of the light hydrocarbon gas to the second reactor.

13. The method of claim 12 , further comprising:
delivering a third portion of the light hydrocarbon gas to the first separation unit to aid in separating the first product mixture.

14. The method of claim 11 , further comprising:
cooling the first product mixture prior to delivering the first product mixture to the first separation unit.

15. The method of claim 11 , wherein separating the first product mixture takes place by distillation, and the DME is obtained as an overhead product from the distillation.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Harandi Mohsen N
• Rajagopalan Suriyanarayanan
• Staubs David W
• Helton Terry E
• Hindman Mitch L

Classifications

• C10G7/04 Primary

  Dewatering · CPC title

• Y02P30/20

  using bio-feedstock · CPC title

• C10G3/44 Primary

  characterised by the catalyst used · CPC title

• C10G2300/10

  Feedstock materials · CPC title

• C10G2400/02

  Gasoline · CPC title